全文获取类型
收费全文 | 1935篇 |
免费 | 61篇 |
国内免费 | 3篇 |
专业分类
化学 | 1254篇 |
晶体学 | 20篇 |
力学 | 49篇 |
数学 | 171篇 |
物理学 | 505篇 |
出版年
2023年 | 21篇 |
2022年 | 27篇 |
2021年 | 22篇 |
2020年 | 42篇 |
2019年 | 37篇 |
2018年 | 36篇 |
2017年 | 40篇 |
2016年 | 53篇 |
2015年 | 57篇 |
2014年 | 74篇 |
2013年 | 129篇 |
2012年 | 147篇 |
2011年 | 157篇 |
2010年 | 105篇 |
2009年 | 87篇 |
2008年 | 115篇 |
2007年 | 119篇 |
2006年 | 92篇 |
2005年 | 86篇 |
2004年 | 57篇 |
2003年 | 51篇 |
2002年 | 36篇 |
2001年 | 24篇 |
2000年 | 21篇 |
1999年 | 29篇 |
1998年 | 16篇 |
1997年 | 13篇 |
1996年 | 11篇 |
1995年 | 13篇 |
1994年 | 17篇 |
1993年 | 13篇 |
1992年 | 21篇 |
1991年 | 14篇 |
1990年 | 11篇 |
1989年 | 13篇 |
1988年 | 13篇 |
1987年 | 16篇 |
1986年 | 6篇 |
1985年 | 17篇 |
1984年 | 16篇 |
1983年 | 11篇 |
1982年 | 16篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 8篇 |
1976年 | 7篇 |
1975年 | 9篇 |
1974年 | 7篇 |
1973年 | 6篇 |
排序方式: 共有1999条查询结果,搜索用时 15 毫秒
131.
132.
U.?Pal J.F.?Sanchez Ramirez H.B.?Liu A.?Medina J.A.?AscencioEmail author 《Applied Physics A: Materials Science & Processing》2004,79(1):79-84
The synthesis of bimetallic nanoparticles has become so important in recent times due to its multi-faceted applications. The structure of the synthesised particles influences directly their properties. In this paper, we report the synthesis of Au/Cu nanoparticles by a simultaneous reduction method, considering three different molar concentrations (AuCu, AuCu3 and Au3Cu) of the components. In order to determine the size and structure of the obtained clusters, the particles were examined by optical spectroscopy, transmission electron microscopy and high-resolution transmission electron microscopy. One of the major factors, the minimum bimetal formation energy, was calculated by an embedded-atom method. The relation between the Au/Cu proportions has been demonstrated to affect the size of the particles and the corresponding structures. From the basic structural analysis it is found that the particles were fcc-like, multiple twin or multiple defect particles for the different Au/Cu concentrations. The smallest particles were identified for the Au/Cu sample with 50% of each, and the most crystalline structures were also obtained in the same sample. PACS 61.46.+w; 61.16.-d; 31.15.Qg 相似文献
133.
Synthesis of nanometer-sized particles with new physical properties is an area of tremendous interest. In metal particles, the changes in size modify the electron density in the particles, which shifts the plasmon band. The most significant size effects occur when the particles are ultrafine (size is <10 nm). Thus the synthesis of ultrafine metal particles is enormously important to exploit their unique and selective application. Here we report a novel method for the synthesis of ultrafine gold particles in the size range of 0.5–3 nm using dopamine hydrochloride (dhc), an important neurotransmitter. This is the first time where such an important bioactive molecule like dhc has been used as a reagent for the transformation of Au(III) to Au(0). The synthesis is carried out, for the first time, either in simple aqueous or in a nonionic micellar (for example Triton X-100 (TX-100)) medium. The gold sol has a beautiful yellow–brown color showing max at 470 nm. The appearance of the absorption peak at substantially shorter wavelength (usually gold sol absorbs at 520 nm) indicates that the particles are very small. The method discussed here is very simple, reproducible and does not involve any reagent, which contains 'P' or 'S' atoms. Also in this case no polymer or dendrimer or thiol-related stabilizer is used. The effects of different parameters (such as the presence or absence of O2, temperature, TX-100 concentration and dhc concentration) on the formation of ultrafine gold particles are discussed. The effects of 3-mercapto propionic acid and pyridine on the ultrafine gold sol are also studied and compared with those on photochemically prepared gold sol. It is observed that 3-mercapto propionic acid dampens the plasmon absorption at 470 nm of ultrafine gold particles. Pyridine, on the other hand, has no effect on the particles. 相似文献
134.
Nagarajan K Joshi HK Chaudhury PK Pal K Cooney JJ Enemark JH Sarkar S 《Inorganic chemistry》2004,43(15):4532-4533
Synthesis of [PPh4]2[Mo(SPh)2(S2C2(CN)2)2] (2) from [PPh4]2[MoO(S2C2(CN)2)2] (1) has been achieved to mimic the postulated [Mo(S)6] core of polysulfide reductase with two thiolates and two bis(ene-dithiolate) ligands. Compound 2 reacts with polysulfide to yield H2S, modeling the function of polysulfide reductase. The facile conversion of 2 back to 1 in moist solvent suggests that the interconversion of the [MoIV = O] and [MoIV - X] (X = O-Ser, S-Cys, Se-Cys) moieties might occur in the DMSO reductase class of enzymes under appropriate hydrophobic/hydrophilic conditions. 相似文献
135.
A solution phase UV-irradiation technique has been exploited to produce an AuSe nanoalloy through fusion of preformed Au (photoproduced) and Se (chemically prepared) in a micellar (TX-100) medium. 相似文献
136.
Anita Saha Madhumangal Pal Tapan K. Pal 《Journal of Mathematical Modelling and Algorithms》2003,2(4):407-409
Volume Contents
Contents of Volume 2 (2003) 相似文献137.
138.
Studies on CdS nanoparticles dispersed in silica matrix prepared by sol-gel technique 总被引:2,自引:0,他引:2
B. Bhattacharjee S.K. Bera D. Ganguli S. Chaudhuri A.K. Pal 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,31(1):3-9
SiO2/CdS-nanoparticle composite films (SiO2:CdS=85:15, 80:20, 75:25 and 70:30) were prepared by the sol-gel route. The films were characterized by studying microstructural
(XRD and TEM) and optical (transmittance and photoluminescence) properties. Band gaps of these films annealed at different
temperatures (373-473 K) for different times (10-120 min) indicated that the signature of nanocrystallinity is retained throughout
the range of our experimental conditions. A thermal diffusion process controlled growth in the crystallite size with increasing
annealing time and temperature. The average radii of the nanoparticles varied as the cube root of the annealing time but showed
exponential dependence on the inverse of annealing temperature. Photoluminescence (PL) studies of the composite films indicated
excitonic transitions. Theoretical analysis of the line shapes of the PL peaks recorded at 300 K and 80 K could be accounted
for by the combined effects of size distribution and phonon broadening. It was observed that the deformation potential (E
d) effectively controlled the line shapes of the PL measurements.
Received 24 May 2002 Published online 27 January 2003
RID="a"
ID="a"e-mail: msakp@mahendra.iacs.res.in 相似文献
139.
A di(-oxo)-bridged dinuclear complex, [VO2(pamh)]2 was isolated by reacting bis(acetylacetonato)vanadium(IV) and the Schiff base, N-(anisoyl)-N-(picolinylidene)-hydrazine (Hpamh) in acetonitrile. The complex crystallizes in the space group
;1; (#2) on crystallographic inversion center. Crystal data: a = 8.2202(12) Å, b = 9.8389(19) Å, c = 10.1907(17) Å, = 68.245(15)°, = 74.47(2)°, = 66.710(19)°, V = 696.0(2) Å3, and Z = 1. The physical properties of the complex and the structural parameters are consistent with the +5 oxidation state of the metal ions. The monomeric VO2(pamh) unit is square-pyramidal. The planar mononegative ligand (pamh–) coordinates the metal ion via the pyridine-N, the imine-N, and the amide-O atoms. One of the oxo groups completes the NNOO basal plane and also participates in the Vndash;Ondash ;V bridge formation. The other oxo group satisfies the fifth apical coordination site. The molecular structure of the dimeric complex, [VO2(pamh)]2 can be described as two edge-shared distorted VO4N2 octahedra. 相似文献
140.
A 100 MWt reactor design has been conceived to support flux level of the order of 1015 n/cm2/s in selected flux trap zones. The physics design considers high enriched metallic alloy fuel in the form of annular plates
placed in a D2O moderator tank in a hexagonal lattice arrangement. By choosing a tight lattice pitch in the central region and double the
lattice pitch in the outer region, it is possible to have both high fast flux and thermal flux trap zones. By design the flux
level in the seed fuel has been kept lower than in the high flux trap zones so that the burning rate of the seed is reduced.
Another important objective of the design is to maximize the time interval of refueling. As against a typical refueling interval
of a few weeks in such high flux reactor cores, it is desired to maximize this period to as much as six months or even one
year. This is possible to achieve by eliminating the conventional control absorbers and replacing them with a suitable amount
of fertile material loading in the reactor. Requisite number of seedless thorium-aluminum alloy plates are placed at regular
lattice locations vacated by seed fuel in alternate fuel layers. It is seen that these thorium plates are capable of acquiring
asymptotic fissile content of 14 g/kg in about 100 days of irradiation at a flux level of 8 × 1014 n/cm2/s. In summary, the core has a relatively higher fast flux in the central region and high thermal flux in the outer region.
The present physics design envisages a flat core excess reactivity for the longest possible cycle length of 6 months to one
year. It is also possible to modify the design for constant subcriticality for about the same period or longer duration by
considering neutron spallation source at the centre and curtailing the power density in the inner core region by shielding
it with a layer of thoria fuel loading.
相似文献