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11.
Kourkoumelis N Demertzis MA Kovala-Demertzi D Koutsodimou A Moukarika A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(10):2253-2259
The reactions of the potent and widely used anti-inflammatory drug diclofenac, HL, with diorganotin(IV) oxides were studied. The dimeric tetraorganodistannoxane complexes [Me(2)LSnOSnLMe(2)](2), [Bu(2)LSnOSnLBu(2)](2), [Ph(2)LSnOSnLPh(2)](2) and the dibutyltin complex [Bu(2)SnL(2)], have been prepared and structurally characterized in the solid state by means of vibrational and 119Sn M?ssbauer spectroscopy. Determination of lattice dynamics by temperature-dependent 119Sn M?ssbauer spectroscopy. From the variable-temperature M?ssbauer effect, the Debye temperature was determined. The complexes have been characterized in solution by NMR (1H and 13C) spectroscopy. Vibrational, M?ssbauer, and NMR data are discussed in terms of the proposed structures. 相似文献
12.
Bakaoukas N Kapolos J Koliadima A Karaiskakis G 《Journal of chromatography. A》2005,1087(1-2):169-176
Reversed-flow gas chromatography, which is a sub-technique of inverse gas chromatography, is an experimental arrangement simulating a simple model for the action of air pollutants on buildings and monuments, in laboratory scale. By using a commercial gas chromatograph and an appropriate mathematical analysis, kinetic parameters such as rate constants for adsorption k1, adsorption/desorption kR and surface reaction k2, as well as surface diffusion coefficients Dgamma, deposition velocities Vd and reaction probabilities gamma of SO2 on marble surfaces at different temperatures (303.15-353.15 K) in the presence or in the absence of protective materials (an acrylic copolymer, Paraloid B-72 or a siloxane, CTS Silo 111) were calculated. From the above mentioned physicochemical quantities the ability of the examined materials to minimize the dry deposition of SO2 on marble is carrying out and a possible mechanism for the interaction between SO2 and Paraloid B-72 was suggested. Both materials (CTS SILO 111 and Paraloid B-72) are good enough for protecting marble against SO2 at low temperatures (303.15-323.15), while at high temperatures (333.15-353.15), siloxane seems to protect marble better than acrylic copolymer. 相似文献
13.
Nikolaos A. Peppas George N. Valkanas Eugenia T. Diamanti-Kotsida 《Journal of polymer science. Part A, Polymer chemistry》1976,14(5):1241-1247
A new method for the production of polydimethylbenzylenes,$ \rlap{--} [{\rm C}_6 {\rm H}_4 ({\rm CH})_2 {\rm CH}_{\rm 2} \rlap{--} ]_n $, involves the polycondensation of the mono- and dichloromethyl and mono- and diacetoxymethyl derivatives of p-xylene via an acid-catalyzed reaction in anhydrous acetic acid. The reaction of the difunctional derivatives is slower than the reaction of the monofunctional ones, leading to linear, predominantly crystalline, high-melting polymers with molecular weights of 2000–3000. Polycondensation of both monomers under different feed ratios leads to polymers with the same structure, and the monofunctional monomers condense with themselves more favorably than with the difunctional ones. Thus a head-to-head structure is preferred, and crystalline polymers of high structural purity are obtained. 相似文献
14.
Rafael Mayorga-Gonzlez Miguel Rivera-Torrente Nikolaos Nikolopoulos Koen W. Bossers Roozbeh Valadian Joaquín Yus Beatriz Seoane Bert M. Weckhuysen Florian Meirer 《Chemical science》2021,12(24):8458
Metal–Organic Frameworks (MOFs) have the potential to change the landscape of molecular separations in chemical processes owing to their ability of selectively binding molecules. Their molecular sorting properties generally rely on the micro- and meso-pore structure, as well as on the presence of coordinatively unsaturated sites that interact with the different chemical species present in the feed. In this work, we show a first-of-its-kind tomographic imaging of the crystal morphology of a metal–organic framework by means of transmission X-ray microscopy (TXM), including a detailed data reconstruction and processing approach. Corroboration with Focused Ion Beam-Scanning Electron Microscopy (FIB-SEM) images shows the potential of this strategy for further (non-destructively) assessing the inner architecture of MOF crystals. By doing this, we have unraveled the presence of large voids in the internal structure of a MIL-47(V) crystal, which are typically thought of as rather homogeneous lattices. This challenges the established opinion that hydrothermal syntheses yield relatively defect-free material and sheds further light on the internal morphology of crystals.TXM-tomography unraveled large macropore defects within a MIL-47(V) MOF crystal. These pores do not seem to be well connected and they show a preferential orientation. 相似文献
15.
Nikolaos S. Papageorgiou 《Analysis Mathematica》1991,17(2):141-152
16.
Georgia Gatidou Nikolaos S. Thomaidis Themistokles D. Lekkas 《Analytica chimica acta》2005,528(1):89-99
A method for the simultaneous determination of two antifouling booster biocides, diuron (1-(3,4 dichlorophenyl) 3,3 dimethyl urea) and irgarol 1051 (2-methylthio-4-tert-butylamino-6-cyclopropylamino-s-triazine), and their metabolites, DCPMU (1-(3,4 dichlorophenyl)-3 methyl urea), DCPU (1-(3,4 dichlorophenyl) urea), DCA (3,4 dichloroaniline) and M1 (2-methylthio-4-tert-butylamino-s-triazine) in seawater by high performance liquid chromatography-diode array detector (HPLC-DAD) was developed. The optimization of the extraction procedure included the type of sorbent and the type of the organic solvent for the elution. Optimization of the liquid chromatography (LC) separation was also performed and the robustness of the developed separation was tested, in respect to the effect of three factors (column temperature, flow rate and initial strength of acetonitrile) on the retention times, peak resolution and peak area of the six compounds. The optimized procedure included off-line extraction of these compounds from seawater samples using C18 solid phase extraction (SPE) cartridges. The inter-day precision of the developed procedure was less than 14% (as R.S.D.s) for all the tested compounds. Satisfactory recoveries (higher than 82%) were obtained for all substances, except for DCA, for which low recovery was obtained (30.5%). The limits of detection (LODs) of the substances varied between 0.005 (DCPMU) and 0.026 (M1) μg L−1. 相似文献
17.
Nikolaos C. Papandreou Stella Makedonopoulou Ekaterini A. Antoniadou‐Vyza Irene M. Mavridis Stavros J. Hamodrakas 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(12):o730-o732
The title salt, C18H22N5+·Cl?, is a member of a new series of lipophilic 4,6‐diamino spiro‐s‐triazines which are potent inhibitors of dihydrofolate reductase. The protonated triazine ring deviates from planarity, whereas the cyclohexane ring adopts a chair conformation. A rather unusual hydrogen‐bonding scheme exists in the crystal. There is a centrosymmetric arrangement involving two amino groups and two triazine ring N atoms, with graph‐set R(8) and an N?N distance of 3.098 (3) Å, flanked by two additional R(8) systems, involving two amino groups, a triazine ring N atom and a Cl? anion, with N?Cl distances in the range 3.179 (2)–3.278 (2) Å. Furthermore, the Cl? anion, the protonated triazine ring N atom and an amino group form a hydrogen‐bonding system with graph‐set R(6). 相似文献
18.
Nikolaos Mourtzis Kyriaki Eliadou Konstantina Yannakopoulou 《Supramolecular chemistry》2013,25(8):587-593
Methyl Orange (MO), an azo-dye molecule with an inherent dipole moment, has been used as a probe to explore the influence of anionic or cationic substituents of cyclodextrins (CDs) on the mode of insertion to form pseudorotaxanes, using NMR spectroscopy. MO is oriented in a single mode inside the βCD cavity, with the dimethylamino group localized at the secondary side. This orientation is completely reversed when MO enters the anionic sodium heptakis[6-deoxy-6-(3-thiopropionate)]-βCD (βpsp) cavity, whereas inside the cationic heptakis(6-deoxy-6-amino)-βCD hydrochloride, MO flips once more, to adopt the same orientation as in βCD. In the latter case the water solubility of MO is significantly lowered. The disposition of the guest in βCD and in each βCD derivative in a single mode was attributed principally to anti-parallel dipole-dipole stabilization. In the wider γCD, the availability of more cavity space leads to 1:2 and 2:2 host/guest stoichiometries and the effect of dipoles is of secondary significance. In the anionic sodium octakis[6-deoxy-6-(3-thiopropionate)]-γCD, MO is positioned as in βpsp, but a 1:2 adduct is also detected. Finally, MO does not dissolve in octakis(6-deoxy-6-amino)-γCD hydrochloride solution. 相似文献
19.
Nikolaos Pahimanolis Arto Salminen Paavo A. Penttilä Juuso T. Korhonen Leena-Sisko Johansson Janne Ruokolainen Ritva Serimaa Jukka Seppälä 《Cellulose (London, England)》2013,20(3):1459-1468
In this paper, nanofibrillated cellulose/carboxymethyl cellulose (CMC) composite films were prepared using tape casting. The obtained transparent films showed shear induced partial alignment of fibrils along the casting direction, resulting in birefringence in cross polarized light. The carboxyl groups of CMC could be further utilized to create ionic crosslinking by treatment with glycidyl trimethyl ammonium chloride (GTMA). The GTMA treated composite films had improved mechanical properties both in wet and dry state. The chemical composition and morphologies of composites were analyzed with X-ray photoelectron spectroscopy, elemental analysis, scanning electron microscopy and wide-angle X-ray scattering. 相似文献
20.
We consider a nonlinear Neumann problem driven by the p -Laplacian plus an indefinite potential and a Carathéodory reaction which at ±∞ is resonant with respect to any nonprincipal variational eigenvalue of the differential operator. Using critical point theory and Morse theory (critical groups), we show that the problem has at least three nontrivial smooth solutions, two of which have constant sign. In the process we prove some results of independent interest concerning the unique continuation property of eigenfunctions and the critical groups at infinity of a C1-functionals. 相似文献