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51.
Alim Mohammad A. Bak Tadeusz Atanacio Armand J. Ionescu Mihail Kennedy Brendan Price William S. Du Plessis Johan Pourmahdavi Maryam Zhou Meifang Torres Allan Nowotny Janusz 《Ionics》2017,23(12):3517-3531
Ionics - This work reports the effect of tantalum (0.1–1 at.% Ta) on the photocatalytic performance of TiO2 annealed at 1373 and 1673 K in air. It was shown that addition of... 相似文献
52.
M. A. Idris Z. A. Z. Jamal S. B. Jamaludin N. Nafarizal A. K. Othman M. Z. Sahdan M. P. Zakaria M. Ionescu J. Nowotny 《Ionics》2014,20(4):581-592
The present work considers the application of oxide semiconductors in the conversion of solar energy into the chemical energy required for water purification (removal of microbial cells and toxic organic compounds from water) and the generation of solar hydrogen fuel by photoelectrochemical water splitting. The first part of this work considers the concept of solar energy conversion by oxide semiconductors and the key performance-related properties, including electronic structure, charge transport, flat band potential and surface properties, which are responsible to the reactivity and photoreactivity of oxides with water. The performance of oxide systems for solar energy conversion is briefly considered in terms of an electronic factor. The progress of research in the formation of systems with high performance is considered in terms of specific aspects of nanotechnology, leading to the formation of systems with high performance. The nanotechnology approach in the development of high-performance photocatalysts is considered in terms of the effect of surface energy associated with the formation of nanostructured system on the formation of surface structures that exhibit outstanding properties. The unresolved problems that should be tackled in better understanding of the effect of nanostructures on properties and performance of oxide semiconductors in solar energy conversion are discussed. This part is summarised by a list of unresolved problems of crucial importance in the formation of systems with enhanced performance. This work also formulates the questions that must be addressed in order to overcome the hurdles in the formation of oxide semiconductors with high performance in water purification and the generation of solar fuel. The research strategy in the development of oxide systems with high performance, including photocatalysts for solar water purification and photoelectrodes for photoelectrochemical water splitting, is considered. The considerations are focused on the systems based on titanium dioxide of different defect disorder as well as its solid solutions and composites. 相似文献
53.
Emine Kayhan Ravi Mohan Prasad Dr. Alexander Gurlo Dr. Oktay Yilmazoglu Dr. Jörg Engstler Dr. Emanuel Ionescu Songhak Yoon Prof. Dr. Anke Weidenkaff Prof. Dr. Jörg J. Schneider 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(47):14996-15003
Low‐layered, transparent graphene is accessible by a chemical vapor deposition (CVD) technique on a Ni‐catalyst layer, which is deposited on a <100> silicon substrate. The number of graphene layers on the substrate is controlled by the grain boundaries in the Ni‐catalyst layer and can be studied by micro Raman analysis. Electrical studies showed a sheet resistance (Rsheet) of approximately 1435 Ω per □, a contact resistance (Rc) of about 127 Ω, and a specific contact resistance (Rsc) of approximately 2.8×10?4 Ω cm2 for the CVD graphene samples. Transistor output characteristics for the graphene sample demonstrated linear current/voltage behavior. A current versus voltage (Ids–Vds) plot clearly indicates a p‐conducting characteristic of the synthesized graphene. Gas‐sensor measurements revealed a high sensor activity of the low‐layer graphene material towards H2 and CO. At 300 °C, a sensor response of approximately 29 towards low H2 concentrations (1 vol %) was observed, which is by a factor of four higher than recently reported. 相似文献
54.
Manickam Minakshi Pritam Singh David Ralph Dominique Appadoo Mark Blackford Mihail Ionescu 《Ionics》2012,18(6):583-590
The structural characteristics of olivine-type lithium orthophosphate Li(Mg0.5Ni0.5)PO4 synthesized via solid-state reaction have been studied using X-ray diffraction, ion beam technique, scanning electron microscopy, infrared spectroscopy, transmission electron microscopy and energy dispersive X-ray analysis. The parent LiNiPO4 compound can be synthesized in olivine structure without any evidence of secondary phases as impurities. The structural quality of the parent LiNiPO4 in the absence of secondary component phases resulted in the formation of hexagonal closed packed structure. The olivine analogue compound containing mixed M (M?=?Mg, Ni) cations, Li(Mg0.5Ni0.5)PO4 contained Li3PO4 as a second phase upon synthesis, however a carbothermal reduction method produced a single-phase compound. The redox behaviour of carbon-coated Li(Mg0.5Ni0.5)PO4 cathode in aqueous lithium hydroxide as the electrolyte showed reversible lithium intercalation. 相似文献
55.
Delia Ionescu 《PAMM》2006,6(1):813-814
A new approach to nonlinear RLC circuits, which is based on the geometric Birkhoffian formalism, is described in this note. The configuration space and a special Pfaffian form, called Birkhoffian, are obtained from the constitutive relations of the involved resistors, inductors and capacitors and from Kirchhoff's laws. No assumptions are placed upon the topology of the network. Properties of the corresponding Birkhoffian such as its regularity, or its dissipativeness, are discussed in this context. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
56.
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58.
Mariana Stoica Monica Caldararu Alice Capritza N. I. Ionescu 《Reaction Kinetics and Catalysis Letters》1997,60(1):65-70
The transient surface behavior on oxidation and reduction of a partially oxidized alumina-supported platinum catalyst containing
residual water have been observed by AC electrical conductance (G) measurements. 相似文献
59.
The Gravitational Field of an Electrically Charged Mass Point and the Causality Principle in the RTG
We find the effective Riemannian space–time corresponding to the gravitational field generated by a charged mass point in the framework of the relativistic theory of gravity. The causality principle plays an important role in solving this problem. The analytic form and the domain of definition, i.e., the gravitational radius, of the obtained solution differ from the corresponding results in Einstein's general relativity theory. 相似文献
60.
Gianina Dobrescu Daniela Berger Florica Papa N. I. Ionescu 《Applied Surface Science》2003,220(1-4):154-158
Fractal dimensions of three different samples of lanthanum ferrite were computed using single adsorption method. The fractal Dubinin–Radushkevitch isotherm was used to fit directly the experimental nitrogen adsorption data. Avnir–Jaroniec method for fractal dimension determination was also used. Low and intermediate fractal dimensions were obtained according to BET specific surface areas. 相似文献