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101.
E. Yu. Fursova V. I. Ovcharenko G. V. Romanenko V. N. Ikorskii Yu. G. Shvedenkov I. P. Asanov L. N. Mazalov 《Journal of Structural Chemistry》2001,42(2):251-260
The crystal structures of two manganese complexes with the enaminoketone derivatives of 3-imidazoline nitroxide: MnL
2
COOMe
(layered polymeric) and MnL
2
CF3
(DMF)2 (molecular) have been determined. The polymer structure of MnL
2
COOMe
is the result of direct coordination of the nitroxyl O atoms of the neighboring bischelate fragments by the Mn atoms. This forms heterospin exchange clusters >N-O–Mn(II)–O-N< with strong antiferromagnetic interactions between the odd electrons of the paramagnetic centers. The structure of MnL
2
CF3
(DMF)2 is characterized by ligand cis-coordination in the octahedral coordination polyhedron. Due to the molecular nature of the complex, the solid compound has only weak ferromagnetic intramolecular indirect exchange interactions. The charge states of atoms in coordination units was confirmed by X-ray photoelectron data. 相似文献
102.
Crystal stmctures of two layer polymeric hetcrospin complexes Cu(LHal,R )2 , where L are deprotonated enaminoketone derivatives of a stable radical 3-imidazoline nitroxide (Hal = Cl, R = CF3 and Hal = Br, R = COOC2H5), are described. In the solid state, both compounds have a layer polymeric structure with Cu(11) ions coordinating the O
atoms of the nitroxyl groups of the neighboring molecules. The stmcture of the product of decomposition of Cu(LBr,COOC
2H5
2 — Cu(L′)2Br2 · 2H2O—which is a rare example of a complex with a coordinated zwitterion (4-carboxy-2,255-tetramethyl-3-imidazoline zwitterion),
is analyzed.
Translated fromZhumal Struktunoi Khimii, Vol. 41, No. 2, pp. 349–358, March–April, 2(XX). 相似文献
103.
O. V. Kuznetsova E. Yu. Fursova G. A. Letyagin G. V. Romanenko V. I. Ovcharenko 《Russian Chemical Bulletin》2018,67(7):1202-1205
Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]?2H2O, [Co12(hfac)10(OH)14(H2O)8]?2H2O?2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]?3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]?2H2O?2Me2CO, whose structures were confirmed by X-ray analysis. 相似文献
104.
105.
K. Yu. Maryunina G. V. Romanenko E. M. Zueva S. V. Fokin A. S. Bogomyakov V. I. Ovcharenko 《Russian Chemical Bulletin》2013,62(11):2337-2344
The synthesis, structures, and magnetochemical data for the heterospin chain polymer complexes Cu(hfac)2LAll and Cu(hfac)2LBu·0.5Solv, where hfac is the hexafluoroacetylacetonate anion, LAll and LBu are 2-(1-allyl-1H-pyrazol-4-yl)- and 2-(1-butyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyls, respectively, Solv is isopropylbenzene or tert-butylbenzene, were described. These polycrystalline solids were found to exhibit similar magnetic anomalies. Thus, the effective magnetic moment first decreases and then increases with temperature, resulting in the specific minimum in the curve μeff(T). The study of the magneto-structural correlations showed that the appearance of the minimum is attributed to different factors. For Cu(hfac)2LAll, this is the phase transition accompanied by the structural rearrangement of the exchange cluster >N—·O—CuII—O·—N<, which leads to a change in the energy of the exchange interaction between the unpaired electrons of the paramagnetic centers. By contrast, for Cu(hfac)2LBu·0.5PriPh and Cu(hfac)2LBu·0.5ButPh, the appearance of the minimum is a consequence of the coexistence of exchange interaction energies with opposite signs, while the structure of the solid phase remains unchanged. 相似文献
106.
N. A. Artiukhova K. Yu. Maryunina S. V. Fokin E. V. Tretyakov G. V. Romanenko A. V. Polushkin A. S. Bogomyakov R. Z. Sagdeev V. I. Ovcharenko 《Russian Chemical Bulletin》2013,62(10):2132-2140
A method was developed for the synthesis of a nitronyl nitroxide containing cyclopentane substituents in positions 4 and 5 of the imidazoline ring, viz., 2-(3-pyridyl)-4,5-bis(spiropentyl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (LCP). The reaction of CuII hexafluoroacetylacetonate with LCP affords different products depending on the reaction conditions: mononuclear [Cu(hfac)2(LCP)2], binuclear [Cu(hfac)2LCP]2, tetranuclear {[Cu(hfac)2]4(LCP)2}, or chain polymer {[Cu(hfac)2]3(LCP)2} n . Temperature changes induce structural transformations accompanied by a change in the spin state in exchange clusters in the solid [Cu(hfac)2LCP]2 and {[Cu(hfac)2]4(LCP)2}. 相似文献
107.
G. V. Romanenko O. V. Kuznetsova E. Yu. Fursova V. I. Ovcharenko 《Journal of Structural Chemistry》2014,55(3):481-487
Using single crystal X-ray diffraction the structure of polynuclear [Ni6(OH)4(Piv)7(HOC4H8O)(HPiv)4], {K4[Ni12(CO3)2(Piv)16(OH)8(HOC4H8OH)2]}HPiv, {[Ni6(OH)4(Piv)6(HOC4H8O)(Me2CO)(HOC4H8OH)2]4×(Piv)4}, and {K[Ni2L2(Piv)3]}∞ complexes, where HOC4H8OH is 1,4-butanediol, HPiv is pivalic acid, and L is the anion of nitroxyl radical 2,2,5,5-tetramethyl-4-(3′,3′,3′-trifluoro-2′-oxy-1′-propenyl)-3-imidazolin-1-oxyl is determined. 相似文献
108.
The trielectronic recombination of an In+ (4d
105s
2
1
S
0) ion in collisions with slow electrons, including the two-electron excitation of the 5s2 core of the ion with the simultaneous capture of the triply excited 5p
3 intermediate autoionizing state with its subsequent radiative stabilization 5p
3 → 5s5p
2 + hν has been detected and experimentally examined for the first time. The maximum effective cross section of trielectronic recombination
is 1.6 × 10−16 cm2, which is comparable to the effective cross sections for both dielectronic recombination and electron excitation of the In+ ion. 相似文献
109.
R. E. Ovcharenko I. I. Tupitsyn V. G. Kuznetsov A. S. Shulakov 《Optics and Spectroscopy》2011,111(6):940-948
Using the density functional method in the pseudopotential approximation, we calculate the probabilities of X-ray emission
transitions and shapes of the L
2,3 X-ray emission bands of Mg in crystals of metallic magnesium and monoxide MgO. We have paid special attention to the study
of mechanisms by which these bands were formed; therefore, along with the total intensities, we determine the partial s- and d-contributions. In addition, the intensities of the L
2,3 bands of Mg have been separated into contributions from direct (intra-atomic) transitions and charge-transfer crossover transitions.
We show that an unexpectedly large contribution of partial d-transitions in magnesium oxide is caused by crossover transitions of electrons of valence states of ligands to the core 2p-level of Mg, i.e., charge-transfer transitions. In metallic magnesium, the contribution of these transitions proved to be
insignificant. An appreciable contribution of crossover transitions has also been revealed in s-contributions of X-ray emission bands. To estimate the calculation accuracy, we have compared the shapes of theoretical spectra
with the shapes of experimental L
2,3 X-ray emission bands of Mg. 相似文献
110.
Back Cover: C(sp2)‐Coupled Nitronyl Nitroxide and Iminonitroxide Diradicals (Chem. Eur. J. 10/2014) 下载免费PDF全文
Dr. Svyatoslav Tolstikov Prof. Evgeny Tretyakov Dr. Sergey Fokin Dr. Elizaveta Suturina Prof. Galina Romanenko Dr. Artem Bogomyakov Dr. Dmitri Stass Dr. Alexander Maryasov Prof. Matvey Fedin Prof. Nina Gritsan Prof. Victor Ovcharenko 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(10):2968-2968