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391.
Chan HB Marcet Z Woo K Tanner DB Carr DW Bower JE Cirelli RA Ferry E Klemens F Miner J Pai CS Taylor JA 《Optics letters》2006,31(4):516-518
We present measurements of transmission of infrared radiation through double-layer metallic grating structures. Each metal layer contains an array of subwavelength slits and supports transmission resonance in the absence of the other layer. The two metal layers are fabricated in close proximity to allow coupling of the evanescent field on individual layers. The transmission of the double layer is found to be surprisingly large at particular wavelengths, even when no direct line of sight exists through the structure as a result of the lateral shifts between the two layers. We perform numerical simulations using rigorous coupled wave analysis to explain the strong dependence of the peak transmission on the lateral shift between the metal layers. 相似文献
392.
It is crucial for fundamental physical chemistry techniques to find their application in tackling real-world challenges. Hitherto, Raman optical activity (ROA) spectroscopy is one of the examples where a promising future within the pharmaceutical sector is foreseen, but has not yet been established. Namely, the technique is believed to be able to contribute in investigating the conformational behaviour of drug candidates. We, herein, strive towards the alignment of the ROA analysis outcome and the pharmaceutical expectations by proposing a fresh strategy that ensures a more complete, reliable, and transferable ROA study. The strategy consists of the treatment of the conformational space by means of a principal component analysis (PCA) and a clustering algorithm, succeeded by a thorough ROA spectral analysis and a novel way of estimating the contributions of the different chemical fragments to the total ROA spectral intensities. Here, vancomycin, an antibiotic glycopeptide, has been treated; it is the first antibiotic glycopeptide studied by means of ROA and is a challenging compound in ROA terms. By applying our approach we discover that ROA is capable of independently identifying the correct conformation of vancomycin in aqueous solution. In addition, we have a clear idea of what ROA can and cannot tell us regarding glycopeptides. Finally, the glycopeptide class turns out to be a spectroscopically curious case, as its spectral responses are unlike the typical ROA spectral responses of peptides and carbohydrates. This preludes future ROA studies of this intriguing molecular class.Raman optical activity tackles the complex conformational space of glycopeptide antibiotics. 相似文献
393.
I.G. Bearden H. Bøggild J. Boissevain P.H.L. Christiansen L. Conin J. Dodd B. Erazmus S. Esumi C.W. Fabjan D. Ferenc A. Franz J.J. Gaardhøje A.G. Hansen O. Hansen D. Hardtke H. van Hecke E.B. Holzer T.J. Humanic P. Hummel B.V. Jacak K. Kaimi M. Kaneta T. Kohama M. Kopytine M. Leltchouk A. Ljubičić Jr. B. Lörstad N. Maeda L. Martin A. Medvedev M. Murray H. Ohnishi G. Paić S.U. Pandey F. Piuz J. Pluta V. Polychronakos M. Potekhin G. Poulard D. Reichhold A. Sakaguchi J. Schmidt-Sørensen J. Simon-Gillo W. Sondheim T. Sugitate J.P. Sullivan Y. Sumi W.J. Willis K. Wolf N. Xu D.S. Zachary 《The European Physical Journal C - Particles and Fields》2000,18(2):317-325
Two-particle correlations of negative pions as a function of charged particle multiplicity are studied in Pb+Pb collisions
at GeV per nucleon using the NA44 experiment at the CERN Super Proton Synchrotron(SPS). We find that the source size parameters
increase with the charged particle multiplicity. However the slope of the source size parameters plotted as a function of
charged multiplicity is slightly larger at high multiplicity than at low multiplicity. The value of is independent of charged multiplicity. For Pb+Pb collisions, is larger than and for all multiplicity intervals, whereas these three radius parameters were approximately equal in S+Nucleus collisions. The
ratios () and () for Pb+Pb data show almost no dependence on charged multiplicity. The duration of pion emission is constant at 3.81.1 fm/c as a function of the charged multiplicity in Pb+Pb collisions. Effective volume (V) is also calculated as V=, assuming a cylindrically shaped source. We found, within the limited statistics, the effective volume rapidly increases
at high multiplicity.
Received: 17 July 2000 / Revised version: 3 November 2000 / Published online: 8 December 2000 相似文献
394.
A. Pai S. V. Dhurandhar P. Hello J. -Y. Vinet 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,8(3):333-346
The large scale interferometric gravitational wave detectors consist of Fabry-Perot cavities operating at very high powers
ranging from tens of kW to MW for next generations. The high powers may result in several nonlinear effects which would affect
the performance of the detector. In this paper, we investigate the effects of radiation pressure, which tend to displace the
mirrors from their resonant position resulting in the detuning of the cavity. We observe a remarkable effect, namely, that
the freely hanging mirrors gain energy continuously and swing with increasing amplitude. It is found that the “time delay”,
that is, the time taken for the field to adjust to its instantaneous equilibrium value, when the mirrors are in motion, is
responsible for this effect. This effect is likely to be important in the optimal operation of the full-scale interferometers
such as VIRGO and LIGO.
Received 12 July 1999 相似文献
395.
396.
用化学方法制备出La2/3Ca1/3MnO3/TE(TE=Cu、Fe和Zn)复合颗粒系统,并通过零场和外加低磁场(0.3 T)下电阻率(ρ)随温度(T)变化关系测量对这些复合系统的输运和低场磁电阻行为进行了比较性研究.相对于纯La2/3Ca1/3MnO3颗粒系统,Cu引入后,绝缘体-金属转变温度(TIM)降低,ρ减小,ρ(T)曲线表现出明显的热滞豫现象,磁电阻(MR)在转变温度附近表现出峰行为且峰值处的MR值高达~35%.引入Fe后,TIM升高,电阻率减小,但MR随T降低而单调增加.引入Zn后,TIM降低,ρ增加,在TIM附近也出现MR峰但峰值较小.同时,也注意到,在含Fe和Zn的系统中都没有观察到明显的热滞豫现象. 相似文献
397.
Forecasting concentrations of air pollutants by logarithm support vector regression with immune algorithms 总被引:2,自引:0,他引:2
Kuo-Ping LinPing-Feng Pai Shun-Ling Yang 《Applied mathematics and computation》2011,217(12):5318-5327
The need to minimize the potential impact of air pollutants on humans has made the accurate prediction of concentrations of air pollutants a crucial subject in environmental research. Support vector regression (SVR) models have been successfully employed to solve time series problems in many fields. The use of SVR models for forecasting concentrations of air pollutants has not been widely investigated. Data preprocessing procedures and the parameter selection of SVR models can radically influence forecasting performance. This study proposes a support vector regression with logarithm preprocessing procedure and immune algorithms (SVRLIA) model which takes advantage of the structural risk minimization of SVR models, the data smoothing of preprocessing procedures, and the optimization of immune algorithms, in order to more accurately forecast concentrations of air pollutants. Three pollutants, namely particulate matter (PM10), nitrogen oxide, (NOx), and nitrogen dioxide (NO2), are collected and examined to determine the feasibility of the developed SVRLIA model. Experimental results reveal that the SVRLIA model can accurately forecast concentrations of air pollutants. 相似文献
398.
399.
多孔材料因具有轻量化、高孔隙率和减振/散热等优良多物理特性,在航空航天等领域具有广阔应用前景。采用拓扑优化方法对含多种多孔材料的结构进行结构与材料微结构构型一体化设计,有助于获得具有优良力学性能的结构设计。然而,传统逆均匀化微结构设计方法无法确保不同多孔材料微结构之间的连接性,设计结果不具备可制造性。本文面向含多种多孔材料的双尺度结构基频最大化设计问题,考虑不同微结构之间的连接性,协同设计多孔材料的微结构构型及其在宏观尺度下的布局。采用均匀化方法计算多孔材料的宏观等效力学性能,通过对不同多孔材料微结构单胞的边界区域采用相同的拓扑描述确保双尺度优化过程中任意空间排布下不同微结构的连接性,并通过优化算法确定微结构间的连接形式及微结构拓扑。在宏观尺度,提出结合离散材料插值模型和RAMP插值模型RAMP (Rational Approximation of Material Properties)的多孔材料各向异性宏观等效刚度及质量插值模型,获得清晰的多孔材料宏观尺度布局并减轻优化过程中伪振动模态的影响。建立以双尺度结构基频最大化为目标,以材料用量为约束的优化列式,推导灵敏度表达式,并基于梯度优化算法求解双尺度结构拓扑优化问题。数值算例表明,采用本文优化方法能够有效确保基频最大化双尺度结构设计中不同多孔材料微结构之间的连接性,增强优化设计结果的可制造性。 相似文献