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11.
Pashkevich K. I. Khomutov O. G. Filyakova V. I. Kuchin A. V. 《Russian Chemical Bulletin》1994,43(6):1002-1003
Russian Chemical Bulletin - Asymmetric polyfluorinated ketones RFCOR are formed by treating various derivatives of (polyfluoro)alkanoic acids (esters, anhydrides, acid chlorides) with lithium... 相似文献
12.
E. P. Promyshlennikova V. E. Kirichenko K. I. Pashkevich D. N. Grigor'eva R. V. Golovnya 《Russian Chemical Bulletin》1991,40(8):1541-1545
Retention indices and dI/dT values were obtained for members of six homologous and six pseudohomologous series of polyfluorinated saturated carboxylic esters on capillary columns with OV-101 or XE-60 as stationary phase. There was a nonlinear dependence of retention indices of fluorinated fatty acid esters on carbon chain length of homologs with m, n=1–6. A universal correlation equation was shown to describe the chromatographic behavior of polyfluorinated carboxylic esters.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1740–1745, August, 1991. 相似文献
13.
Polyfluoroalkyl-containing aziridinyl ketones, unlike their nonfluorinated analogs, react with hydrogen halides to give only -halo- -anvnoketones or their hydrogen halide salts. Thermal decomposition of the latter in the case where Hal = CI affords -chlorovinyl ketones.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 684–686, March, 1996. 相似文献
14.
Pashkevich D. S. Mukhortov D. A. Petrov V. B. Alekseev Yu. I. Asovich V. S. Barabanov V. G. 《Russian Journal of Applied Chemistry》2004,77(1):92-97
Formation of high-temperature inverse wave of the filtration combustion of graphite fixed bed in fluorine was studied. Scientific principles of the industrial process of the tetrafluoromethane synthesis from graphite and fluorine were developed. 相似文献
15.
V. I. Filyakova R. R. Latypov M. N. Rudaya K. I. Pashkevich 《Russian Chemical Bulletin》1991,40(7):1496-1499
-Polyfluoroalkyl-,-enones formed in the E,Z form are converted by the action of atmospheric oxygen into a 937 mixture of E,Z and Z,E isomers in the dark and 6040 mixture of these isomers in the light. The Z isomer of 1-phenyl-4,4, 4-trifluoro-2-buten-1-one was isolated preparatively for the first time and its E conformation relative to the C-C bond was established. The Z,E isomer spontaneously transforms into the indicated equilibrium mixtures.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1685–1689, July, 1991. 相似文献
16.
A. D. Sinegibskaya K. I. Pashkevich V. L. Saloutin N. A. Klyuev E. Kh. Dank 《Chemistry of Heterocyclic Compounds》1978,14(4):458-463
sym-Triazolo[3,4-b][1,2,4,5]tetraazepines were obtained by condensation of 4-amino-3-hydrazino-1,2,4-triazoline-5-thione with -dicarbonyl compounds, and 1-[4-amino-1,2,4-triazol-3-yl]-3,5-dialkylpyrazoles were obtained by condensation of the same thione with -dicarbonyl compounds.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 555–559, April, 1978. 相似文献
17.
Conclusions During the reaction of hydrazines and o-phenylenediamine with 2-halosubstituted (3-keto-esters, including fluoroalkyl substituted, two reaction paths are realized; substitution of the halogen atoms in position 2 by hydrogen and condensation with formation of various compounds depending on the structure of the starting -ketoester and dinucleophile.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2527–2535, November, 1987. 相似文献
18.
V. I. Saloutin M. I. Kodess A. N. Fomin S. I. Selivanov B. A. Ershov K. I. Pashkevich 《Russian Chemical Bulletin》1988,37(2):318-321
Conclusions By1H and19F NMR spectroscopy it was shown that reaction of fluoroalkyl -ketoesters with methylhydrazine in deuteromethanol at –30 to 30C involves intermediate formation of the -ketoester salts with methylhydrazine and 3,5-dioxypyrazolidines which successively split off methanol and H2O with formation of 3-oxypyrazolines and pyrazol-5-ones, respectively.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 399–402, February, 1988. 相似文献
19.
Bromination of -aminovinyl ketones (AVK) with geminal arrangement of the fluoroalkyl and amino groups gives N-bromo derivatives. Regioisomeric AVK with the amino groups in the -position relative to the fluoroalkyl group undergo bromination under analogous conditions to give a mixture of the -bromo and ,N-dibromo derivatives. -Bromo derivatives of AVK disproportionate upon storage.Division of Fine Chemical Synthesis, Institute of Organic Chemistry, Urals Branch, Russian Academy of Sciences, 620219 Ekaterinburg. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 746–749, March, 1992. 相似文献
20.
Il’inskii A. V. Kastro R. A. Pashkevich M. E. Shadrin E. B. 《Technical Physics》2019,64(12):1790-1795
Technical Physics - We have analyzed the dielectric spectra of thin (1200 Å) films of vanadium dioxide, a material with strong electron–electron correlations. We have tested both undoped... 相似文献