Measurement of the transverse kinetic energies of argon recoil ions produced in 120 MeV -Ar collisions

Measurements were carried out to deduce the transverse kinetic energies of highly charged argon recoil ions produced in single collisions of 120 MeV ions with argon atoms in which the post collision charge states of the projectiles were not determined. A time of flight spectrometer was designed and fabricated to detect the charge states of recoils. Experimental procedures for optimizing the spectrometer for extraction, transmission and detection of recoils are described. A simple approach for determining the transverse kinetic energy of the recoil ions from FWHM of the peaks is reported. This method is shown to be independent of the choice of collision partners and requires only the knowledge of the physical values of “optimized parameters” of time-of-flight spectrometer used in the experiment. The transverse kinetic energy of the recoil ions determined from the present approach is found to vary from 0.03 eV for to 4.02 eV for Ar¹⁰⁺. These values are compared with the results reported by earlier workers and are shown to follow a q²-behaviour up to a charge state q =8+ of the recoil ions. Received: 5 February 1998 / Revised: 8 June 1998 / Accepted: 11 June 1998     

Radiation grafting of acrylonitrile on ethylene-propylene diene terpolymer rubber: Optimization of grafting parameters and oil resistance properties

Radiation induced grafting of acrylonitrile (ACN) on ethylene-propene diene terpolymer (EPDM) rubber film was investigated by mutual radiation grafting technique. Effect of experimental variables viz. radiation dose, dose rate, type of solvent and monomer content on extent of grafting was studied. From the kinetic studies a mathematical relation R _g α[M]^0.7 D ^0.68 showing non-linear relationship for rate of grafting with monomer concentration and dose was deduced. The grafted samples showed increased hardness and oil resistance.     

Mutual binary separations of cadmium(II), indium(III) and thallium(III) as chlorides by their extraction in high molecular weight amines

The extraction of cadmium(II), indium(III) and thallium(III) with high molecular weight amines have been studied from aqueous hydrochloric acid solutions. Using the data mutual binary separations of these three elements with high separation coefficients are proposed. Various variables like type of amine, amine concentration and organic diluent were explored to propose the best conditions of separations.     

Electroproduction of π+ mesons in the resonance region

Results on the reaction ep→e′nπ⁺ are presented in the mass range 1.355 ?W ?1.775 GeV at q₂=1GeV² and in the range 1.415 ? W ? 1.595 GeV at q²=0.6 GeV². From the angular distribution of the π⁺ meson the polarization terms σ_u + ?σ_L, σ_p and σ_I have been determined in the range of production angles 0 <θ_π⁺ ?63°     

Microestimation of explosives present in different compositions

Summary High explosives having the sameR _f values on a thin-layer chromatogram and difficult to separate are readily resolved as their coloured -complexes with aromatic amines. After liberation from their complexes on the plate, up to 1.5 g of the explosives can be conveniently estimated at their characteristic absorption maxima.

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Zusammenfassung Hochexplosive Substanzen mit gleichenR _f -Werten auf Dünnschichtchromatogrammen, die sich schlecht trennen lassen, werden als gefärbte -Komplexe mit aromatischen Aminen gut voneinander getrennt. Nach Freisetzung aus den Komplexen auf der Platte können bis zu 1,5 g der Explosivstoffe bei ihrem charakteristischen Absorptionsmaximum auf übliche Weise bestimmt werden.

     

The influence of ultrasonic waves on manganese dioxide sol in the atmosphere of nitrogen

Summary The influence of ultrasonic waves at 1 MC/sec and 225 watts/cm² power on the negatively charged manganese dioxide sol has been investigated in an atmosphere of nitrogen and thereby excluding oxygen. The stability of the sol on exposure to ultrasonic waves is affected in a similar way as in presence of air but the extent to which the sol gets unstable on exposure is less in the absence of oxygen than in its presence. The specific conductivity increases but hydrogen ion concentration remains practically constant as the time of exposure increases.

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Zusammenfassung Der Einflu? von Ultraschall (1 mHz, 225 W/cm²) auf negativ geladenes Mangandioxidsol wurde unter Stickstoff unter Ausschlu? von Sauerstoff untersucht. Die Stabilit?t des Sols ist in gleicher Weise wie bei Gegenwart von Luft ver?ndert, nur wird das Sol bei Ausschlu? von Sauerstoff weniger instabil. Die spezifische Leitf?higkeit steigt mit steigender Expositionszeit, w?hrend die Wasserstoffionenkonzentration praktisch konstant bleibt.

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The authors are thankful to the Council of Scientific and Industrial Research for the award of scholarship for this work.     

Polarization dependent reflectivity and optical constants of single crystal rutile RuO2 in the range 0.5 to 9.5 eV

We have measured the near-normal incidence reflectivity of single crystal RuO₂ (rutile) for $\text{E}$ 6 $\text{c}$-axis and $\text{E}$ ⊥ $\text{c}$-axis at room temperature in the photon energy range 0.5 – 9.5 eV. From a Kramers-Kronig analysis of the reflectivity we have obtained the spectral dependence of the real, ?₁(ω), and imaginary, ?₂(ω), parts of the complex dielectric constant. Comparison with recent band structure and density of states calculations and past experimental studies of related solids has enabled us to gain further insight into the nature of the oxygen $\text{p}$-electrons and metal $\text{d}$-electrons in this material.     

Formation of benzoic acid in the palladium(II) catalyzed cleavage of phenyl-antimony and phenyl-phosphorus groups of Ph3Sb and Ph3P

Palladium (II) catalyzed cleavage of phenyl-antimony and phenyl-phosphorus groups of Ph₃Sb and Ph₃P under carbon-dioxide or CO/NO atmosphere leading to benzoic acid, has been demonstrated.