Slippage of nonsuperfluid helium films

We measured the mechanical response of 3He and 4He films on an oscillating substrate using an ultrasonic technique. Up to the coverage at which the fluid state appears at absolute zero, a part of the nonsuperfluid 3He and 4He films underwent slipping relative to the substrate at low temperatures. From the temperature dependence of the slippage, it was found that a thermally activated process plays an important role in the frictional force of this system.     

The reaction of hydrogen atoms with 1-butanethiol and thiolane the role of chemically activated 1-butanethiol

The reaction of 1-butanethiol with hydrogen atoms has been studied at temperatures of 295° and 576° K under the pressure of 660 Pa, using a conventional discharge-flow apparatus. The reaction products (besides hydrogen sulfide and methane) under the low conversion range (～10%) consisted mainly of n-butane, 1-butene, and propylene-propane, with the relative yields of 70, 25, and 5% at 295° K and 25, 50, and 10% at 576°K. Analysis of kinetic equations by numerical integration indicates that the following initial steps are consistent with the experimental results: where the following expressions have been derived for k₁ and k₂: The subsequent reaction of the butylthio radical with hydrogen atoms leads to the chemically activated 1-butanethiol which either stabilizes to 1-butanethiol or decomposes to 1-butene and hydrogen sulfide, depending on the experimental conditions. A similar analysis of the data on the thiolane-H system has yielded the following rate parameters for the initial step to form the 4-mercapto-1-butyl radical: .     

Synthesis of a novel C-6 nigrogen-substituted carbapenem from 6-aminopenicillanic acid

Synthesis of optically active 6-phthalimidocarbapenems from 6-aminopenicillanic acid is described.     

Novel method for linking CdS nanoparticles at liquid-liquid interface

Liquid-liquid interface of water-hexane provides a unique reaction environment in which CdS nanoparticles capped with mercaptoethylamine could be linked together to form a homodimer with a divalent acid chloride, sebacoyl chloride. Prior to the reaction, mercaptoethylamine-capped CdS in aqueous solution was purified by dialysis and freeze-drying. The observation with a transmission electron microscope suggested the formation of a homodimer of CdS nanoparticles.     

Heat transfer enhancement in a turbulent natural convection boundary layer along a vertical flat plate

An experimental study on heat transfer enhancement for a turbulent natural convection boundary layer in air along a vertical flat plate has been performed by inserting a long flat plate in the spanwise direction (simple heat transfer promoter) and short flat plates aligned in the spanwise direction (split heat transfer promoter) with clearances into the near-wall region of the boundary layer. For a simple heat transfer promoter, the heat transfer coefficients increase by a peak value of approximately 37% in the downstream region of the promoter compared with those in the usual turbulent natural convection boundary layer. It is found from flow visualization and simultaneous measurements of the flow and thermal fields with hot- and cold-wires that such increase of heat transfer coefficients is mainly caused by the deflection of flows toward the outer region of the boundary layer and the invasion of low-temperature fluids from the outer region to the near-wall region with large-scale vortex motions riding out the promoter. However, heat transfer coefficients for a split heat transfer promoter exhibit an increase in peak value of approximately 60% in the downstream region of the promoter. Flow visualization and PIV measurements show that such remarkable heat transfer enhancement is attributed to longitudinal vortices generated by flows passing through the clearances of the promoter in addition to large-scale vortex motions riding out the promoter. Consequently, it is concluded that heat transfer enhancement of the turbulent natural convection boundary layer can be substantially achieved in a wide area of the turbulent natural convection boundary layer by employing multiple column split heat transfer promoters. It may be expected that the heat transfer enhancement in excess of approximately 40% can be accomplished by inserting such promoters.     

Variational formulation of stability problems for thin-walled members

Summary The governing equations for thin-walled members subjected to axial force, biaxial bending and torsion are formulated by variational method. The resulting equations differ slightly with currently accepted governing equations. Numerical examples are solved for simple problems to illustrate some of the features of the proposed equations.

---

Übersicht Die beschreibenden Differentialgleichungen für dünnwandige Bauglieder, die durch achsiale Kräfte, biachsiale Biegung und Torsion beansprucht sind, werden nach einem Variationsverfahren aufgestellt. Die so erhaltenen Gleichungen unterscheiden sich etwas von den zur Zeit üblichen Gleichungen. Um die Eigenschaften der jetzt vorgeschlagenen Gleichungen zu zeigen, werden numerische Ergebnisse für einige einfache Aufgaben angegeben.

---

---

On leave from University of Tokyo, Tokyo Japan.     

Partial Protection of Carbohydrate Derivatives. Part 21. Lead(II) Nitrate Mediated Triisopropylsilyl Ether Formation; Preparation of 2′-Deoxy-3′-O-triisopropylsilylribonucleosides

Introduction of the triisopropylsilyl protecting group to the 3′-position of 5′-O-aroyl-2′-deoxyribonucleosides wa effectively performed by the use of triisopropylsilyl chlor ide in DMF in the presence of pyridine and lead(II) nitrate the latter was substituted in this reaction for silver nitr ate. Simple treatment of the resulting triisopropylsilyl ethers with sodium methoxide in THF gave 2′-deoxy-3′-O-tri-isopropylsilylribonucleosides in excellent yields.     

Micro-PIV measurement and CFD analysis of a thin liquid flow between rotating and stationary disks

Abstract  

A strongly sheared flow in a thin liquid layer between rotating and stationary disks is studied experimentally and numerically to clarify the characteristics of the flow in rotation-shearing chemical reactors. The disk diameter is 10 mm and the separation between the disks is 500 μm. The rotational speeds that are examined are 300, 500 and 700 rpm. The micro-PIV technique is used to measure the velocity in the liquid layer. A commercial CFD software is also used to obtain the results for the comparison and validation purposes. The overall velocity distributions revealed by the micro-PIV measurement are in good agreement with the CFD results. Both results show some interesting characteristics of the flow field, including the presence of a secondary flow and its influence on the tangential velocity profiles. The near-wall measurement in the micro-PIV technique is appreciably improved by the use of a simple digital, high-pass filtering technique that is applied to the acquired particle images. It is found that the flow characteristics in the thin liquid layer can be evaluated efficiently if the micro-PIV technique is used together with the high-pass filtering technique that is examined here.     

Synthesis of 5'-terminal capped oligonucleotides using O-N phosphoryl migration of phosphoramidite derivatives

Trivalent phosphoramidite derivatives could be readily converted by reacting with 1-hydroxy-7-azabenzotriazole to phosphotriester intermediates; these intermediates reacted smoothly with phosphorylated compounds to give pyrophosphate derivatives. This new phosphorylation approach enabled a facile and rapid synthesis of 5'-adenylated DNA oligomers (A(5')ppDNA) on resins using a silyl-type linker. Our new approach could be applied to the synthesis of a 2'-OMe-RNA oligomer containing the 5'-terminal 2,2,7-trimethylguanosine cap structure.