<Emphasis Type="Italic">Tetra</Emphasis>-armed conjugated microporous polymers for gas adsorption and photocatalytic hydrogen evolution

Two novel tetra-armed conjugated microporous polymers with different geometries have been designed and synthesized via Suzuki-Miyaura cross coupling polycondensation. Both polymers are stable in various organic solvents tested and are thermally stable. The pyrene-containing polymer of PrPy with the rigid pyrene unit shows a higher Brunauer-Emmet-Teller specific surface area of 1219 m² g^?1 than the tetraphenylethylene-containing polymer of PrTPE (770 m² g^?1), which leads to a high CO₂ uptake ability of 3.89 mmol g^?1 at 1.13 bar/273 K and a H₂ uptake ability of 1.69 wt% at 1.13 bar/77 K. The photocatalytic hydrogen production experiments revealed that PrPy also shows a better photocatalytic performance than PrTPE due to the higher conjugation degree and planar structure, the broader UV-visible (UV-Vis) absorption, the lower photoluminescence lifetime, and the higher specific surface area.     

Encapsulation of RNA by negatively charged human serum albumin via physical interactions

Human serum albumin (HSA) is the most abundant plasma protein and has an inherent ability to target tumor cells. It is an excellent candidate for drug delivery. However, HSA cannot form complex with DNA or RNA, because it is negatively charged under physiological conditions. In this work, we reported a simple method to prepare HSA/RNA nanoparticles mainly by physical interaction. Firstly, the solution pH is adjusted to 4.0, under which condition HSA is positively charged. It forms complex with RNA via electrostatic interaction. The solution is then heated at 75 oC for 15 min to stabilize the structure and the size of the formed complex. The HSA/RNA nanoparticle prepared by this method has a diameter about 110 nm and a narrow distribution. It is also stable for days under physiological conditions. Cellular essays demonstrate that these particles exhibit a high cellular uptake efficiency and non-toxicity to HeLa cells.     

On the homomorphisms of power-set <Emphasis Type="Italic">Q</Emphasis>-algebras

We continue the study of homomorphisms between power-set Q-algebras. First, by means of decomposed ul-Q-relations between ordered semigroups we give a general characterization for the homomorphisms between power-set Q-algebras. Also, we consider a new category OSGRP whose objects are ordered semigroups and whose morphisms are decomposed ul-Q-relations, and discuss the relationship between the category OSGRP and the category Q-Alg of Q-algebras.     

TV‐like regularization for backward parabolic problems

This paper investigates an inverse problem for parabolic equations backward in time, which is solved by total‐variation‐like (TV‐like, in abbreviation) regularization method with cost function ∥u_x∥². The existence, uniqueness and stability estimate for the regularization problem are deduced in the linear case. For numerical illustration, the variational adjoint method, which presents a simple method to derive the gradient of the optimization functional, is introduced to reconstruct the unknown initial condition for both linear and nonlinear parabolic equations. The conjugate gradient method is used to iteratively search for the optimal approximation. Numerical results validate the feasibility and effectiveness of the proposed algorithm. Copyright © 2016 John Wiley & Sons, Ltd.     

The double-light-beam method in three-dimensional scattered-light photoelasticity

This paper presents a new scattered-light photoelasticity technique which may be called the double-light-beam measurement method. Principal-stress directions and relative retardations related to the principal-stress differences can be measured at any point within an ordinary three-dimensional photoelastic model by this method. This method does not need double loading and the quantities to be measured depend only on the relative light intensity. Moreover, the output signals alternate, providing improved accuracy and stability. If supported by an appropriate program-control and digital processing system, the double-light-beam method can be used to quickly determine the internal stress distribution in ordinary three-dimensional photoelastic models.     

SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION

A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane.     

Relationship between bearing capacity and depth of soft layer of paddy fields in South China

The bearing capacity of paddy field in South China was measured with a kind of penetrometer. A straight line relationship is valuable in summarizing the dependence of bearing capacity on depth of soft soil layer.     

An investigation on the lift force of a wing pitching in dynamic stall for a comfort control vessel

On the basis of a comfort control system for ocean vessels, the control forces and moments in the form of lift forces from active wings are of important interest. In an ocean vessel comfort control system, active wings or fins are commonly used and constantly adjust their angles of attack to produce optimal sea-keeping conditions. The unsteady nature of the flow field around a wing, and the behaviour of the generated lift force must be understood in order to optimize the comfort control system. This paper presents experimental data on the flow past a pitching wing, paying particular attention to the lagging effects between the fluid dynamic lift force and the motion of the wing at large angles of attack as a function of peak angle of attack and reduced frequency of oscillation. The range of motion investigated has been chosen according to the applicability of a comfort control wing surface. Numerical data is also included to aid explanation on some of the witnessed phenomena.     

基于数字图像的土、岩和混凝土内部结构定量分析和力学数值计算的研究进展

土、岩及混凝土是一种内部结构极其复杂的材料,内部细观组成和结构决定了它们在外力作用下内部应力和应变等物理场的分布状态,在很大程度上控制了它们的宏观力学响应和破坏机理和过程。自1995年以来,数字图像处理技术作为一种材料细观空间结构及几何形态的精确量测和数字表述手段快速地被应用于沥青混凝土、水泥混凝土、土和岩体材料细观结构定量分析中来。本文在研究相关文献的基础上,分析和研究了数字图像技术在土、岩及混凝土内部结构定量分析和力学数值计算中的发展过程和研究成果,内容包括:单个骨料颗粒形态特征定量分析;土、岩和混凝土内部结构定量分析;岩体结构定量分析中的应用;基于数字图像处理的土、岩和混凝土细观结构力学计算。在此基础上,本文进一步对数字图像技术在岩土领域中的应用进展及未来的发展趋势进行了探讨,认为数字图像作为一种空间分布测量手段和数字表述方法使得它具有巨大的潜力,特别是在岩土领域的纵深发展过程中,它可能实现考虑细微观结构性的岩土力学和工程分析和预测的、新的方法和理论。     

Nonlocal interaction of a dislocation with a crack

Summary Based on the classical stress analysis, the stress field of a screw dislocation near a semi-infinite crack is investigated by a conformal mapping method. The classical image force on the dislocation due to the crack is presented by the obtained classical image stress. To eliminate the singularity of the stress field at the crack tip, the nonlocal elasticity theory is adopted. A maximum of the image stress is found near the crack tip and the nonlocal image force is then acquired by the obtained nonlocal stress field. Both the stress and the image force show much difference from the classical ones and seem to be more reasonable physically.

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Nichtlokale Wechselwirkung zwischen einer Versetzung und einem Riß

Übersicht Basierend auf der klassischen Spannungsanalyse einer Schraubenversetzung neben einem halb-unendlichen Riß mittels einer konformen Abbildung wird die klassische Bildkraft auf die Schraubenversetzung als Folge des Risses vorgestellt. Um die Spannungssingularitäten neben der Rißspitze zu beseitigen, wird die nichtlokale Elastizitätstheorie herangezogen, mittels ihrer wird das Maximum der Spannung neben dem Riß gefunden und die nichtlokale Bildkraft ermittelt. Die Spannungen und die Bildkraft der nichtlokalen Elastizitätstheorie zeigen große Unterschiede gegenüber der klassischen Analyse und sind physikalisch vernünftiger.