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221.
222.
Jie Xue Liang Chen Li Zhou Zhifeng Jia Yanping Wang Xinyuan Zhu Deyue Yan 《Journal of Polymer Science.Polymer Physics》2006,44(15):2050-2057
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006 相似文献
223.
The theory of Ribaucour transformations for hypersurfaces in space forms is established. For any such hypersurface M, that admits orthonormal principal vector fields, it was shown the existence of a totally umbilic hypersurface locally associated to M by a Ribaucour transformation. A method of obtaining linear Weingarten surfaces in a three-dimensional space form is provided. By applying the theory, a new one-parameter family of complete constant mean curvature (cmc) surfaces in the unit sphere, locally associated to the flat torus, is obtained. The family contains a class of complete cmc cylinders in the sphere. In particular, one gets a family of complete minimal surfaces and minimal cylinders, locally associated to the Clifford torus.Mathematics Subject Classifications (2000): 53C20. 相似文献
224.
225.
Recently, molecular imaging has been rapidly developed to studyphysiological and pathological processes in vivo at the cellularand molecular levels. Among molecular imaging modalities, opticalimaging has attracted a major attention for its unique advantages.In this paper, we establish a mathematical framework for multispectralbioluminescence tomography (BLT) that allows simultaneous studiesof multiple optical reporters. We show solution existence, uniquenessand continuous dependence on data as well as the limiting behaviourswhen the regularization parameter approaches zero or when thepenalty parameter approaches infinity. Then, we propose twonumerical schemes for multispectral BLT and derive error estimatesfor the corresponding solutions. 相似文献
226.
The three dimensional problem of steady fluid deposition on an inclined rotating disk is solved by similarity transform. For a given spraying rate there may be one, two or no steady state solution. The inclination causes a downward draining flow and a lateral flow. Perturbation solutions compare well with exact similarity solutions when the fluid film is thin. 相似文献
227.
Z.G. Xiao R.J. HuH.Y. Wu G.M. JinZ.Y. Li L.M. DuanH.W. Wang B.G. ZhangS.F. Wang Z.Y. WeiH.S. Xu Y.T. ZhuS.L. Li F. FuX.H. Yuan Z.Q. Feng 《Physics letters. [Part B]》2006
The inclusive reduced velocity correlation functions of the intermediate mass fragments were measured in the reactions of 36Ar + 112,124Sn at 35 MeV/u. The anti-correlation is observed to be stronger in 36Ar + 124Sn system than that in 36Ar + 112Sn. The difference of the correlation functions between the two reactions is mainly contributed by the particle pairs with high momenta. A three body Coulomb repulsive trajectory model is employed to calculate the emission time scale of the IMFs for the two systems. The time scale is 150 fm/c in 36Ar + 112Sn and 120 fm/c in the 36Ar + 124Sn, respectively. 相似文献
228.
Jiaqiang Wang Hua Fang Ying Li Junjie Li Zhiying Yan 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):75-79
Cobalt-doped mesoporous titania with a crystalline framework synthesized by surfactant templating method presented highly selective (99%) and reasonable conversion rate (49%) of catalytic oxidation of para-chlorotoluene to para-chlorobenzaldehyde in acetic acid using aqueous hydrogen peroxide as oxidant for the first time. Recycling of the catalyst indicates that the catalyst can be used a number of times without losing its activity to a greater extent. By contrast, cobalt-doped mesoporous titania without a crystalline structure and cobalt doped the commercial titania, Degussa P25 prepared by impregnation method with the similar concentration of cobalt were found inactive. The effects of catalyst concentration, reaction time, reaction temperature, and solvents on the performance of the catalyst were also investigated. 相似文献
229.
Xiao-Hong Xu Xiao-Li Li Fang Wang Feng-Xian Jiang Hai-Shun Wu 《Applied Surface Science》2006,252(8):2910-2914
FexPt100−x(30 nm) and [FexPt100−x(3 nm)/ZrO2]10 (x = 37, 48, 57, 63, 69) films with different ZrO2 content were prepared by RF magnetron sputtering technique, then were annealed at 550 °C for 30 min. This work investigates the effect of ZrO2 doping on the microstructural evolution, magnetic properties, grain size, as well as the ordering kinetics of FePt alloy films. The as-deposited films behaved a disordered state, and the ordered L10 structure was obtained by post-annealing. The magnetic properties of the films are changed from soft magnetism to hard magnetism after annealing. The variation of the largest coercivities of [FexPt100−x/ZrO2]10 films with the Fe atomic percentage, x and differing amounts of ZrO2 content reveals that as we increase the ZrO2 content we must correspondingly increase the amount of Fe. This phenomenon suggests that the Zr or O atoms of ZrO2 preferentially react with the Fe atoms of FePt alloy to form compounds. In addition, introducing the nonmagnetic ZrO2 can reduce the intergrain exchange interactions of the FePt/ZrO2 films, and the interactions are decreased as the ZrO2 content increases, the dipole interactions are observed in FePt/ZrO2 films as the ZrO2 content is more than 15%. 相似文献
230.
We have prepared composite magnetic core–shell particles using the process of soap-free emulsion polymerization and the co-precipitation method. The shell of the synthesized composite sphere is cobalt ferrite (CoFe2O4) nanoparticles and the core consists of poly(styrene-co-methacrylic acid) polymer. The mean crystallite sizes of the coated CoFe2O4 nanoparticles were controlled in the range of 2.4–6.7 nm by the concentration of [NH4+] and heated temperature. The magnetic properties of the core–shell spherical particles can go from superparamagnetic to ferromagnetic behavior depending on the crystalline sizes of CoFe2O4. 相似文献