Dependence of calibration sensitivity of a polysulfone/Ru(II)-tris(4,7-diphenyl-1,10-phenanthroline)-based oxygen optical sensor on its structural parameters

The optimum performance of an optical oxygen sensor based on polysulfone (PSF)/[Ru(II)-Tris(4,7-diphenyl-1,10-phenanthroline)] octylsulfonate (Ru(dpp)OS) was checked by carefully tuning the parameters affecting the membrane preparation. In particular, membranes having thickness ranging between 0.2 and 8.0 μm with various luminophore concentrations were prepared by dip-coating and tested. The membrane thickness was controlled by tuning the solution viscosity, and was measured both by secondary ion mass spectrometry (SIMS) and by visible spectroscopy (Vis). Luminescence-quenching-based calibration was a single value of the Stern-Volmer constant (K^′SV) for membranes containing up to 20 mmol Ru(dpp) g⁻¹ PSF (1.35 μm average thickness). The K^′SV value decreased for larger concentration. The highest sensitivity was obtained with membrane thickness around 1.6 μm, having a response time close to 1 s. Thicker membranes exhibited an emission saturation effect and were characterized by longer response time. The K^′SV behavior was interpreted on the basis of a mathematical approach accounting for the contribution of luminescence lifetime (τ₀), oxygen diffusion coefficient (DO₂) and oxygen solubility inside the membrane (sO₂) establishing the role of all of them and allowing their experimental determination. Moreover, a simple experimental way to estimate K^′SV without needing calibration was proposed. It was based either on the light emission asymmetry or on the percent variation of light emission on passing from pure nitrogen to pure oxygen.     

Current development of analytical affinity chromatography: Design and biotechnological uses of molecular recognition surfaces

Analytical high performance liquid affinity chromatography (analytical HPLAC) has been investigated as an experimental guide to both synthetic design and affinity technological use of peptide and protein recognition surfaces. This work has progressed from the ongoing use of analytical affinity chromatography to study interaction mechanisms of naturally-occurring peptides and proteins, including enzyme fragment complexes and neuroendocrine biosynthetic precursors. We recently initiated a study to use analytical HPLAC for de novo design of recognition peptides called “anti-sense peptides”. Present data suggest the potential to use anti-sense peptides as “synthetic antibodies”, in immobilized forms, for biomolecular separation and analysis. Analogous studies have been started with immobilized natural antibodies in analytical immuno HPLAC. Our present data typify the growing usefulness of analytical HPLAC when designing recognition molecules, analyzing their interaction characteristics, and devising ways to use them in affinity technology.     

Noether symmetry approach in matter-dominated cosmology with variable G and Λ

In the framework of renormalization-group improved cosmologies, we use the Noether symmetry approach to get exact and general integration of the matter-dominated cosmological equations. This is performed by using an expression of Λ = Λ (G) determined by the method itself. We also work out a comparison between such a model and the concordance ΛCDM model as to the magnitude–redshift relationship, hence showing that no appreciable differences occur.     

Diversity enabling equilibration: disorder and the ground state in artificial spin ice

We report a novel approach to the question of whether and how the ground state can be achieved in square artificial spin ices where frustration is incomplete. We identify two sources of randomness that affect the approach to ground state: quenched disorder in the island response to fields and randomness in the sequence of driving fields. Numerical simulations show that quenched disorder can lead to final states with lower energy, and randomness in the sequence of driving fields always lowers the final energy attained by the system. We use a network picture to understand these two effects: disorder in island responses creates new dynamical pathways, and a random sequence of driving fields allows more pathways to be followed.     

Entropy and irreversibility for a single isolated two level system: New individual quantum states and new nonlinear equation of motion

We propose a new nonlinear equation of motion for a single isolated two-level quantum system. The resulting generalized two-level quantum dynamical theory entails a new alternative resolution of the long-standing dilemma on the nature of entropy and irreversibility. Even for a single isolated degree of freedom, in addition to the individual mechanical states for which all the results of conventional quantum mechanics remain valid, our theory implies the existence of new nonmechanical individual quantum states. These states have nonzero individual entropy and, by virtue of a constant-energy, internal redistribution mechanism, relax irreversibly toward stable equilibrium. We discuss the possibility of an experimental verification of these conclusions by means of a high-resolution, essentially single-particle, magnetic-resonance experiment.     

Smart panel with active damping units. Implementation of decentralized control

This paper contains the second part of a study on a smart panel with five decentralized velocity feedback control units using proof mass electrodynamic actuators [Gonzalez Diaz et al., J. Acoust. Soc. Am. 124, 886 (2008)]. The implementation of five decentralized control loops is analyzed, both theoretically and experimentally. The stability properties of the five decentralized control units have been assessed with the generalized Nyquist criterion by plotting the loci of the eigenvalues of the fully populated matrix of frequency response functions between the five error signals and five input signals to the amplifiers driving the actuators. The control performance properties have been assessed in terms of the spatially averaged response of the panel measured with a scanning laser vibrometer and the total sound power radiated measured in an anechoic room. The two analyses have shown that reductions of up to 10 dB in both vibration response and sound radiation are measured at low audio frequencies, below about 250 Hz.     

Supersonic cluster beam fabrication of metal–ionogel nanocomposites for soft robotics

Soft robotics is an emerging field targeting at the development of robotic bodies and architectures characterized by flexibility, adaptability, and motility typical of that of biological systems. The use of electroactive ionic polymer–metal nanocomposites able to reversibly deform in response to low-intensity electric fields constitutes a promising solution for the implementation of actuators into soft robots. Currently, the use of this class of nanocomposites is hampered by several drawbacks, mainly related to the mismatch between the mechanical properties of the polymer and the metallic electrodes compromising their stability and resilience upon cyclic deformation.Here, we report and discuss on the use of supersonic cluster beam implantation (SCBI) as an effective strategy for the fabrication of soft electroactive ionic polymeric nanocomposite actuators. SCBI relies on the use of supersonically accelerated beams of neutral metal nanoparticles that can be aerodynamically collimated and directed onto a polymeric target to generate thin nanostructured metal layers physically interpenetrating with the polymer.Soft electroactive actuators based on engineered ionogel and ionogel-based hybrid nanocomposites provided with monolithically integrated cluster-assembled gold electrodes will be discussed. These systems can undergo long-term bending deformation in a low-voltage regime, due to the nanostructured electrode resilience. The use of cluster-assembled nanostructured electrodes opens new opportunities for the high-throughput manufacturing of soft ionic actuators with excellent mechanical resiliency, high-performance actuation, and high durability.     

Biomolecular Release Stimulated by Electrochemical Signals at a Very Small Potential Applied

DNA release electrochemically stimulated by applying ?10 mV on the modified electrode was studied. The release process was based on the local (interfacial) pH change produced upon H₂O₂ reduction electrocatalyzed by the immobilized microperoxidase‐11. SiO₂ nanoparticles attached to the electrode surface and functionalized with trigonelline and boronic acid species changed their electrical charge from positive to negative upon the interfacial pH change, thus allowing electrostatic adsorption of negatively charged DNA on the positive interface and then its repulsion/release from the negative interface. The loaded/released DNA molecules were labeled with a fluorescent dye to allow easy detection of the released DNA molecules. The important feature of the developed system is the controlled DNA release upon applying very small electrical potential on the modified electrode.     

Bayesian Nonparametric Estimation for Reinforced Markov Renewal Processes

Starting from the definitions and the properties of reinforced renewal processes and reinforced Markov renewal processes, we characterize, via exchangeability and de Finetti’s representation theorem, a prior that consists of a family of Dirichlet distributions on the space of Markov transition matrices and beta-Stacy processes on distribution functions. Then, we show that this family is conjugate and give some estimate results.

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Two-Wavelet Localization Operators on $$ L^p(\mathbb{R}^n) $$ for the Weyl-Heisenberg Group

We give results on the boundedness and compactness of localization operators with two admissible wavelets on for the Weyl-Heisenberg group.