一种大视场相位测量轮廓术系统标定方法

在进行大视场相位测量轮廓术系统参量标定时需要大的标定平面和精密移动台,由于携带不方便,不易进行现场标定。提出了一种用于相位测量轮廓术系统参量的高精度、现场标定方法,采用一块较小的平面标定靶在有效测量体积内不同位置多次摆放,以获取密集的数据点。先标定出摄像机的内参量和外参量,再指定一个全局参考平面和若干辅助参考平面,然后在图像平面上分区计算出每个位置标定靶上每点相对辅助参考平面的高度差和相位差,最后应用极大似然估计法估计出相位高度映射参量。实验中平面高度测量的标准偏差达到0.0433 mm。这种方法只需要较小的平面标定靶,标定过程方便、精度高,完全适合大视场三维测量相位测量轮廓术系统现场标定要求。     

Time-dependent density functional theory molecular dynamics simulation of doubly charged uracil in gas phase

We use time-dependent density functional theory and Born-Oppenheimer molecular dynamics methods to investigate the fragmentation of doubly ionized uracil in gas phase. Different initial electronic excited states of the dication are obtained by removing electrons from different inner-shell orbitals of the neutral species. We show that shape-equivalent orbitals lead to very different fragmentation patterns revealing the importance of the intramolecular chemical environment. The results are in good agreement with ionion coincidence measurements of uracil collision with 100 keV protons.     

First-principles investigation of chemical modification on two-dimensional iron–phthalocyanine sheet

Successful synthesis of single iron–phthalocyanie(FePc) framework layer on substrate and its transferrable properties open the door for decorating the separately distributed transition metals for exploring the diverse properties. We have studied the effects of chemical modification on two-dimensional FePc organometallic framework with density functional theory. For simplicity, the non-metal atoms with variant valence electrons are used as prototypes to estimate the effects from chemical modifications with different functional groups. The thermo-stabilities of the non-metal atom decorated complex sheet materials have been estimated by the first-principles constant energy molecular dynamic simulations. Upon the nonmetal atom adsorption, the magnetic moment could be changed from 2 μBto 0, 1, 2, and 3 μBper unit cell for the case of tetra-, penta-, hexa-, and hepta-valent non-metal modifications, respectively, showing interesting promise to tailor its magnetic properties for potential applications.     

偶极子在径向非均匀介质中的电磁场分布

提出了柱状多层介质中的磁偶极子在任意介质层中的电磁场的递推算法，给出了磁偶极子产生的电磁波在柱状多层介质中的反射、透射系数和广义反射系数，从而得到了任意介质层中满足各层界面边界条件的电磁场解析表达式．     

Experimental confirmation of a new reversed butterfly-shaped attractor

This paper reports a new reverse butterfly-shaped chaotic attractor and its experimental confirmation. Some basic dynamical properties, and chaotic behaviours of this new reverse butterfly attractor are studied. Simulation results support brief theoretical derivations. Furthermore, the system is experimentally confirmed by a simple electronic circuit.     

Rotation selectivity of random phase encoding in volume holograms

We present the study of angular selectivity for holographic multiplexing based on random phase encoding by a ground glass. The rotational selectivity of the volume hologram is calculated theoretically and coincides with the experimental measurement. By controlling the parameters including rotational center, effective numerical aperture of both volume hologram and the ground glass, we can obtain different rotational selectivity applied to random phase encoding in volume holographic storage.     

Study on improving output capability of high-power lasers providing short pulses by using different laser glasses together in the amplifier chain

We have discussed the optical and laser properties of different laser glass types. According to the properties of the gain and the B integral in the high-power laser amplifier chain, an optimal configuration is pointed out to improve the output capability at short pulses based on reducing nonlinear refractive index n₂. In this way, high gain glasses and low n₂ glasses are used in different amplifier stages simultaneously. The simulated results show that on the condition that the maximal output energies of both the configurations are same at 3 and 5 ns, the maximal output capability growth ratio of 30.48% () and 42.24% () for the optimal configuration can be obtained at 1 ns, respectively.     

Imaging in turbid media with intensity-modulated lasers

We describe the formation of a narrow beam for intensity-modulated electromagnetic radiation propagating through highly scattering materials. We propose to use this beam to reconstruct images, similar to X-ray back-projection techniques. For sufficiently high modulation frequency, the photon density wave is primarily carried by photons that suffer small or no large-angle scattering, which gives rise to the beam’s narrow divergence. The beam-narrowing concept is supported by large-scale numerical simulations to examine the quality of the imaging.     

Quantitative analysis of thin samples by differential absorption imaging using a laser-plasma soft X-ray source

We consider the application of the differential absorption imaging technique in the soft X-ray region. The surface-density maps of test samples containing bromine, resulting from the application of the differential absorption imaging technique, are presented. Images of the samples were obtained in an X-ray monochromatic projection imaging scheme based on a spherically bent crystal using line emission close to the $L_2$ edge of bromine from a microplasma produced by focusing a nanosecond laser on the surface of an aluminum target.     

Extraction of local coordination structure in a low‐concentration uranyl system by XANES

Obtaining structural information of uranyl species at an atomic/molecular scale is a critical step to control and predict their physical and chemical properties. To obtain such information, experimental and theoretical L₃‐edge X‐ray absorption near‐edge structure (XANES) spectra of uranium were studied systematically for uranyl complexes. It was demonstrated that the bond lengths (R) in the uranyl species and relative energy positions (ΔE) of the XANES were determined as follows: ΔE₁ = 168.3/R(U—O_ax)² ? 38.5 (for the axial plane) and ΔE₂ = 428.4/R(U—O_eq)² ? 37.1 (for the equatorial plane). These formulae could be used to directly extract the distances between the uranium absorber and oxygen ligand atoms in the axial and equatorial planes of uranyl ions based on the U L₃‐edge XANES experimental data. In addition, the relative weights were estimated for each configuration derived from the water molecule and nitrate ligand based on the obtained average equatorial coordination bond lengths in a series of uranyl nitrate complexes with progressively varied nitrate concentrations. Results obtained from XANES analysis were identical to that from extended X‐ray absorption fine‐structure (EXAFS) analysis. XANES analysis is applicable to ubiquitous uranyl–ligand complexes, such as the uranyl–carbonate complex. Most importantly, the XANES research method could be extended to low‐concentration uranyl systems, as indicated by the results of the uranyl–amidoximate complex (～40 p.p.m. uranium). Quantitative XANES analysis, a reliable and straightforward method, provides a simplified approach applied to the structural chemistry of actinides.