全文获取类型
收费全文 | 758篇 |
免费 | 23篇 |
国内免费 | 3篇 |
专业分类
化学 | 524篇 |
晶体学 | 8篇 |
力学 | 33篇 |
数学 | 95篇 |
物理学 | 124篇 |
出版年
2023年 | 5篇 |
2022年 | 53篇 |
2021年 | 29篇 |
2020年 | 27篇 |
2019年 | 24篇 |
2018年 | 31篇 |
2017年 | 24篇 |
2016年 | 37篇 |
2015年 | 17篇 |
2014年 | 14篇 |
2013年 | 55篇 |
2012年 | 39篇 |
2011年 | 42篇 |
2010年 | 31篇 |
2009年 | 33篇 |
2008年 | 31篇 |
2007年 | 22篇 |
2006年 | 22篇 |
2005年 | 18篇 |
2004年 | 10篇 |
2003年 | 19篇 |
2002年 | 15篇 |
2001年 | 10篇 |
2000年 | 11篇 |
1999年 | 6篇 |
1998年 | 11篇 |
1997年 | 14篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 5篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 9篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 3篇 |
1970年 | 3篇 |
1961年 | 3篇 |
排序方式: 共有784条查询结果,搜索用时 15 毫秒
11.
S. M. Al-Jobori R. K. Itawi A. Saad K. M. Shihab M. Jalil S. S. Farhan 《Journal of Radioanalytical and Nuclear Chemistry》1990,144(3):229-239
As a part of the Iraqi Food Analysis Programme /I.F.A.P./ the concentration of Na, Mg, P, Cl, K, Ca, Zn, Se, Br, Rb and I in natural milk collected from different regions of Iraq, and in milk powder samples have been determined by using the NAA technique. It was found that except for the elements I, Rb and Br the concentration of the elements was approximately identical in both the natural milks and milk powders. 相似文献
12.
Salama Tarek A. El-Ahl Abdel-Aziz S. Khalil Abdel-Galil M. Girges Margret M. Lackner Bernd Steindl Christian Elmorsy Saad S. 《Monatshefte für Chemie / Chemical Monthly》2003,134(9):1241-1252
Summary. Several new 1-aryl-, aralkyl-, and heteroaryl-5-(4-phenylbuta-1,3-dienyl)tetrazole derivatives and annulated tetrazole derivatives were efficiently and regiospecifically prepared in nearly quantitative yield via a facile one step reaction of dienones with a combination of tetrachlorosilane and sodium azide in acetonitrile under mild conditions. A complete structure assignment of three representative examples of the tetrazoles was achieved by advanced 2D NMR measurements including COSY, TOCSY, HSQC, HMBC, NOESY, and ROESY experiments.Received March 17, 2003; accepted March 18, 2003
Published online July 28, 2003 相似文献
13.
Tarek A. Salama Abdel-Aziz S. El-Ahl Abdel-Galil M. Khalil Margret M. Girges Bernd Lackner Christian Steindl Saad S. Elmorsy 《Monatshefte für Chemie / Chemical Monthly》2003,20(5):1241-1252
Several new 1-aryl-, aralkyl-, and heteroaryl-5-(4-phenylbuta-1,3-dienyl)tetrazole derivatives and annulated tetrazole derivatives were efficiently and regiospecifically prepared in nearly quantitative yield via a facile one step reaction of dienones with a combination of tetrachlorosilane and sodium azide in acetonitrile under mild conditions. A complete structure assignment of three representative examples of the tetrazoles was achieved by advanced 2D NMR measurements including COSY, TOCSY, HSQC, HMBC, NOESY, and ROESY experiments. 相似文献
14.
A reasonably sensitive and highly selective spectrophotometric method for the determination of mercury(II) is proposed. The method is based on the extraction of the ion-associate formed by a mercury(II) thiacrown ether cationic complex with Bromocresol Green as the anionic counter-ion using chloroform as the extracting solvent. The effect of thiacrown ethers of different cavity sizes, namely 1,4,7,10,13-pentathiacyclopentadecane (PTP) and 1,4,7,10,13,16-hexathiacyclooctadecane (HTO), the thiacrown ether concentration, the extracting solvent, the bromocresol green concentration and the aqueous phase pH on the extraction were investigated. Measurement of the absorbance at the lambda(max) (420 nm) of the extracted ion-associate reveals that Beer's law is obeyed over 0.5-12.0 ppm mercury(II) for both ligands. Slight interference from copper(II) and cadmium(II) is exhibited by the PTP ligand, while HTO is negligibly affected by these metal ions. Strong interference from silver(I) is evident for both ligands while alkali, alkaline earth and other transition metals tested posed negligible interference. Analysis of mercury in synthetic complex mixtures was satisfactory. 相似文献
15.
Osmotic and activity coefficients in the aqueous quaternary system sodium chloride-potassium chloride-calcium chloride were derived from isopiestic measurements at 25°C. The isopiestic data were treated by the various procedures of Scatchard, Friedman, and Reilly, Wood, and Robinson. The results obtained showed good agreement with those obtained by pseudo-ternary transforms. Interaction parameters obtained indicated the preponderance of pairwise interactions. Excess Gibbs free energies of mixing were calculated. 相似文献
16.
The chiroptical properties and transient rheological behavior of (acetyl)(ethyl)cellulose (AEC) m-cresol liquid crystalline solutions have been investigated. Chiroptical properties were manipulated through (i) increasing degree of acetylation of ethyl cellulose (EC), and (ii) blending AEC with EC. At the same average degree of acetylation (DA), the chiroptical properties of pure AEC were different from those of the EC/AEC mixtures. However, at the same DA, the AEC and mixed AEC/EC solutions showed similar steady state flow and oscillatory behaviors, but the transient behaviors were different. At high flow rates the mixed AEC/EC solutions exhibited double recoil after cessation of steady-state flow, whereas the AEC solutions showed double recoil only in the high DA AEC solutions. All solutions, pure and mixed, had the same stress relaxation behavior. Both pitch and handedness affected the transient behavior. After cessation of high shear rate flow, the rate of modulus evolution decreased with increasing pitch, and was faster in right-handed mesophases than in left-handed ones at a similar pitch. 相似文献
17.
Saad H. Al-Kouraishi 《Journal of Radioanalytical and Nuclear Chemistry》1988,125(1):213-220
An instant kit of cysteine (amino acid) to be labelled with99mTc was prepared. Optimal conditions were found, and a procedure to prepare the kit ready to use in liophilized form to gain the highest labelling yield. More than 95% labelling yield was obtained when99mTc (TcO
4
–
) eluted from99mTc-generator was added to the contents of the kit. Each kit contains 0.66 mg of SnCl2·2H2O as stannite and 66 mg cysteine in lyophilized form. The formulation of cysteine tin (kit) was stable for nearly three months giving labelling yield more than 95%. Using GCS technique, different species of technetium and labelled cysteine were identified when Sephadex (G-50, G-25) was applied. Biodistribution of the labelled preparation revealed that kidney was the target organ. The ratio of accumulated dose in kidneys/liver was greater than 2. 相似文献
18.
Summary A microanalytical radioactive method for the estimation of the iodine number in linseed oil has been fully described. The application of the method was carried out on three varieties of linseed oil, namely: Guiza IV, Indian and Baladi. The relationship between the radioactivity measured on the oil spot and the iodine consumed for saturation is described.A simple equation has been put forward for the direct estimation of the iodine value from the specific activity and the number of counts on the oil spot. The method could be used on different varieties of oils and fats. 相似文献
19.
Al-Shihry SS 《Molecules (Basel, Switzerland)》2004,9(8):658-665
Knoevenagel condensations between aldehydes and substrates containing active methylene groups were carried out in ethanol at room temperature, in the presence of potassium phosphate, to afford unsymmetrical olefins. These condensations have been shown to afford only the E-isomers in greater than 80% yields. Salicylaldehyde first produces the Knoevenagel condensation products, which undergo a subsequent heterocyclization to give coumarin derivatives. The structures of the synthesized compounds were established on the basis of UV, IR, MS and NMR spectroscopy. 相似文献
20.
Typical cis-PtA(2)G(2) models of key DNA lesions formed by cis-type Pt anticancer drugs are very dynamic and difficult to characterize (A(2) = diamine or two amines; G = guanine derivative). Retro models have A(2) carrier ligands designed to decrease dynamic motion without eliminating any of three possible conformers with bases oriented head-to-tail (two: DeltaHT and LambdaHT) or head-to-head (one: HH). All three were found in NMR studies of eight Me(2)DABPtG(2) retro models (Me(2)DAB = N,N'-dimethyl-2,3-diaminobutane with S,R,R,S and R,S,S,R configurations at the chelate ring N, C, C, and N atoms, respectively; G = 5'-GMP, 3'-GMP, 5'-IMP, and 3'-IMP). The bases cant to the left (L) in (S,R,R,S)-Me(2)DABPtG(2) adducts and to the right (R) in (R,S,S,R)-Me(2)DABPtG(2) adducts. Relative to the case in which the bases are both not canted, canting will move the six-membered rings closer in to each other ("6-in" form) or farther out from each other ("6-out" form). Interligand interactions between ligand components near to Pt (first-first sphere communication = FFC) or far from Pt (second-sphere communication = SSC) influence stability. In typical cases at pH < 8, the "6-in" form is favored, although the larger six-membered rings of the bases are close. In minor "6-out" HT forms, the proximity of the smaller five-membered rings could be sterically favorable. Also, G O6 is closer to the sterically less demanding NH part of the Me(2)DAB ligand, possibly allowing G O6-NH hydrogen bonding. These favorable FFC effects do not fully compensate for possibly stronger FFC dipole effects in the "6-in" form. SSC, phosphate-N1H cis G interactions favor LambdaHT forms in 5'-GMP and 5'-IMP complexes and DeltaHT forms in 3'-GMP and 3'-IMP complexes. When SSC and FFC favor the same HT conformer, it is present at >90% abundance. In six adducts [four (S,R,R,S)-Me(2)DABPtG(2) and (R,S,S,R)-Me(2)DABPtG(2) (G = 3'-GMP and 3'-IMP)], the minor "6-out" HT form at pH approximately 7 becomes the major form at pH approximately 10, where G N1H is deprotonated, because the large distance between the negatively charged N1 atoms minimizes electrostatic repulsion and probably because the G O6-(NH)Me(2)DAB H-bond (FFC) is strengthened by N1H deprotonation. At pH approximately 10, phosphate-negative N1 repulsion is an unfavorable SSC term. This factor disfavors the LambdaHT R form of two (R,S,S,R)-Me(2)DABPtG(2) (G = 5'-GMP and 5'-IMP) adducts to such an extent that the "6-in" DeltaHT R form remains the dominant form even at pH approximately 10. 相似文献