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101.
Nataliya Yu. Strutynska Vyacheslav N. Baumer Igor V. Zatovsky Artem A. Babaryk Nikolay S. Slobodyanik 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(4):i39-i41
The complex phosphate tricaesium calcium iron bis(diphosphate), Cs3CaFe(P2O7)2, has been prepared by the flux method. Isolated [FeO5] and [CaO6] polyhedra are linked by two types of P2O7 groups into a three‐dimensional framework. The latter is penetrated by hexagonal channels along the a axis where three Cs atoms are located. Calculations of caesium Voronoi–Dirichlet polyhedra give coordination schemes for the three Cs atoms as [8 + 3], [9 + 1] and [9 + 4]. The structure includes features of both two‐ and three‐dimensional frameworks of caesium double pyrophosphates. 相似文献
102.
Igor V. Zatovsky Nikolay S. Slobodyanik V. I. Ivanenko Yu. S. Oseledchik V. Yu. Letsenko Tetiana I. Ushchapivska 《Crystal Research and Technology》2016,51(2):178-182
Solid solutions KTi1‐XHfXOPO4 (х = 0.008 – 0.107) possessing the KTiOPO4 structure, have been synthesized in molten system K2O‐P2O5‐TiO2‐HfF4. The crystal growth experiment of Hf‐doped KTP crystal has been reported. The X‐ray powder diffraction data and chemical analysis are also presented. It has been shown that KTiOPO4 crystal structure slightly changes when Hf incorporates into the framework. Transmission/absorption spectra of KTi0.974Hf0.026OPO4 crystals have been recorded. The incorporation of Hf ions shifts the optical absorption edge in the UV‐visible spectrum towards the long‐wavelength region with absorption near 387 nm. 相似文献
103.
We introduce a microacoustic sensor, which combines the quartz crystal microbalance, a liquid-filled cavity and an intermediate artificial layer with effective acoustic properties. Each of the three components fulfils a specific task. The quartz vibrates in its thickness shear mode and acts as source and detector of shear waves, which penetrate the intermediate artificial layer and excite a resonance in the liquid-filled cavity. Both the piezoelectric transducer and the liquid-filled cavity are high-Q resonators with well-adjusted resonance frequencies very close to each other. The intermediate artificial layer couples the two resonators in a distinct manner via control of the propagation of acoustic waves between the quartz crystal and the liquid-filled cavity layer. The origin of the sensor signal is a change of the resonance frequency of the liquid-filled cavity caused by variations of acoustic properties of the liquid analyte inside the cavity, first of all speed of sound. This resonance appears as second resonance peak in the admittance spectrum of the quartz crystal. 相似文献
104.
105.
Andrey B. Koldobskii Nikolay P. Tsvetkov Ekaterina V. Solodova Valery N. Kalinin 《Journal of fluorine chemistry》2010,131(8):852-9595
This paper describes a novel synthetic approach to 2-cyano-3-trifluoromethylthiophenes fused with cyclobutene rings with variable spiro conjunctions. The reaction of substituted 1-bromo-2-trifluoroacetylcyclobutenes with mercaptoacetonitrile results in the substitution of bromine with S-center to afford the corresponding nitriles in high yields, which form the target thiophenes by subsequent treatment of lithium 2,2,6,6-tetramethylpiperidide and acetic anhydride. 相似文献
106.
Nikolay L. Aleksandrov 《Proceedings of the Combustion Institute》2009,32(1):205-212
The kinetics of ignition in stoichiometric CnH2n+2:O2:Ar mixtures with 90% dilution for n = 1-5 has been studied experimentally and numerically under the action of a high-voltage nanosecond discharge. It was shown that the initiation of the discharge by a high-voltage pulse 115 kV in amplitude with a specific deposited energy of 10-30 mJ/cm3 leads to more than an order of magnitude decrease in the ignition delay time. The generation of atoms, radicals and excited and charged particles by the discharge was numerically described. The role of different atoms and radicals (O, H and CnH2n+1) was analyzed. The temporal evolution of the densities of intermediate components in the plasma assisted ignition was discussed. 相似文献
107.
A method for constructing binary self-dual codes having an automorphism of order p
2 for an odd prime p is presented in (S. Bouyuklieva et al. IEEE. Trans. Inform. Theory, 51, 3678–3686, 2005). Using this method, we investigate
the optimal self-dual codes of lengths 60 ≤ n ≤ 66 having an automorphism of order 9 with six 9-cycles, t cycles of length 3 and f fixed points. We classify all self-dual [60,30,12] and [62,31,12] codes possessing such an automorphism, and we construct
many doubly-even [64,32,12] and singly-even [66,33,12] codes. Some of the constructed codes of lengths 62 and 66 are with
weight enumerators for which the existence of codes was not known until now.
相似文献
108.
Dendronized Hyperbranched Macromolecules: Soft Matter with a Novel Type of Segmental Distribution 下载免费PDF全文
Priv.‐Doz. Dr. Albena Lederer Prof. Dr. Walther Burchard Tobias Hartmann Johannes S. Haataja Dr. Nikolay Houbenov Andreas Janke Dr. Peter Friedel Dr. Ralf Schweins Dr. Peter Lindner 《Angewandte Chemie (International ed. in English)》2015,54(43):12578-12583
Dendronization of a hyperbranched polyester with different generation dendrons leads to pseudo‐dendritic structures. The hyperbranched core is modified by the divergent coupling of protected monomer units to the functional groups. Compared to dendrimers, the synthetic effort is significantly less, but the properties are very close to those of high‐generation dendrimers. The number of functional groups, molar mass, and rheology behavior even in the early generation (G1–G4) pseudo‐dendrimers strongly resembles the behavior of dendrimers in higher generations (G5–G8). Comparison of the segmental and internal structure with perfect dendrimers is performed using SANS, dynamic light scattering and viscosity analysis, microscopy and molecular dynamics simulation. The interpretation of the results reveals unique structural characteristics arising from lower segmental density of the core, which turns into a soft nano‐sphere with a smooth surface even in the first generation. 相似文献
109.
110.
Nikolay Kuznetsov 《Comptes Rendus Mecanique》2004,332(1):73-78
This Note deals with the linearized water-wave problem involving a surface-piercing cylinder in water of infinite depth. A solution to this problem is proved to be unique for all values of the radian frequency when the cylinder intersecting the free surface at arbitrary angles is subjected to certain geometric arrangements. To cite this article: N. Kuznetsov, C. R. Mecanique 332 (2004). 相似文献