全文获取类型
收费全文 | 105481篇 |
免费 | 593篇 |
国内免费 | 382篇 |
专业分类
化学 | 51188篇 |
晶体学 | 1516篇 |
力学 | 4627篇 |
综合类 | 13篇 |
数学 | 16734篇 |
物理学 | 32378篇 |
出版年
2022年 | 634篇 |
2021年 | 893篇 |
2020年 | 981篇 |
2019年 | 1113篇 |
2018年 | 2760篇 |
2017年 | 3113篇 |
2016年 | 2828篇 |
2015年 | 1552篇 |
2014年 | 2168篇 |
2013年 | 3883篇 |
2012年 | 5918篇 |
2011年 | 5496篇 |
2010年 | 4322篇 |
2009年 | 4084篇 |
2008年 | 3513篇 |
2007年 | 3438篇 |
2006年 | 3328篇 |
2005年 | 6785篇 |
2004年 | 6075篇 |
2003年 | 4331篇 |
2002年 | 2594篇 |
2001年 | 2501篇 |
2000年 | 1711篇 |
1999年 | 1414篇 |
1998年 | 1229篇 |
1997年 | 1106篇 |
1996年 | 936篇 |
1995年 | 870篇 |
1994年 | 852篇 |
1993年 | 831篇 |
1992年 | 1024篇 |
1991年 | 1078篇 |
1990年 | 1002篇 |
1989年 | 1004篇 |
1988年 | 911篇 |
1987年 | 819篇 |
1986年 | 777篇 |
1985年 | 898篇 |
1984年 | 986篇 |
1983年 | 840篇 |
1982年 | 851篇 |
1981年 | 762篇 |
1980年 | 713篇 |
1979年 | 796篇 |
1978年 | 914篇 |
1977年 | 932篇 |
1976年 | 886篇 |
1975年 | 805篇 |
1974年 | 828篇 |
1973年 | 805篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
92.
93.
K. P. O. Mahesh M. Sivakumar Y. Yamamoto Y. Tsujita H. Yoshimizu S. Okamoto 《Journal of Polymer Science.Polymer Physics》2004,42(18):3439-3446
A crystalline δ form of a syndiotactic polystyrene (sPS) membrane was prepared from a solution of sPS (1 wt %) and p‐chlorotoluene (p‐CT) by a solution‐casting method. The mesophase (δ empty form) of sPS was obtained by the extraction of the guest solvent from the δ form of sPS by a stepwise solvent‐extraction method. The sPS/p‐CT mesophase membrane [p‐CT (A‐M)] was used for the sorption of 1 mol % p‐CT for different times and for the sorption of different concentrations of p‐CT, chlorobenzene (CB), p‐xylene (p‐X), toluene, and chloroform for 48 h. The presence of solvents in the sPS membrane was confirmed by IR analysis. A thermal study revealed that the sorption amount of 1 mol % p‐CT increased with increasing immersion time, and the sorption amounts of different solvents increased with increasing solvent concentration. Differential scanning calorimetry results showed that the desorption peak temperature increased as the amount of the solvent increased in the clathrated sPS membrane. Wide‐angle X‐ray diffraction results showed that 2θ at 8.25° was slightly shifted toward 8°, and there was no change in the peak position at 10° for p‐CT (A‐M), which was immersed in different solvents (1 mol %); however, the intensity of 2θ at 10° was not similar for all the samples. Among the solvents used for the sorption studies at 1 mol %, p‐CT (A‐M) could sorb more p‐CT and CB than p‐X, toluene, and chloroform. The solvent sorption isotherm was the Langmuir sorption mechanism. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3439–3446, 2004 相似文献
94.
Sándor G?r?g 《Analytical sciences》2004,20(5):767-782
The development during the last 15 years and the state-of-the-art in the analysis of bulk steroid hormone drugs and hormone-like structures and pharmaceutical formulations made thereof are summarized. Other steroids (sterols, bile acids, cardiac glycosides, vitamins D) as well as biological-clinical aspects and pharmacokinetic and metabolic studies are excluded from this review. The state-of-the-art is summarized based on comparisons of monographs in the latest editions of the European Pharmacopoeia, United States Pharmacopoeia and the Japanese Pharmacopoeia. This is followed by sections dealing with new developments in the methodology for the fields of spectroscopic and spectrophotometric, chromatographic, electrophoretic and hyphenated techniques as well electroanalytical methods. The review is terminated by two problem-oriented sections: examples on impurity and degradation profiling as well as enantiomeric analysis. 相似文献
95.
The electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols on graphite electrodes was studied using cyclic voltammetry, chronoamperometry, constant-potential coulometry and preparative constant-potential electrolysis techniques. The data revealed that the reduction on graphite was irreversible and followed an EC mechanism. The diffusion coefficients and the number of electrons transferred were determined using the chronoamperometric Cottrell slope and the ultramicro disc Pt-electrode steady-state current. The number of electrons was also determined by bulk electrolysis. The compounds were subjected to constant-potential preparative electrolysis and the electrolysis products were purified and identified by spectroscopic methods. Based on these findings, a mechanism for the electro-reduction process is proposed. 相似文献
96.
A sequential injection methodology for the spectrophotometric determination of calcium, magnesium and alkalinity in water samples is proposed. A single manifold is used for the determination of the three analytes, and the same protocol sequence allows the sequential determination of calcium and magnesium (the sum corresponds to the water hardness). The determination of both metals is based on their reaction with cresolphtalein complexone; mutual interference is minimized by using 8-hydroxyquinoline for the determination of calcium and ethylene glycol-bis(beta-aminoethyl ether)-N,N,N',N'-tetraacetic acid (EGTA) for the determination of magnesium. Alkalinity determination is based on a reaction with acetic acid, and corresponding color change of Bromcresol Green. Working ranges of 0.5 - 5 mg dm(-3) for Ca, 0.5 - 10 mg dm(-3) for Mg, and 10 - 100 mg HCO3- dm(-3), for alkalinity have been achieved. The results for water samples were comparable to those of the reference methods and to a certified reference water sample. RSDs lower than 5% were obtained, a low reagent consumption and a reduced volume of effluent have been accomplished. The determination rate for calcium and magnesium is 80 h(-1), corresponding to 40 h(-1) per element, while 65 determinations of alkalinity per hour could be carried out. 相似文献
97.
Kinetic parameters of amino acid cations in an MK-40 ion-exchange membrane are calculated from the conductivity data. A theoretical quantum-chemical analysis of experimental activation energies for conduction suggests a mechanism of elementary act of transport of amino acid cations in the membrane. 相似文献
98.
We introduce extensions of the Mangasarian-Fromovitz and Abadie constraint qualifications to nonsmooth optimization problems with feasibility given by means of lower-level sets. We do not assume directional differentiability, but only upper semicontinuity of the defining functions. By deriving and reviewing primal first-order optimality conditions for nonsmooth problems, we motivate the formulations of the constraint qualifications. Then, we study their interrelation, and we show how they are related to the Slater condition for nonsmooth convex problems, to nonsmooth reverse-convex problems, to the stability of parametric feasible set mappings, and to alternative theorems for the derivation of dual first-order optimality conditions.In the literature on general semi-infinite programming problems, a number of formally different extensions of the Mangasarian-Fromovitz constraint qualification have been introduced recently under different structural assumptions. We show that all these extensions are unified by the constraint qualification presented here. 相似文献
99.
V E Krivonozhko O B Utkin A V Volodin I A Sablin M Patrin 《The Journal of the Operational Research Society》2004,55(10):1049-1058
The aim of the paper is to present and substantiate a technique to visualize DEA modelling results without any loss of mathematical rigour. The proposed family of parametric optimization methods allows one to construct an intersection of the multidimensional frontier with a two-dimensional plane determined by any pair of given directions. This approach reduces the efficiency analysis of production units to the investigation of well-known functions in economics. We also propose constructive methods to calculate marginal rates of substitution, marginal rates of transformation and so on. 相似文献
100.