首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2593篇
  免费   104篇
  国内免费   10篇
化学   1949篇
晶体学   24篇
力学   67篇
综合类   1篇
数学   264篇
物理学   402篇
  2023年   35篇
  2022年   71篇
  2021年   78篇
  2020年   77篇
  2019年   65篇
  2018年   52篇
  2017年   47篇
  2016年   108篇
  2015年   64篇
  2014年   91篇
  2013年   128篇
  2012年   219篇
  2011年   224篇
  2010年   104篇
  2009年   88篇
  2008年   156篇
  2007年   150篇
  2006年   127篇
  2005年   108篇
  2004年   72篇
  2003年   77篇
  2002年   59篇
  2001年   26篇
  2000年   20篇
  1999年   23篇
  1998年   9篇
  1997年   11篇
  1996年   9篇
  1995年   11篇
  1994年   11篇
  1993年   14篇
  1992年   13篇
  1991年   14篇
  1988年   8篇
  1985年   12篇
  1984年   22篇
  1981年   15篇
  1979年   9篇
  1978年   7篇
  1975年   10篇
  1974年   7篇
  1973年   8篇
  1959年   8篇
  1956年   8篇
  1955年   7篇
  1948年   21篇
  1947年   10篇
  1938年   6篇
  1934年   9篇
  1933年   7篇
排序方式: 共有2707条查询结果,搜索用时 15 毫秒
1.
2.
A special family of partitions occurs in two apparently unrelated contexts: the evaluation of one-dimensional configuration sums of certain RSOS models, and the modular representation theory of symmetric groups or their Hecke algebras Hm. We provide an explanation of this coincidence by showing how the irreducible Hm-modules which remain irreducible under restriction to Hm_1 (Jantzen–Seitz modules) can be determined from the decomposition of a tensor product of representations sln.  相似文献   
3.
A time-dependent model corresponding to an Oldroyd-B viscoelastic fluid is considered, the convective terms being disregarded. Global existence in time is proved in Banach spaces provided the data are small enough, using the implicit function theorem and a maximum regularity property for a three fields Stokes problem. A finite element discretization in space is then proposed. Existence of the numerical solution is proved for small data, so as a priori error estimates, using again an implicit function theorem. Supported by the Swiss National Science Foundation. Fellowship PBEL2–114311.  相似文献   
4.
This paper presents a method to estimate reflected and transmitted wave amplitude spectra in a bounded domain such as a wave tank, when available data signals must be shortened due to interferences and wall effects. This paper extends the well known Goda and Suzuki two-probe method to three probes. The paper also suggests solutions to compute reliable transmission and reflection coefficients in spite of problems linked to higher harmonics and to the interference between different wave trains propagating in the tank. To cite this article: G. Duclos, A.H. Clément, C. R. Mecanique 331 (2003).  相似文献   
5.
Résumé La méthyl-9-trihydroxy-2,3,7-fluorone-6 permet de déceler les ions de l'antimoine, en présence de tous autres cations et anions. Les conditions deph (ph = 4) sont à observer rigoureusement.Ce nouveau réactif est avantageusement utilisé dans la méthode d'analyse à la touche ou par empreinte.Les limites de sensibilité sont: en godet 0,2; sur papier gélatine 0,5; sur papier filtre 0,8.
Summary Methyl-9-trihydroxy-2,3,7-fluorone-6 is a reagent which allows to detect antimony ion in the presence of all the other cations and anions. Aph value of 4 must be strictly maintained.This new reagent can be advantageously applied for spot test and offprint analysis.Limits of identification: On the spot test plate 0,2; On gelatine paper 0,5; On filter paper 0,8.

Zusammenfassung Das Methyl-9-trioxy-2,3,7-fluoron-6 gestattet den Nachweis des Antimonions in Gegenwart aller anderen Kationen und Anionen. Dieph-Bedingungen (ph = 4) sind streng einzuhalten.Dieses neue Reagens läßt sich mit Vorteil zur Tüpfel- oder Abdruckanalyse verwenden.Erfassungsgrenzen: auf der Tüpfelplatte 0,2; auf Gelatinepapier 0,5; auf Filtrierpapier 0,8.
  相似文献   
6.
The study of interactions between biological molecules and model membranes is essential for the understanding of a number of physiological mechanisms involved in viral infections and dissemination. In this paper, the analysis of the interaction between a peptide from the p24 protein of Human Immunodeficiency Virus type 1 (HIV-1) and a phospholipid monolayer has pointed to a cooperative response in which very small amounts of peptide p24-1 (e.g. 0.05 mol%) can lead to measurable effects. Monolayer surface pressure and surface potential isotherms were affected for peptide concentrations as low as 0.05 mol%, with saturation at 0.5 mol%. The expansion effect from p24-1 is confirmed by changes in morphology of the monolayers using Brewster angle microscopy. Even though p24-1 is disordered in aqueous solutions, the interaction with dipalmitoyl phosphatidylcholine (DPPC) causes it to adopt an alpha-helix structure, as shown by circular dichroism (CD) data for multilamellar vesicles (MLV). The expansion of the phospholipid monolayer in a cooperative way may imply that p24-1 has potential antiviral activity, by participating in the cell rupture, with no need of specific receptors in the membrane.  相似文献   
7.
Two Fe–Ta containing sulfido complexes were prepared by the reaction of the metal halide salts with bis-trimethylsilylsulfide in the presence of PMe3. The complexes demonstrate that coordination chemistry with iron sulfides can give access to a range of heterometallic complexes. In [Cl(Me3P)Ta( 2-S)2( 3-S)Fe(PMe3)2]2 the two [Cl(Me3P)Ta] units are arranged around one central Fe2( 2-S)2 unit. In [(Me3P)4(MeCN)2FeII]2+[(Me3P)2TaIVFeII 3( 3-S)4Br4]2– a [TaFe3S4]2+ cuboidal arrangement was observed. The complex salt forms a polymeric structure in the solid-state with weak H-bonds between the ions. The [(Me3P)2TaIVFeII 3( 3-S)4Br4]2– ion was characterised by magnetic measurements showing strong antiferromagnetic interactions between the metal centres.  相似文献   
8.
The interaction between poly(methymethacrylate) (PMMA) and poly(vinyl chloride) (PVC) has been studied indilute urea solutions of dimethylformamide (DMF) at 28℃ using a dilute solution viscometry method. The results show thatthe polymer mixtures are compatible in DMF solution in the absence of urea. The influence of urea addition on the degree ofcompatibility of the polymer mixtures has been studied in terms of the compatibility parameters (△b_m and △[η]_m). It wasfound that the compatibility of the polymer mixtures is decreased with increasing urea addition, passing through a minimumat 0.5 M urea.  相似文献   
9.
10.
The enantiomers of 34 pharmaceutical weak-base analytes were separated by nonaqueous capillary electrophoresis in acidic methanol background electrolytes using the sodium salt of the new, single-isomer chiral resolving agent, octakis(2,3-O-dimethyl-6-O-sulfo)-gamma-cyclodextrin (ODMS). The effective mobilities, separation selectivities and peak resolution values of the weak-base analytes were determined as a function of the ODMS concentration in the 0-40 mM range and were found to follow the theoretical predictions of the charged resolving agent migration model (CHARM model) modified for ionic strength effects. Fast, efficient separations were achieved for both comparatively small and large enantiomers.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号