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191.
Q. Sun Q. Wang X.G. Gong V. Kumar Y. Kawazoe 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(1):77-81
We report results of the atomic and electronic structures of Al7C cluster using ab initio molecular dynamics with ultrasoft pseudopotentials and generalized gradient approximation. The lowest energy structure is
found to be the one in which carbon atom occupies an interstitial position in Al7 cluster. The electronic structure shows that the recent observation [Chem. Phys. Lett. 316, 31 (2000)] of magic behavior of Al7C- cluster is due to a large highest occupied and lowest unoccupied molecular orbital (HOMO-LUMO) gap which makes Al7C- chemically inert. These results have further led us to the finding of a new neutral magic cluster Al7N which has the same number of valence electrons as in Al7C- and a large HOMO-LUMO gap of 1.99 eV. Further, calculations have been carried out on (Al7N)2 to study interaction between magic clusters.
Received 28 July 2001 相似文献
192.
An overview of theoretical and experimental studies of the coherent type-B e
+
e-pair production by photons in aligned crystals performed at Nuclear Physics Institute at Tomsk Polytechnic University is given. 相似文献
193.
M. A. Augustyniak-Jabłokow K. Łukaszewicz A. Pietraszko V. E. Petrashen Yu. V. Yablokov 《Physics of the Solid State》2002,44(8):1480-1483
The EPR spectra evolution of Cs2Zn1?x Cux(ZrF6)2 · 6H2O (x=0.01, 0.6, 0.8, and 1.0) in the temperature range 4.2–330 K and the x-ray structure analysis of the compound with x=1.0 in the range 150–327 K show that the Jahn-Teller (JT) complex Cu(H2O)6 coordination sphere undergoes a plastic deformation. The observed effect is due to the combined influence of small lattice strains existing in the paraphase and a new one appearing as a result of a ferroelastic phase transition and increasing with decreasing temperature below T c . It is proved that both cooperative interactions between JT complexes and ferroelastic strain stabilize a certain JT configuration. The problem of instability of a JT configuration compressed at T ~ 265 K is discussed. 相似文献
194.
Discharges with liquid nonmetallic electrodes of much interest for applications are investigated. It is found that a dc discharge between two streams of tap water in air at atmospheric pressure is stable at a currentof 40≤I≤100 mA. The discharge exists in the diffuse (volume) form with a relatively low current density (∼0.2 A/cm2) and a high (above one kilovolt) voltage drop across the air gap (∼1 cm) between the water electrodes. The current density and voltage depend only slightly on the discharge current. Probe measurements show that three regions can be distinguished in the discharge: two electrode regions (1–2 mm in length) and a discharge column with a constant electric field of ≈0.8 kV/cm (i.e., E/N≈20 Td, because the gas in the discharge is heated up to 1500–2000 K). The average electric field strength near the electrodes is E≈2–3×103 V/cm (E/N≈60–80 Td). The charged particle density in the column is n ∼ 1012 cm−3. The probe measurements of n agree with the previous microwave absorption measurements. The water vapor concentration in the column is also estimated from probe measurements. 相似文献
195.
R. A. Ganeev A. I. Ryasnyanskii M. K. Kodirov Sh. R. Kamalov V. A. Li R. I. Tugushev T. Usmanov 《Technical Physics》2002,47(8):991-995
Nonlinear optical parameters (nonlinear refractive indices and nonlinear absorption coefficients) of solutions of polyvinylpyrrolidone doped by cobalt to various concentrations are measured at the lasing and second-harmonic wavelengths of a picosecond Nd:YAG laser (λ=1064 and 532 nm, respectively, and τ=35 ps). Data on optical limitation in these solutions are presented. The absence of nonlinear absorption in the IR spectral range and its significant effect in the visible range are demonstrated. Optical limitation at a wavelength of 1064 nm is related to defocusing, whereas at 532 nm, this effect is caused by two-photon absorption and partially by inverse saturated absorption and defocusing. Nonlinear optical parameters of metal-polymer complexes are reported. 相似文献
196.
A pressure sensitive paint (PSP) measurement has been known as a pressure field measurement technique based on the oxygen quenching phenomenon of luminescence of specific luminophores. A PSP measurement was applied for pressure field measurement in a low-solidity circular cascade diffuser of a single-stage transonic centrifugal compressor with 5 in pressure ratio for HFC134a gas. The oxygen concentration was about 500 ppm. Ru (bath-phen) was adsorbed on a silica-gel thinlayer chromatography sheet, and the sheet was pasted onto the side-wall between the cascade vanes. A drastic change in luminescent intensity was recognized during a surge condition. Also the pressure variations based on luminescent intensity agreed well with the pressure fluctuations measured using a semiconductor pressure sensor with high-frequency-response. It was shown that a PSP measurement worked well to investigate the unsteady pressure fields in a circular cascade diffuser of a transonic centrifugal compressor. Moreover, the time response of PSP becomes clear as a problem to be overcome for the present. 相似文献
197.
B. Dubrulle F. Hersant 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):379-386
We generalize an analogy between rotating and stratified shear flows. This analogy is summarized in Table 1. We use this analogy
in the unstable case (centrifugally unstable flow vs. convection) to compute the torque in Taylor-Couette configuration, as a function of the Reynolds number. At low Reynolds
numbers, when most of the dissipation comes from the mean flow, we predict that the non-dimensional torque G = T/ν2
L, where L is the cylinder length, scales with Reynolds number R and gap width η, G = 1.46η3/2(1 - η)-7/4
R
3/2. At larger Reynolds number, velocity fluctuations become non-negligible in the dissipation. In these regimes, there is no
exact power law dependence the torque versus Reynolds. Instead, we obtain logarithmic corrections to the classical ultra-hard (exponent 2) regimes: G = 0.50
. These predictions are found to be in excellent agreement with avail-able experimental data. Predictions for scaling of velocity
fluctuations are also provided.
Received 7 June 2001 and Received in final form 7 December 2001 相似文献
198.
The influence of interatomic distances on magnetic ordering in RMnSi compounds (R=La, Y, Sm, and Gd)
S. A. Nikitin T. I. Ivanova Yu. A. Ovchenkova M. V. Maslennikova G. S. Burkhanov O. D. Chistyakov 《Physics of the Solid State》2002,44(2):308-311
Magnetic ordering in the RMnSi (R=La, Y, Sm, and Gd) compounds is investigated. It is found that the type of magnetic ordering depends on the d Mn-Mn distance between manganese atoms inside the magnetic layers located in the planes perpendicular to the c axis. This inference is based on the results of studies performed with SmMnSi and GdMnSi compounds in which the distances between manganese atoms are close to the critical value d Mn-Mn that corresponds to the crossover between ferromagnetic and antiferromagnetic ordering in RMnSi compounds. The introduction of lanthanum and yttrium atoms into the rare-earth sublattice leads to an increase and a decrease in the unit cell size, respectively, and brings about magnetic phase transitions in the compounds under investigation. 相似文献
199.
N. L. Dmitruk O. Yu. Borkovskaya R. V. Konakova I. B. Mamontova S. V. Mamykin D. I. Voitsikhovskiy 《Technical Physics》2002,47(6):698-702
The effect of 60Co gamma irradiation at doses of 103-2×105 Gy on the photoconversion and dark I-V characteristics of Au/GaAs surface-barrier solar cells (SCs) is studied. The morphology of the interface microrelief is varied
to reach the highest photoconversion efficiency. Of the two types of microrelief morphology (dendritic and quasi-grating)
obtained by the chemical anisotropic etching of n-(100)GaAs, the latter is more promising, particularly for SCs designed for space application, since the associated SCs offer
higher efficiency and radiation resistance. 相似文献
200.
The circular dichroism (CD) method has been used to study the stereochemistry of the bisbenzyltetrahydroisoquinoline alkaloids. A relationship has been established between the absolute configurations of the asymmetric centers and the parameters of the Cotton effects in the CD spectra. The changes in the CD spectra on protonation have been correlated with conformational rearrangements of the molecules due to the different attachment of the oxygen bridges.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 818–823, November–December, 1979. 相似文献