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111.
Ivan Petters Matija Modruan Nikolina Vidovi Ivo Crnolatac Nikola Cindro Ivo Piantanida Giovanna Speranza Gordan Horvat Vladislav Tomii 《Molecules (Basel, Switzerland)》2022,27(12)
Cyclic pentaphenylalanine was studied as an efficient anion sensor for halides, thiocyanate and oxoanions in acetonitrile and methanol. Stability constants of the corresponding complexes were determined by means of fluorimetric, spectrophotometric, 1H NMR, and microcalorimetric titrations. A detailed structural overview of receptor–anion complexes was obtained by classical molecular dynamics (MD) simulations. The results of 1H NMR and MD studies indicated that the bound anions were coordinated by the amide groups of cyclopeptide, as expected. Circular dichroism (CD) titrations were also carried out in acetonitrile. To the best of our knowledge, this is the first example of the detection of anion binding by cyclopeptide using CD spectroscopy. The CD spectra were calculated from the structures obtained by MD simulations and were qualitatively in agreement with the experimental data. The stoichiometry of almost all complexes was 1:1 (receptor:anion), except for dihydrogen phosphate where the binding of dihydrogen phosphate dimer was observed in acetonitrile. The affinity of the cyclopeptide receptor was correlated with the structure of anion coordination sphere, as well as with the solvation properties of the examined solvents. 相似文献
112.
Nikola Batina Adrian Huerta Orest Pizio Stefan Sokolowski Andrij Trokhymchuk 《Journal of Electroanalytical Chemistry》1998,450(2):6845
The NVT Monte Carlo simulation results are reported for a model of two-dimensional (2D) chemically associating fluid with six attractive sites per monomer disc. Three of these sites are of the type α and the other three of the type β. The sites α and β are fixed inside a hard core, they follow each other anticlockwise, with a `valence' angle of 60°. It is assumed that only α+β site–site association of two different discs occurs. Complex formation, dependent on the density and association energy, is much more sophisticated, in comparison to previously studied models of dimerizing and polymerizing discs. An analysis of complexes in terms of the fractions of singly, doubly,…, hexa-bonded particles is performed, and the dimensions and distributions of complexes are studied. We obtained the pair distribution functions of particles and structure factor in the fluid layer. The model was inspired by experiments on visualization of organic monolayers in the framework of scanning tunneling microscopy (STM). Currently it yields a preliminary insight into the molecular organization of crystal violet molecules on the iodine covered (111) single-crystal surface plane observed experimentally. Extensions of the model and methodology are discussed. 相似文献
113.
114.
Basarić N Horvat M Mlinarić-Majerski K Zimmermann E Neudörfl J Griesbeck AG 《Organic letters》2008,10(18):3965-3968
The photochemical reaction of N-(1-adamantyl)phthalimide (1) gives cleanly one product, the novel hexacyclic benzazepine derivative of 2,4-methanoadamantane 2. Its structure was characterized by spectroscopic methods and X-ray analysis and represent the first example of the 2-azahexacyclo[8.7.1.1 (1,4).0 (4,9).0 (11,16).0 (12,18)]nonadeca-4,6,8-triene skeleton. The product is formed by a domino process of two consecutive excited-state intramolecular gamma-hydrogen-transfer reactions. Base hydrolysis of the benzazepine 2 gives in high yield the keto derivative of the 1,2-substituted adamantane epsilon-amino acid 3. 相似文献
115.
Novel adamantane-oxalamide derivatives, N,N′-bis(1-adamantylglycine methyl ester)oxalamide (meso-1 and rac-1), N,N′-bis(3-aminoadamantane-1-carboxylic acid methyl ester)oxalamide (2) and N,N′-bis(3-aminoadamantane-1-carboxylic acid)oxalamide (3) were prepared and structurally characterized by spectroscopic methods and X-ray analysis. Crystal packing of the structures meso-1 and rac-1 is defined by one-dimensional α-networks of hydrogen-bonded chains. The crystal structures of 2 and 3 are characterized by two-dimensional β-networks of hydrogen bonds. The oxalamide 3 crystallizes as the solvates only. In the crystal structure of 3 the protic solvent participates in hydrogen bonding with the oxalamide moieties. However, in non-protic solvents 3 crystallizes as a solvate but the solvent does not participate in hydrogen bonding. The two-dimensional network of hydrogen bonds connecting molecules of 3 generates channels, which are filled by discrete solvent molecules. 相似文献
116.
Photochemical reactivity of a series of picolines and their N-methylated salts has been investigated by preparative irradiations and UV–vis spectroscopy. Understanding competing photochemical processes and knowledge of their relative efficiencies is important in the application of pyridines as photocages or in the synthesis of complex polycycles. Contrary to previous reports for the gas phase, picolines are not reactive in the phototransposition, presumably due to protonation of the pyridine nitrogen in the excited state. Deuterium exchange was observed upon irradiation in CD3CN–D2O, but it was rationalized by photoionization and radical formation. On the other hand, N-methylated picoline salts are not protonated upon excitation. They undergo photohydration and phototransposition (Φ R = 0.01–0.06). Upon irradiation of iodides, azabicyclic [3.1.0] hydration products were obtained. A difference in product distribution was observed between iodides and perchlorates, due to photoelimination of perchloric acid leading to the thermal aziridine ring opening. Moreover, excitation of iodide derivatives gives rise to change transfer transition forming iodide radicals that eventually give I3 ? with the quantum efficiency Φ R = 0.015–0.02. 相似文献
117.
David Moreno-González Francisco J. Lara Nikola Jurgovská Laura Gámiz-Gracia Ana M. García-Campaña 《Analytica chimica acta》2015
A new analytical method based on capillary zone electrophoresis-tandem mass spectrometry is proposed and validated for the identification and simultaneous quantification of nine aminoglycosides in honey samples. Detection using an ion trap mass analyzer operating in the multiple reaction monitoring mode was used. Different parameters were optimized in order to obtain an adequate separation combined with the highest sensitivity. In order to achieve high selectivity in the sample treatment, a commercially-available molecularly imprinted polymer has been used for the solid phase extraction of the analytes. Under optimum conditions, recoveries for fortified samples ranged from 88.2 to 99.8%, with relative standard deviations lower than 8%. The limits of detection ranged from 0.4 to 28.5 μg kg−1. Furthermore, the decision limit and the detection capability were evaluated, ranging from 3.5 to 60.5 μg kg−1 and from 6.0 to 103.1 μg kg−1, respectively, demonstrating the sensitivity and applicability of this fast and simple method. 相似文献
118.
119.
Froner E D'Amato E Adamo R Prtljaga N Larcheri S Pavesi L Rigo A Potrich C Scarpa M 《Journal of colloid and interface science》2011,360(1):86-92
A layer of macrocyclic calix[4]arene derivatives has been grafted on the internal surface of the mesochannels of the ordered mesoporous SBA-15 to develop highly efficient trap for heavy transition metal (HTM) ions. To ensure the successful anchoring of calix[4]arene derivatives on the surface of SBA-15, two different types of calix[4]arene derivatives, one with one trimethoxysilane functional group and another with two trimethoxysilane functional groups have been explored. XRD, N(2) adsorption and TEM results provide strong evidence that the mesoporous structure of the supporting materials retain their long range ordering throughout the grafting process. Solid-state NMR, TG and FT-IR spectroscopy indicate that both types of calix[4]arene derivatives can be well-anchored on the surface of the wall of SBA-15. Calix[4]arene derivative with only one trimethoxysilane functional group showed high grafting efficiency compared to that with two trimethoxysilane functional groups due to the intramolecular and intermolecular polycondensation between two trimethoxysilane functional groups. The HTM ions extraction capacity in aqueous solution of macrocycle functionalized SBA-15 nanohybrides for a series of HTM ions has been studied. The obtained materials demonstrated very high HTM ions extraction capacity up to 96% for Pb(2+) in aqueous solution. 相似文献
120.
Pavlov N Gilles P Didierjean C Wenger E Naydenova E Martinez J Calmès M 《The Journal of organic chemistry》2011,76(15):6116-6124
The asymmetric Friedel-Crafts alkylation of various indoles with a chiral nitroacrylate provides optically active β-tryptophan analogues after reduction of the nitro group and removal of the chiral auxiliary. This reaction generally occurs in good yield and high diastereoselectivity (up to 90:10). 相似文献