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991.
G. N. Merrill 《Journal of Physical Organic Chemistry》2007,20(1):19-29
Ab initio molecular orbital calculations were carried out on epibromohydrin (EBH) and epichlorohydrin (ECH) in an attempt to elucidate their reactivity with respect to a hard nucleophile, hydroxide. These systems were modeled in both the gas phase and a polar solvent under basic conditions. In the gas phase, it was determined that a direct displacement mechanism (nucleophilic attack at the C1 position) was operative for EBH, while an indirect pathway (nucleophilic attack at the C3 position and subsequent intramolecular displacement) was followed for ECH. In an acetone solution, only the indirect displacement mechanism was found to occur. An electrostatic argument is advanced to account for this behavior in polar solution. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
992.
A. I. Golovashkin G. N. Izmaïlov G. V. Kuleshova T. Q. Khánh A. M. Tskhovrebov L. N. Zherikhina 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(3):243-249
A scheme of magnetic calorimeter for registration of rare events
characterized by small energy release (cosmic rays, WIMPs, solitary X-ray
quanta) is proposed. The calorimeter is brought to operation by adiabatic
demagnetization, and its magnetic response is measured by a quantum
interferometer (SQUID, A. Barone and G. Paterno, Physics and applications of Josephson Effect). Special consideration is given to the specific
features of calorimeter operation in the ferromagnetic transition region.
The trigger registration of ultrasmall energy release by a ferromagnetic
system in the metastable state is described. 相似文献
993.
V. V. Kondrat'ev E. G. Tolstopyatova V. V. Malev 《Russian Journal of Electrochemistry》2002,38(6):589-595
The charge transfer in poly-3-methylthiophene films in 0.05–0.5 M LiClO4 solutions in acetonitrile is studied by cyclic voltammetry and chronoamperometry. An analysis of data on the current relaxation following a film perturbation by a low-voltage pulse reveals two constituents of the current relaxation, both exponentially dependent on time. Dependence of parameters of the empirical equation derived for the current relaxation on experimental variables is studied. 相似文献
994.
The coupling of visible nanosecond laser pulses to metallic targets irradiated in vacuum is studied. The expressions of the vapour and plasma ignition times are obtained. Two cases for vapour breakdown in the plasma ignition process are considered. The first case is that 40 generations of new electrons are born in vapour generation time before plasma formation as assumed in the literature. The second case is that 10 generations of new electrons are born in vapour generation time. Molybdenum (Mo), niobium (Nb) and aluminium (Al) targets are considered for illustrations of our results. The expression of the plasma ignition time for the Al target is substantially different from that reported in the literature. The vapour and plasma ignition threshold laser intensities are calculated and compared with those reported in the literature. Reasons for disagreement are discussed. The plasma ignition threshold estimated in the second case is noted to be in good agreement with the reported experimental result. 相似文献
995.
996.
N. O. Mchedlov-Petrosyan L. A. Fedorov S. A. Sokolovskii Yu. N. Surov R. Salinas Maiorga 《Russian Chemical Bulletin》1992,41(3):403-409
A study has been made of the acidic ionization, structural conversions, and prototropic tautomerism of rhodamine chromogens in methanol and dimethyl sulfoxide, using IR,
13
C NMR, and electronic spectroscopy. The lactone structure has been established for the colorless form of rhodamines in DMSO. For rhodamine B in mixtures of water with DMSO, the lactone/zwitterion ratio has been estimated.V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow 117975. Khar'kov State University, Khar'kov 310077. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 512–521, March, 1992. 相似文献
997.
Exponential growth is estimated for integral operators with continuous periodic kernels of exponential type. The result is
applied to the boundary-value problem for a general hyperbolic differential equation having periodic coefficients with Goursat
boundary conditions. It is proved that the exponential characteristic for such a boundary-value problem has canonical form.
__________
Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 38, Suzdal
Conference-2004, Part 3, 2006. 相似文献
998.
We construct a three-parameter family of contact metric structures on the unit tangent sphere bundle T
1
M of a Riemannian manifold M and we study some of their special properties related to the Levi-Civita connection. More precisely, we give the necessary
and sufficient conditions for a constructed contact metric structure to be K-contact, Sasakian, to satisfy some variational conditions or to define a strongly pseudo-convex CR-structure. The obtained
results generalize classical theorems on the standard contact metric structure of T
1
M. 相似文献
999.
1000.
Dorota G?azowska Janusz Matkowski 《Journal of Mathematical Analysis and Applications》2007,331(2):1187-1199
The invariance of the geometric mean G with respect to the Lagrangian mean-type mapping (Lf,Lg), i.e. the equation G○(Lf,Lg)=G, is considered. We show that the functions f and g must be of high class regularity. This fact allows to reduce the problem to a differential equation and determine the second derivatives of the generators f and g. 相似文献