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排序方式: 共有195条查询结果,搜索用时 15 毫秒
71.
A porphycene having four CF3 groups at the beta-pyrrolic positions affords a stable 20pi-conjugated form in the presence of a 2H+-2e- donor due to the high redox potential of the tetrapyrrole ring framework. No visible band in the UV-vis spectrum and the highly ruffled structure determined by X-ray crystallography support its nonaromatic character. The ethylene bridge moiety in the 20pi-conjugated framework displayed the olefinic reactivities. 相似文献
72.
Yasushi Narushima Nobuko Sagara Hideho Ogasawara 《Journal of Optimization Theory and Applications》2011,149(1):79-101
The second-order cone complementarity problem (SOCCP) is an important class of problems containing a lot of optimization problems.
The SOCCP can be transformed into a system of nonsmooth equations. To solve this nonsmooth system, smoothing techniques are
often used. Fukushima, Luo and Tseng (SIAM J. Optim. 12:436–460, 2001) studied concrete theories and properties of smoothing functions for the SOCCP. Recently, a practical computational method
using the smoothed natural residual function to solve the SOCCP was given by Chen, Sun and Sun (Comput. Optim. Appl. 25:39–56,
2003). In the present paper, we propose an algorithm to solve the SOCCP by using the smoothed Fischer-Burmeister function. Some
preliminary numerical results are given. 相似文献
73.
Matsumoto M Suzuki H Watanabe N Ijuin HK Tanaka J Tanaka C 《The Journal of organic chemistry》2011,76(12):5006-5017
Thermally stable rotamers of bicyclic dioxetanes bearing 6-hydroxynaphthalen-1-yl (anti-5a and syn-5a), 3-hydroxynaphthalen-1-yl (anti-5b and syn-5b), and 5-hydroxy-2-methylphenyl groups (anti-5c and syn-5c) were synthesized. These dioxetanes underwent TBAF (tetrabutylammonium fluoride)-induced decomposition accompanied by the emission of light in DMSO and in acetonitrile at 25 °C. For all three pairs of rotamers, the chemiluminescence efficiency Φ(CL) for anti-5 was 8-19 times higher than that for syn-5, and the rate of CTID (charge-transfer-induced decomposition) for anti-5 was faster than that for syn-5. The chemiluminescence spectra of the rotamers for 5a and 5c, respectively, were different. This discrepancy in the chemiluminescence spectra between rotamers can presumably be attributed to the difference in the structures of de novo keto imide anti-14 and syn-14 in an excited state, which inherit the structures of the corresponding intermediary anionic dioxetanes anti-13 and syn-13. The important difference in chemiluminescence efficiency between anti-5 and syn-5 is discussed from the viewpoint of a chemiexcitation mechanism for CTID of oxidophenyl-substituted dioxetane. 相似文献
74.
N Yamashita N Konishi T Tanaka M Okubo 《Langmuir : the ACS journal of surfaces and colloids》2012,28(35):12886-12892
Micrometer-sized, hemispherical particles were successfully prepared as a result of the cleavage of Janus PMMA/PS composite particles by dispersion into acetone/water (9/1-10/0 v/v) media or a THF/water (8/2 v/v) medium. The spherical composite particles having a Janus structure were prepared by the slow evaporation of toluene from homogeneous PMMA/PS/toluene droplets dispersed in an aqueous medium in advance. It was clarified that the difference in affinity between PMMA and PS phases with respect to the media caused the cleavage of the composite particles. This method is expected to be a novel approach to the preparation of nonspherical polymer particles. 相似文献
75.
76.
77.
Federica Pozzi Nobuko Shibayama Marco Leona John R. Lombardi 《Journal of Raman spectroscopy : JRS》2013,44(1):102-107
Surface‐enhanced Raman spectroscopy (SERS) has found increasing acceptance in art conservation and forensic science for its great potential in detecting trace amounts of material. However, SERS is not a separation technique, and, therefore, it is not always suitable for distinguishing different components in a mixture. Coupling of thin layer chromatography (TLC) and SERS has been investigated in this article as a tool for the separation and identification of four alkaloids, namely harmalol, harmaline, harmane and harmine, from the seed extract of Syrian rue (Peganum harmala). The alkaloids contained in this plant were historically used as a dye and for medicinal purposes and have recently drawn attention due to their antitumor activity. The use of TLC over high‐performance liquid chromatography (HPLC) is a convenient way to reduce the amount of material, equipment and time needed for the analysis, and coupling of TLC with SERS provides vibrational information on each compound in the mixture. HPLC analyses with diode array detection were also carried out as a test of our technique, to ascertain the composition of Syrian rue extract and validate the results obtained from TLC‐SERS investigations. In addition, Syrian rue extract and its commercial alkaloid components were characterized by SERS and normal Raman spectroscopy here for the first time, in order to provide valuable reference data to be used for identification purposes. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
78.
This paper focuses on Bezout equations derived from multivariate polynomial matrices in which relationships between one primary variable and other variables are described by real entire functions. We propose a method for obtaining a solution belonging to a set of multivariate rational function matrices in which all entries are real entire functions with respect to the primary variable. The proposed method is based on a new approach that overcomes the constraints and difficulties due to many variables by expanding a class of solutions to multivariate rational function matrices. 相似文献
79.
A Aijaz A Karkamkar YJ Choi N Tsumori E Rönnebro T Autrey H Shioyama Q Xu 《Journal of the American Chemical Society》2012,134(34):13926-13929
Ultrafine Pt nanoparticles were successfully immobilized inside the pores of a metal-organic framework, MIL-101, without aggregation of Pt nanoparticles on the external surfaces of framework by using a "double solvents" method. TEM and electron tomographic measurements clearly demonstrated the uniform three-dimensional distribution of the ultrafine Pt NPs throughout the interior cavities of MIL-101. The resulting Pt@MIL-101 composites represent the first highly active MOF-immobilized metal nanocatalysts for catalytic reactions in all three phases: liquid-phase ammonia borane hydrolysis, solid-phase ammonia borane thermal dehydrogenation, and gas-phase CO oxidation. 相似文献
80.
Masakatsu Matsumoto Fumihiko Kakuno Aoi Kikkawa Naoyuki Hoshiya Nobuko Watanabe Hisako K. Ijuin 《Tetrahedron letters》2009,50(20):2337-2341
Bicyclic dioxetane 5 bearing a 3-hydroxynaphthalen-2-yl group and its analogs 14 and 15 decomposed to give light with efficiencies of only 0.002-0.005% in a tetrabutylammonium fluoride (TBAF)/THF system, which was as expected for dioxetanes with a so-called ‘even’ substitution pattern. However, the chemiluminescence efficiencies (ΦCL) markedly increased when these dioxetanes were decomposed with alkaline metal t-butoxide in THF. This enhancement of ΦCL by alkaline metal ion was most likely due to the highly ordered conformation of an aromatic ring by chelate formation of the metal ion with both an oxido anion and oxygen atom of a tetrahydrofuran ring in an intermediary dioxetane like 12. Alkaline metal ion-enhanced chemiluminescence was similarly observed for dioxetane 6 bearing a 2-hydroxyphenyl group. 相似文献