Very high-frequency gravitational waves from magnetars and gamma-ray bursts

Extremely powerful astrophysical electromagnetic(EM) systems could be possible sources of highfrequency gravitational waves(HFGWs). Here, based on properties of magnetars and gamma-ray bursts(GRBs), we address "Gamma-HFGWs"(with very high-frequency around 10~(20) Hz) caused by ultra-strong EM radiation(in the radiation-dominated phase of GRB fireballs) interacting with super-high magnetar surface magnetic fields(～10~(11) T).By certain parameters of distance and power, the Gamma-HFGWs would have far field energy density ?gw around10~(-6), and they would cause perturbed signal EM waves of～10~(-20) W/m~2 in a proposed HFGW detection system based on the EM response to GWs. Specially, Gamma-HFGWs would possess distinctive envelopes with characteristic shapes depending on the particular structures of surface magnetic fields of magnetars, which could be exclusive features helpful to distinguish them from background noise. Results obtained suggest that magnetars could be involved in possible astrophysical EM sources of GWs in the very high-frequency band, and Gamma-HFGWs could be potential targets for observations in the future.     

Translational and rotational energy content of benzene molecules IR-desorbed from an in vacuo liquid surface

Benzene molecules were desorbed from an in vacuo aqueous liquid beam by direct irradiation of the beam with an IR laser tuned to the 2.85 μm absorption band of water. Spectroscopic interrogation of the desorbed benzene molecules was performed via 1 + 1 Resonance-Enhanced Multi-photon Ionisation (REMPI). Rotational contour analyses of the 6 vibronic transition of benzene were performed to determine the rotational temperature of those molecules ejected during the desorption event. At the peak of the desorption plume density, the rotational temperatures were found to be up to ～100 K lower than that recorded for molecules spontaneously evaporating from the liquid surface. At longer IR-UV laser delay times the benzene rotational temperatures are found to return to those observed following spontaneous evaporation. No evidence of IR desorbed neutral or cationic benzene-containing clusters was observed. However, ionic clusters were observed to be formed after REMPI of the benzene monomer. Analysis of the benzene intensity and that of post-REMPI formed clusters as a function of IR-UV delay shows that number density and local translational temperature vary along the desorption plume.     

Side-chain tunability of furan-containing low-band-gap polymers provides control of structural order in efficient solar cells

The solution-processability of conjugated polymers in organic solvents has classically been achieved by modulating the size and branching of alkyl substituents appended to the backbone. However, these substituents impact structural order and charge transport properties in thin-film devices. As a result, a trade-off must be found between material solubility and insulating alkyl content. It was recently shown that the substitution of furan for thiophene in the backbone of the polymer PDPP2FT significantly improves polymer solubility, allowing for the use of shorter branched side chains while maintaining high device efficiency. In this report, we use PDPP2FT to demonstrate that linear alkyl side chains can be used to promote thin-film nanostructural order. In particular, linear side chains are shown to shorten π-π stacking distances between backbones and increase the correlation lengths of both π-π stacking and lamellar spacing, leading to a substantial increase in the efficiency of bulk heterojunction solar cells.     

Exponential Stability and Uniform Boundedness of Solutions for Nonautonomous Periodic Abstract Cauchy Problems. An Evolution Semigroup Approach

Let u _{μ, x, s} (., 0) be the solution of the following well-posed inhomogeneous Cauchy Problem on a complex Banach space X $$\left \{\begin{array}{ll}\dot{u}(t) = A(t)u(t) + e^{i\mu t}x, \quad t > s \\ u(s) = 0. \end{array} \right.$$ Here, x is a vector in X,?μ is a real number, q is a positive real number and A(·) is a q-periodic linear operator valued function. Under some natural assumptions on the evolution family ${\mathcal{U} = \{U(t, s): t \geq s\}}$ generated by the family {A(t)}, we prove that if for each?μ, each s?≥ 0 and every x the solution u _{μ, x, s} (·, 0) is bounded on R ₊ by a positive constant, depending only on x, then the family ${\mathcal{U}}$ is uniformly exponentially stable. The approach is based on the theory of evolution semigroups.     

Supramolecular control of hetero-multinuclear polytopic binding of metal ions (Zn(II), Cu(I)) at a single calix[6]arene-based scaffold

A Calix[6]arene scaffold was functionalized to provide a tridentate binding site at the small rim and three bidentate chelate sites at the large rim of the cone to generate a heteropolytopic ligand. Its complexation to one equivalent of Zn(II) at the small rim yields a funnel complex displaying both host-guest properties and preorganization of the three chelate groups at the large rim. These two aspects allowed the full control of the binding events to regioselectively form dinuclear Zn(II) and heteropolynuclear Zn(II)/Cu(I) complexes. The heteropolynuclear systems all rely on the host-guest relationship thanks to the induced-fit behavior of the calix cavity. With the short guest MeCN, the large rim is preorganized into a trigonal tris-triazole core and accommodates a single Cu(I) ion. A long guest breaks this spatial arrangement, and three Cu(I) ions can then be bound at the tris-bidentate triazole-dimethylamine site at the large rim. In a noncoordinating solvent however, the tetranuclear complex is submitted to scrambling and the addition of exogenous π-acceptor ligands is required to control the binding of Cu(I) in a well-defined environment. Hindrance selectivity was then induced by the accessibility at the small rim site. Indeed, while CO can stabilize Cu(I) at both coordination sites, PPh(3) cannot fit into the cavity and forces Cu(I) to relocate at the large rim. The resulting well-defined symmetrical tetranuclear complex thus arises from the quite remarkable selective supramolecular assembly of nine partners (1 Zn(II), 3 Cu(I), 1 calixarene, 1 guest alkylamine, 3 PPh(3)).     

Canady Cold Helios Plasma Reduces Soft Tissue Sarcoma Viability by Inhibiting Proliferation,Disrupting Cell Cycle,and Inducing Apoptosis: A Preliminary Report

Soft tissue sarcomas (STS) are a rare and highly heterogeneous group of solid tumors, originating from various types of connective tissue. Complete removal of STS by surgery is challenging due to the anatomical location of the tumor, which results in tumor recurrence. Additionally, current polychemotherapeutic regimens are highly toxic with no rational survival benefit. Cold atmospheric plasma (CAP) is a novel technology that has demonstrated immense cancer therapeutic potential. Canady Cold Helios Plasma (CHCP) is a device that sprays CAP along the surgical margins to eradicate residual cancer cells after tumor resection. This preliminary study was conducted in vitro prior to in vivo testing in a humanitarian compassionate use case study and an FDA-approved phase 1 clinical trial (IDE G190165). In this study, the authors evaluate the efficacy of CHCP across multiple STS cell lines. CHCP treatment reduced the viability of four different STS cell lines (i.e., fibrosarcoma, synovial sarcoma, rhabdomyosarcoma, and liposarcoma) in a dose-dependent manner by inhibiting proliferation, disrupting cell cycle, and inducing apoptosis-like cell death.     

Formation of linear triquinanes by serial homolytic cyclisation

Treatment of the trienyl bromide (2) with tributylgermane affords the two stereo-isomers of 4-methyl-$\text{cis,anti,cis}$-tricyclo[6,3,0,0²,⁶] undecane 9 (27%) and related tricyclic compounds by processes involving three consecutive radical ring closures     

Reactivity of a two heteroatom stabilized anionic chromium (0) carbene complex towards a mono- and a disubstituted alkyne: New synthesis of γ-aminobutenolides and formation of a novel oligomer chromium (0) complex

The reaction of the chromium anionic carbene complex 1 towards diphenylacetylene and phenylacetylene is reported. In the former case the synthesis of γ-functionalized butenolides results after demetallation of the chromium complex 2 and the latter leads to the formation of a novel oligomer chromium complex 5. These complexes were characterized by mass spectrometry, IR and ¹H and ¹³C NMR spectroscopies and their structures were confirmed by single-crystal X-ray analysis.