Behavior of 2-nitroso-4-nitropropiophenone under conditions of cyclization to haloanthranils

The cyclization of 2-nitroso-4-nitropropiophenone under the influence of hydrogen chloride proceeds in a more complex manner than in the cases previously described for other 4-substituted-2-nitrosopropiophenones: three, rather than two, haloanthranils are formed, and their formation is accompanied simultaneously by a number of redox transformations. This fact is explained by a decrease in the ability of the carbonyl group in the investigated ketone to undergo protonation.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1334–1337, October, 1976.     

Structure of ammonium salts of 2-oxy-1,4-butylene-and 2-oxy-1,5-amylenephosphoric acids

The structures of dioxaphosphepane (I) and dioxaphosphecane (II) salts prepared by hydrolysis of the corresponding bicyclophosphates have been compared. In both cases, hydrolysis occurs with breaking of the P–O bond of the fragment at the secondary carbon atom of bicyclophosphate. In phosphocycles I and II, the endocyclic bond angles O–P–O are 104.2 and 104.9°, and the exocyclic ones are 117.7 and 118.6°, respectively. Conformations of the anions in I and II differ substantially: for I it is a twist conformation^C1T_C4, and for II a distorted armchair. The data obtained are compared with those found earlier for similar molecules.Moscow State Pedagogical University. Translated fromZhurnal Strukturnoi Khimii, Vol. 34, No. 4, pp. 154–160, July–August, 1993.Translated by T. Yudanova     

Condensed imidazo-1,2,4-azines. 12. Synthesis and structure of substituted 5-H-imidazo[1,2-b]-1,2,4-triazepin-4-ones (-thiones)

The synthesis has been effected of new representatives of the imidazo[1,2-b]-1,2,4-triazepin-4-ones (-thiones). It has been shown with the aid of IR and UV spectroscopic and mass spectrometric methods that the lactam (thione) form is the predominant one for the compounds synthesized.For Communication 11, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 694–699, May, 1985.     

Über das Fluoreszenzthermochrome Acetonitrilo-Kupferjodid mit Dibenzo-18-Krone-6

About the Fluorescence Thermochromism of Acetonitrile Copper Iodide with Dibenzo-18-Crown-6 Copper iodide reacts in actonitrile solution with dibenzo-18-crown-6 to form a compound,(CuJ)₄(CH₃CN)₄(db-18-c-6), which fluoresces yellow at 298K, but pink at 77 K. It decomposes at 55.3°C. (5 Torr) by lost of acetonitrile and a heterogeneous mixture of copper iodide and polyether results. In absence of dibenzo-18-crown-6, copper iodide forms with acetonitrile a heterogeneous mixture of copper iodide and polyether results. In absence of dibenzo-18-crown-6, copper iodide forms with acetonitrile a solvate CuJ. CH₃CN. It also shows fluorescence thermochromism (yellow at 298 K, but green at 77 k) but decomposes at 0°C and 760 Torr. The luminescences pectra of the macrocyclic polyether complex at 298 K is redshifted. This probably results from intersection between the crown and the acetonitrile copper iodide.