全文获取类型
收费全文 | 546篇 |
免费 | 12篇 |
专业分类
化学 | 237篇 |
晶体学 | 5篇 |
力学 | 7篇 |
数学 | 240篇 |
物理学 | 69篇 |
出版年
2019年 | 6篇 |
2015年 | 7篇 |
2014年 | 9篇 |
2013年 | 28篇 |
2012年 | 14篇 |
2011年 | 11篇 |
2010年 | 10篇 |
2009年 | 15篇 |
2008年 | 16篇 |
2007年 | 16篇 |
2006年 | 18篇 |
2005年 | 20篇 |
2004年 | 28篇 |
2003年 | 12篇 |
2002年 | 13篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1987年 | 5篇 |
1985年 | 5篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 12篇 |
1981年 | 5篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1976年 | 10篇 |
1975年 | 8篇 |
1974年 | 11篇 |
1973年 | 8篇 |
1972年 | 9篇 |
1971年 | 6篇 |
1970年 | 8篇 |
1969年 | 8篇 |
1968年 | 9篇 |
1967年 | 6篇 |
1966年 | 7篇 |
1964年 | 5篇 |
1963年 | 6篇 |
1962年 | 5篇 |
1958年 | 5篇 |
1957年 | 9篇 |
1955年 | 5篇 |
1948年 | 5篇 |
1941年 | 10篇 |
1937年 | 7篇 |
1936年 | 5篇 |
1935年 | 15篇 |
1933年 | 10篇 |
排序方式: 共有558条查询结果,搜索用时 578 毫秒
121.
The analysis and improvement of an immersed boundary method (IBM) for simulating turbulent flows over complex geometries are presented. Direct forcing is employed. It consists in interpolating boundary conditions from the solid body to the Cartesian mesh on which the computation is performed. Lagrange and least squares high‐order interpolations are considered. The direct forcing IBM is implemented in an incompressible finite volume Navier–Stokes solver for direct numerical simulations (DNS) and large eddy simulations (LES) on staggered grids. An algorithm to identify the body and construct the interpolation schemes for arbitrarily complex geometries consisting of triangular elements is presented. A matrix stability analysis of both interpolation schemes demonstrates the superiority of least squares interpolation over Lagrange interpolation in terms of stability. Preservation of time and space accuracy of the original solver is proven with the laminar two‐dimensional Taylor–Couette flow. Finally, practicability of the method for simulating complex flows is demonstrated with the computation of the fully turbulent three‐dimensional flow in an air‐conditioning exhaust pipe. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
122.
In this paper, we consider set covering problems with a coefficient matrix almost having the consecutive ones property, i.e., in most rows of the coefficient matrix, the ones appear consecutively and only a few blocks of consecutive ones appear in the remaining rows. If this property holds for all rows it is well known that the set covering problem can be solved efficiently. For our case of almost consecutive ones we present a reformulation exploiting the consecutive ones structure to develop bounds and a branching scheme. Our approach has been tested on real-world data as well as on theoretical problem instances. 相似文献
123.
From Klebsiella pneumoniae (+)(11S, 11aS) - 1,2,3,10,11,11a - hexahydro - 9 - hydroxy - 11 - (3′ - indolyl) - 5H - pyrrolo[2,1-c][1,4]benzodiazepin - 5 - one (1) has been isolated for which the name tilivalline is suggested. Structure elucidation and synthesis are reported. 相似文献
124.
The Structure of [HSi9]3− in the Solid State and Its Unexpected Highly Dynamic Behavior in Solution 下载免费PDF全文
Corinna Lorenz Florian Hastreiter Dr. Johnny Hioe Dr. N. Lokesh Dr. Stefanie Gärtner Prof. Dr. Nikolaus Korber Prof. Dr. Ruth M. Gschwind 《Angewandte Chemie (International ed. in English)》2018,57(39):12956-12960
We report on the first unambiguous detection of the elusive [HSi9]3? anion in solutions of liquid ammonia by various 29Si and 1H NMR experiments including chemical exchange saturation transfer (CEST). The characteristic multiplicity patterns of both the 29Si and 1H resonances together with CEST and a partially reduced 1H,29Si coupling constant indicate the presence of a highly dynamic Si8 entity and a Si?H moiety with slow proton hopping. Theoretical calculations corroborate both reorganization of Si8 on the picosecond timescale via low vibrational modes and proton hopping. In addition, in a single‐crystal X‐ray study of (K(DB[18]crown‐6))(K([2.2.2]crypt))2[ HSi9 ]?8.5 NH3, the H atom was unequivocally localized at one vertex of the basal square of the monocapped square‐antiprismatic cluster. Thus experimental studies and theoretical considerations provide unprecedented insight into both the structure and the dynamic behavior of these cluster anions, which hitherto had been considered to be rigid. 相似文献
125.
Roland A. Fischer Dana Weiß Iris Müller Nikolaus Fröhlich Gernot Frenking 《Journal of organometallic chemistry》2004,689(24):4611-4623
The reactions of the sterically demanding group-13 alkyls ER3 (E = Al, Ga, In; R = CH2t-Bu, CH2SiMe3) with the platinum-complex [(dcpe)Pt(H)(CH2t-Bu)] were re-investigated. The bimetallic compounds [(dcpe)Pt(ER2)(R)] (3: E = Ga, R = CH2SiMe3; 5: E = In, R = CH2t-Bu; dcpe = bis(dicyclohexylphosphino)ethane) with direct σ(Pt-E) bonds were obtained by oxidative addition of an E-C bond to the coordinatively unsaturated fragment [(dcpe)Pt] produced in situ by thermolysis of the starting complex [(dcpe)Pt(CH2t-Bu)(H)]. The single crystal structure determination reveals a Pt-Ga bond length of 2.376(2) Å and a Pt-In bond length of 2.608(1) Å. All new compounds were characterised by elemental analysis, 31P and 195Pt NMR spectroscopy. Interestingly, the Pt-Ga compound 3 slowly transforms into the platinum alkyl/hydride isomer {(dcpe)Pt(μ2-H)[CH2Si(CH3)2 CH2Ga(CH2SiMe3)2]} (4) during crystallization from solution at room temperature. The X-ray single crystal structure analysis revealed both complexes 3 and 4 coexisting in the unit cell in a 1:1 relation. The inaccessibility of analytically pure samples of the Pt-Al complex {(dcpe)Pt[Al(CH2t-Bu)2](CH2t-Bu)} (6), postulated as intermediate of the reaction of [(dcpe)Pt(H)(CH2t-Bu)] with Al(CH2t-Bu) on the basis of 31P and 195Pt NMR data, is attributed to an enhanced tendency to isomerisation into the alkyl/hydride Pt/Al congener of 4. A brief DFT analysis of the bonding situation of the model complex [(dhpe)Pt(GaMe2)(Me)] (1M) revealed, that the contribution of π(Pt-Ga) back-bonding is negligible. 相似文献
126.
Andreatta D Pérez Lustres JL Kovalenko SA Ernsting NP Murphy CJ Coleman RS Berg MA 《Journal of the American Chemical Society》2005,127(20):7270-7271
Time-resolved Stokes shifts in a dye-containing oligonucleotide have been observed over the entire time range from 40 fs to 40 ns. The dynamics fit to a power law with a small exponent of 0.15. Similar relaxation has been seen in proteins but has not been anticipated in DNA. Distinct relaxation components due to specific subcomponents of the system, bulk water, bound water, counterions, backbone, bases, and so on, are not found. The various subcomponents may be so strongly coupled that their motions cannot be treated separately. 相似文献
127.
Reduction of an excess of arsenic with a solution of sodium in liquid ammonia yields the thermally unstable title compound [Na(NH3)5]2As(4).3NH3, which contains isolated square-planar As4(2-) ions with a mean As-As bond length of 2,345 A. 相似文献
128.
Loening NM Rosay M Weis V Griffin RG 《Journal of the American Chemical Society》2002,124(30):8808-8809
The goal of dynamic nuclear polarization (DNP) is to enhance NMR signals by transferring electron spin polarization to the nuclei. Although mechanisms such as the solid effect and thermal mixing can be used for DNP in the solid state, currently, the only practical mechanism in solutions is the Overhauser effect (OE), which usually arises due to dipolar relaxation between electrons and the nuclei. At magnetic fields greater than approximately 1 T, dipolar relaxation does not result in a useful enhancement and therefore the conventional wisdom is that DNP should not work in solutions at high magnetic fields. However, scalar relaxation due to time-dependent scalar couplings has a different magnetic field dependence and can lead to substantial OE enhancements. At room temperature and at a magnetic field of 5 T (211 MHz for protons, 140 GHz for electrons), we have observed that scalar relaxation between electrons and nuclei results in NMR signal enhancements of 180, 42, -36, and 8, for 31P, 13C, 15N, and 19F, respectively. 相似文献
129.
Fernandez I Alvarez Gutierrez JM Kocher N Leusser D Stalke D Gonzalez J Lopez Ortiz F 《Journal of the American Chemical Society》2002,124(51):15184-15185
The first crystal structure of the lithium complex of a P-alkyl-P,P-diphenyl(N-methoxycarbonyl)phosphazene has been characterized. It is dimeric, with the anion chelating the lithium in an unusual six-membered ring. A monomer-dimer equilibrium has been identified in THF solution. Ab initio calculations indicated that the six-membered ring is electronically favored over an alternative Li-C-P-N four-membered ring. 相似文献
130.
P. Gerl F. Schweiger H. Lausch H. Mitsch H. Hornich N. Hofreiter R. Mück L. Schmetterer 《Monatshefte für Mathematik》1969,73(1):84-96
Ohne Zusammenfassung 相似文献