Transformations of cobalt trimethylacetate complexes with pyrazole upon oxidation by air in THF

Synthetic routes to oxidation of cobalt atoms in cobalt trimethylacetate complexes containing coordinated pyrazole molecules have been considered.     

Asymptotics of a multiple Cauchy integral with rapidly oscillating exponential

An asymptotic expansion uniform with respect to a parameter is obtained for a multiple Cauchy integral with a rapidly oscillating exponential in the integrand under the assumption that the singularity lines are in a general position.Translated fromMatematicheskie Zametki, Vol. 58, No. 2, pp. 231–242, August, 1995.The work was financially supported by the Russian Foundation for Basic Research under grant No. 94-01-00193-a.     

Arc Discharge in a Channel with Transparent Walls at Intense Flow Rates of a Plasma Forming Gas

The arc discharge was studied in a transparent channel at an intense flow rate of nitrogen, hydrogen, air, carbon dioxide in the current range 100–1500 A. The internal diameter of the porous channel varied from 10 to 34 mm, the length - from 50 to 150 mm, the air and nitrogen flow rates - from 0.05 to 1.5 kg/s, hydrogen - from 0.005 to 0.05 kg/s. The electric field strength in the arc channel reached a value of 300 V/cm for N₂ and 500 V/cm for H₂. The effect of plasma thermochemical non-equilibrium was discovered.     

Band structures in73Se

Excited states of⁷³Se have been investigated up to spin, 21/2 using techniques of in-beamγ-ray spectroscopy in connection with the⁷⁰Ge(α, n) reaction. Mean lifetimes of 12 levels have been determined applying Doppler-shift andγ-RF-methods. Five different bands have been identified that reflect a variety of different excitation modes. The decoupled 9/2⁺ band is likely to correspond to an oblate deformation while the 5/2⁺ band is interpreted as a strongly coupled prolate band built on the Nilsson configuration [422] 5/2⁺. The 3/2^? band is a strongly coupled band built on the [301] 3/2^} configuration.Nuclear reactions:⁷⁰Ge(α,n),E=14, 16, 18, 19, 20MeV; measuredE _γ,I _γ,σ(E _γ,θ),γγ-coin, linear polarization, DSA,γ(t).⁷⁵Se deduced levels,I, π, τ, δ(E2/M1), B(σλ). Enriched targets, Ge detectors.     

Homogeneous symplectic structures of second order on loop spaces and symplectic connections

Scientific Industrial Association, All-Union Scientific Research Institute of Physicotechnical and Radiotechnical Measurements. Translated from Funktsional'nyi Analiz i Ego Prilozheniya, Vol. 25, No. 2, pp. 65–67, April–June, 1991.     

Structural analysis of the non-dialysable urinary glucoconjugates of normal men.

Enzymic methods were employed to analyse the structure of the non-dialysable urinary glucoconjugates of ten healthy males. The excretion of the urinary glucoconjugates was determined from the glucosyl:galactosyl ratio after acid hydrolysis, and a mean value of 0.27 was obtained. The results of the specific actions of alpha- and beta-glucosidases showed that the non-dialysable urinary glucoconjugates contain a branched alpha-glucan fraction with 1,4- and 1,6-glucosidic bonds, and a beta-glucan fraction containing 1,4-glucosidic bonds.     

Copper-D-penicillamine complex as potential contrast agent for MRI.

In vitro and in vivo proton T1 data are reported that demonstrate that the paramagnetic copper-D-penicillamine complex can be applied as a potential contrast agent to magnetic resonance imaging.