全文获取类型
收费全文 | 2530篇 |
免费 | 425篇 |
国内免费 | 531篇 |
专业分类
化学 | 2005篇 |
晶体学 | 24篇 |
力学 | 96篇 |
综合类 | 5篇 |
数学 | 360篇 |
物理学 | 996篇 |
出版年
2024年 | 3篇 |
2023年 | 58篇 |
2022年 | 95篇 |
2021年 | 97篇 |
2020年 | 111篇 |
2019年 | 83篇 |
2018年 | 78篇 |
2017年 | 89篇 |
2016年 | 123篇 |
2015年 | 119篇 |
2014年 | 128篇 |
2013年 | 229篇 |
2012年 | 235篇 |
2011年 | 244篇 |
2010年 | 155篇 |
2009年 | 157篇 |
2008年 | 195篇 |
2007年 | 189篇 |
2006年 | 167篇 |
2005年 | 117篇 |
2004年 | 92篇 |
2003年 | 75篇 |
2002年 | 65篇 |
2001年 | 60篇 |
2000年 | 53篇 |
1999年 | 50篇 |
1998年 | 33篇 |
1997年 | 30篇 |
1996年 | 45篇 |
1995年 | 42篇 |
1994年 | 40篇 |
1993年 | 32篇 |
1992年 | 28篇 |
1991年 | 34篇 |
1990年 | 26篇 |
1989年 | 15篇 |
1988年 | 16篇 |
1987年 | 13篇 |
1986年 | 11篇 |
1985年 | 10篇 |
1984年 | 11篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1968年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有3486条查询结果,搜索用时 31 毫秒
991.
Naphthalene-naphthalene, anthracene-anthracene, and naphthalene-anthracene assemblies 1.1, 2.2, and 1.2 linked by 2-ureido-4{1H}-pyrimidinone binding module were synthesized. Fluorescence quenching and lifetime measurements demonstrate that the inner-assembly singlet energy transfer from naphthalene to anthracene in 1.2 occurs with the efficiency of ca. 89% and rate constant of ca. 9.8 × 108 s−1. Föster energy transfer mechanism operates in this energy transfer process. 相似文献
992.
Park JG Langenwalter KJ Weinbaum CA Casey PJ Pang YP 《Journal of combinatorial chemistry》2004,6(3):407-413
The use of chlorotrityl resins for the immobilization of amines is sometimes deterred by the lengthy process of loading the reactants on the resins and product decomposition caused by the reactive chlorotrityl group in the presence of 1% TFA as a cleavage agent. Here, we report improved methods developed for selective and efficient loading of aminobenzoic acid derivatives on chlorotrityl resins and for cleavage of aniline-containing products from the resins without decomposition. These methods led to the synthesis of a library of 144 discrete chemicals as potential farnesyltransferase inhibitors (FTIs) using IRORI's radio-frequency-encoded sorting technique and to the study of the applicability of the bivalence approach to the development of FTIs. 相似文献
993.
[structure: see text] The first total synthesis of a molecule possessing the stereochemistry proposed for onchidin is described. The structure synthesized appears to be different from that of the marine natural product. 相似文献
994.
The morphology-dependent resonances (MDRs) in a dielectric sphere that contains many tiny inclusions are studied by use of a recently developed degenerate perturbation method. Degenerate MDRs in the sphere split into multiplets because of the loss of spherical symmetry and manifest themselves as broadened spectral lines in the scattering cross section. Furthermore, the distribution of MDRs in a multiplet is found to obey Wigner's semicircular theorem. 相似文献
995.
Zheng Jin-Yu Pang Jie-Bin Qiu Kun-Yuan Wei Yen 《Journal of Sol-Gel Science and Technology》2002,24(1):81-88
Mesoporous silica materials have been successfully prepared by employing a mixture of -cyclodextrin and urea as a template in a HCl-catalyzed sol-gel process, followed by extraction with water. The obtained materials are characterized by nitrogen adsorption-desorption measurements, powder X-ray diffraction patterns and transmission electron microscopy. The changes of the pore parameters depend on both the weight ratio of -cyclodextrin and urea and the template content in the final silica composite. The effects of the mixture as template (or pore-forming agent) on the physicochemical properties of the two synthesized systems, with different weight ratio and same template content, as well as varied template content and fixed weight ratio, were investigated in this paper. The results show that the hydrogen bonding interactions between -cyclodextrin and urea molecules or urea aggregates, the urea-holding -cyclodextrin molecules themselves as well as inorganic species are the driving force in the formation of mesoporous silica materials. 相似文献
996.
997.
998.
Li Guang-She Li Li-Ping R. L. SmithJr. H. Inomata 《Journal of Molecular Structure》2001,560(1-3):87-93
The structural development of the NiFe2O4 nanocrystals dispersed in a silica matrix was followed by IR and EPR spectroscopies of the dried gel 10NiO–10Fe2O3–90SiO2 after heat treatment. The dried gel obtained at 200°C was amorphous, in which Fe3+ and Ni2+ ions were distributed in the pores of silica matrix. When the dried gel was heat treated at 400°C, NiFe2O4 clusters were partially formed, showing an enhanced interaction with the silica matrix. NiFe2O4 clusters were completely formed in silica matrix when the heat treatment was increased to 600°C, at which the interactions between the clusters and silica matrix reached a maximum. The formation reaction of NiFe2O4 clusters was accompanied by a rearrangement of the silica matrix network. Further increase of the heat treatment temperature to 800°C led to superparamagnetic single domain NiFe2O4 nanocrystals (ca. 4 nm) dispersed in the silica matrix with the elimination of the interactions between magnetic nanocrystals and silica matrix. 相似文献
999.
1000.