Resonances in low-energy rare-gas atom scattering

Precise values of energies and widths of low-lying resonances in some rare-gas atom systems (Ar-Ar, Ne-Kr, Ne-Xe) are reported.     

Influence of a background gas on expanding plasma clots

An expansion of finite plasma clots into the background neutral gas is studied numerically. The presented model includes the quasineutrality violation as well as the interpenetration of plasma and neutral gas at the boundary of the plasma. We estimate the region of plasma parameters where the model is correct. Space distributions of main plasma parameters, cooling of electrons and the process of inter-penetration of the plasma and the neutral gas are analysed as well as an empiric formula for electron temperature is found. Finally, it is shown that the most intensive plasma-gas inter-penetration occurs in the case where the initial plasma and gas densities are the same.     

Labelings of two classes of plane graphs

The paper describes magic labelings of type (1,1,1) for two classes of graphs, which are obtained by a combination of vertex, edge and face labelings.     

Effect of particle geometry on phase transitions in two-dimensional liquid crystals

Using a version of density-functional theory which combines Onsager approximation and fundamental-measure theory for spatially nonuniform phases, we have studied the phase diagram of freely rotating hard rectangles and hard discorectangles. We find profound differences in the phase behavior of these models, which can be attributed to their different packing properties. Interestingly, bimodal orientational distribution functions are found in the nematic phase of hard rectangles, which cause a certain degree of biaxial order, albeit metastable with respect to spatially ordered phases. This feature is absent in discorectangles, which always show unimodal behavior. This result may be relevant in the light of recent experimental results which have confirmed the existence of biaxial phases. We expect that some perturbation of the particle shapes (either a certain degree of polydispersity or even bimodal dispersity in the aspect ratios) may actually destabilize spatially ordered phases thereby stabilizing the biaxial phase.     

The ETACS European project for testing the comparability of sensors and analysers

ETACS is the official acronym for the European project "European Testing and Assessment of Comparability of On-line Sensors/Analysers". This project has three main objectives to achieve the comparability of performance data for sensors and analysers in the environmental field. First, to develop a test protocol for validation and comparison of the performance of on-line sensors/analysers. The test protocol is intended to be generic, that is independent of the specific sensors/analysers and the specific parameters to be monitored. Second, the practical testing of this test protocol to assess its applicability and to develop the techniques used. Finally, to achieve widespread acceptance of the test protocol by producer/suppliers, users and relevant authorities to assist its early adoption as an agreed European standard. Laboratory tests for producing the test protocol have been carried out and completed to check the applicability of such a protocol.     

Chronocoulometry of tris-2,2′-bipyridine cobalt(II) and related transition metal complexes

Integrated pulse polarography and similar techniques have been used for study of reduction of bipyridine complexes of Co(II), Ni(II) and partially also Fe(II) in aqueous solutions. By proper choice of pulse and detection intervals, it is possible to confirm or separate the contribution of reactant adsorption. The pulse polarography of the product reoxidation shows a finite charge transfer rate in the case of tris-2,2′-bipyridine cobalt complex.