Direct olive oil analysis by low‐temperature plasma (LTP) ambient ionization mass spectrometry

A fast, reagentless, and direct method is presented for the mass spectrometric analysis of olive oil without any sample pretreatment whatsoever. An ambient ionization technique, the low‐temperature plasma (LTP) probe, based on dielectric barrier discharge, is used to detect both minor and trace components (free fatty acids, phenolics and volatiles) in raw untreated olive oil. The method allows the measurement of free fatty acids (the main quality control parameter used to grade olive oil according to quality classes), selected bioactive phenolic compounds, and volatiles. The advantages and limitations of the direct analysis of extremely complex mixtures by the ambient ionization/tandem mass spectrometry combination are discussed and illustrated. The data presage the possible large‐scale application of direct mass spectrometric analysis methods in the characterization of olive oil and other foodstuffs. Copyright © 2009 John Wiley & Sons, Ltd.     

国际市场营销管理与决策信息系统(IMMADIS)原型研究

分析归纳了国际市场营销管理与信息的特征，把系统目标分解为三级，依此提出的国际市场营销管理与决策信息系统结构模式，充分考虑了计算机在企业管理中应用的优势与特点，同时又考虑到国情，便于企业开发实施。     

Exchange bias dependence on interface spin alignment in a Ni80Fe20/(Ni,Fe)O thin film

A Ni80Fe20/(Ni,Fe)O thin film exhibits a positive exchange bias when cooled in a zero field and a negative exchange bias when field cooled. With transmission electron microscopy and electron energy loss spectrometry, the composition and magnetic structure has been ascertained and a distribution of magnetization easy axes about the interface extrapolated. The results indicate that the positive exchange bias is from antiferromagnetic interface moments perpendicular to their ferromagnetic counterparts. With field cooling the alignment is put into a parallel configuration resulting in a negative exchange bias.     

基于SIMPLER算法的多重网格方法研究

以二维方腔顶盖驱动流为模型,将多重网格方法和SIMPLER算法进行耦合,对不同雷诺数下多重网格加速SIMPLER算法和SIMPLER算法的计算效率进行了对比,数值计算表明:多重网格加速SIMPLER算法不仅能够解决SIMPLER算法不能准确模拟较高雷诺数流场的问题,而且其计算效率远远高于SIMPLER算法.本文也对松弛因子的选取、多重网格实现形式以及网格层数对多重网格加速SIMPLER算法的影响进行了研究,从而为多重网格加速SIMPLER算法的实施提供了计算技术.     

三维N-S方程计算隐式有限体积法

利用NND有限差分格式，发展了一种新的完全隐式的有限体积数值方法，以求解与时间相关的N－S方程．对通过单元体界面的无粘流和粘性流通量均作隐式处理．对绕流钝锥体和不同攻角的气动辅助实验飞行器的高超声速粘性流和化学反应流获得了定常数值解．对流加热率和流场电子密度的计算值与实验数据进行了比较，符合较好，证实了本方法的精确性．     

Rhodium(III)‐Catalyzed [3+2]/[5+2] Annulation of 4‐Aryl 1,2,3‐Triazoles with Internal Alkynes through Dual C(sp2)H Functionalization

A rhodium(III)‐catalyzed [3+2]/[5+2] annulation of 4‐aryl 1‐tosyl‐1,2,3‐triazoles with internal alkynes is presented. This transformation provides straightforward access to indeno[1,7‐cd]azepine architectures through a sequence involving the formation of a rhodium(III) azavinyl carbene, dual C(sp²)? H functionalization, and [3+2]/[5+2] annulation.     

A new myrsinol-type diterpene polyester from Euphorbia dracunculoides Lam

A new myrsinol-type diterpene polyester, 14-deoxo-3β-O-propinoyl-2α,5α,7β,15β-tetra-O-acetyl-14α-O-benzoyl-myrsinol (1), and its known analogue, 14-deoxo-3β-O-prorionyl-5α,15β-di-O-acetyl-7β-O-nicotinoyl-myrsinol-14β-acetate (2), together with a monoterpenoid, pubinernoid A (3), two indole alkaloids, neoechinulin A (4) and dihydroxyisoechinulin A (5), two benzene derivatives, siringin (6) and (3-methoxyphenyl) acetic acid (7), were isolated from the 70% acetone extract of the aerial parts of Euphorbia dracunculoides Lam. Their structures were elucidated on the basis of spectroscopic evidence and comparison with literature reports. The absolute configuration of 1 was deduced by comparing experimental and calculated ECD spectra. Among them, compounds 4 and 5 were first obtained from the plant source. In addition, the ¹³C NMR data of compound 2 was reported for the first time.     

Rhodium(III)‐Catalyzed [3+2]/[5+2] Annulation of 4‐Aryl 1,2,3‐Triazoles with Internal Alkynes through Dual C(sp2)?H Functionalization

A rhodium(III)‐catalyzed [3+2]/[5+2] annulation of 4‐aryl 1‐tosyl‐1,2,3‐triazoles with internal alkynes is presented. This transformation provides straightforward access to indeno[1,7‐cd]azepine architectures through a sequence involving the formation of a rhodium(III) azavinyl carbene, dual C(sp²) H functionalization, and [3+2]/[5+2] annulation.     

Base‐Promoted Coupling of Carbon Dioxide,Amines, and N‐Tosylhydrazones: A Novel and Versatile Approach to Carbamates

A base‐promoted three‐component coupling of carbon dioxide, amines, and N‐tosylhydrazones has been developed. The reaction is suggested to proceed via a carbocation intermediate and constitutes an efficient and versatile approach for the synthesis of a wide range of organic carbamates. The advantages of this method include the use of readily available substrates, excellent functional group tolerance, wide substrate scope, and a facile work‐up procedure.