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21.
A mixture of benzimidazole salts (2–7), Pd(OAc)2 and K2CO3 in DMF–H2O catalyzes the Suzuki–Miyaura cross‐coupling reactions promoted by microwave irradiation resulting in high yield within a short time. In particular, the yield of the Suzuki–Miyaura reactions with aryl bromides was found to be nearly quantitative. The synthesized benzimidazole salts (2–7) were identified by 1H‐13C, NMR, IR spectroscopic methods and microanalysis. The molecular structure of 1 was determined by X‐ray crystallography. The antibacterial and antifungal activities of the novel benzimidazole derivatives (1–7) were also tested against standard strains. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
22.
The aim of this study was to measure the thermal properties of foamed nano/macro filler–reinforced styrene maleic anhydride (SMA) composites. SMA (66%) as a polymer matrix (10% maleic anhydride content) and various fillers including wood flour, starch, α-cellulose, microcrystalline cellulose and cellulose nanofibrils as reinforcing agents (30%) and lubricant (4%) were used to manufacture the composites in a twin-screw extruder. According to the thermogravimetric analysis (TGA) results, thermal degradation of all the foamed composites was found to be lower than that of SMA composites. The storage modulus values were negatively affected with a second time foaming (reprocessing [recycling] the initially processed composites a second time), as were loss modulus and Tg. As a result, second-time-foamed composite modulus values were lower than those of the foamed composites. According to the melt flow index (MFI) results, viscosity of the SMA was found to increase with the addition of fillers.  相似文献   
23.
There is an increasing interest for the utilization of biomolecules for fabricating novel nanostructures due to their ability for specific molecular recognition, biocompatibility, and ease of availability. Among these molecules, diphenylalanine (Phe-Phe) dipeptide is considered as one of the simplest molecules that can generate a family of self-assembly based nanostructures. The properties of the substrate surface, on which the self-assembly process of these peptides occurs, play a critical role. Herein, we demonstrated the influence of surface texture and functionality on the self-assembly of Phe-Phe dipeptides using smooth silicon surfaces, anodized aluminum oxide (AAO) membranes, and poly(chloro-p-xylylene) (PPX) films having columnar and helical morphologies. We found that helical PPX films, AAO, and silicon surfaces induce similar self-assembly processes and the surface hydrophobicity has a direct influence for the final dipeptide structure whether being in an aggregated tubular form or creating a thin film that covers the substrate surface. Moreover, the dye staining data indicates that the surface charge properties and hence the mechanism of the self-assembly process are different for tubular structures as opposed to the peptidic film. We believe that our results may contribute to the control of surface-induced self-assembly of peptide molecules and this control can potentially allow the fabrication of novel peptide based materials with desired morphologies and unique functionalities for different technological applications.  相似文献   
24.
This study describes the mechanism of flammability reduction in flame-retarded polymer matrix organo-montmorillonite reinforced nanocomposites. Morphologies of untested polymer nanocomposites and char residues formed by combustion in the mass loss calorimeter are characterized by XRD and TEM techniques. It is postulated that a combination of well-dispersed montmorillonite platelets and flame retardants in the polymer matrix provides nano-structured char formation. Initial montmorillonite dispersion in flame-retarded nanocomposites is found to be a major controlling factor on formed char nanostructures. An initially intercalated structure is invariantly converted to complete montmorillonite collapse whereas an initially exfoliated structure transforms to nano-structured chars demonstrating retained exfoliation or a new state of intercalation via incomplete collapse of montmorillonite layers. It is proposed that nano-structured char formation is the effective mechanism of flammability reduction, i.e. reduction in rate of heat release during combustion, in flame-retarded polymer nanocomposites.  相似文献   
25.
At room temperature, cobalt oxide cations directly convert methane to methanol with high selectivity but very low efficiency. Two potential intermediates of this reaction, the [HO-Co-CH(3)](+) insertion intermediate and [H(2)O-Co=CH(2)](+) aquo-carbene complex are produced in a laser ablation source and characterized by electronic and vibrational spectroscopy. Reaction of laser-ablated cobalt cations with different organic precursors seeded in a carrier gas produces the intermediates, which subsequently expand into vacuum and cool. Ions are extracted into a time-of-flight mass spectrometer and spectra are measured via photofragment spectroscopy. Photodissociation of [HO-Co-CH(3)](+) in the visible and via infrared multiple photon dissociation (IRMPD) makes only Co(+) + CH(3)OH, while photodissociation of [H(2)O-Co=CH(2)](+) produces CoCH(2)(+) + H(2)O. The electronic spectrum of [HO-Co-CH(3)](+) shows progressions in the excited state Co-C stretch (335 cm(-1)) and O-Co-C bend (90 cm(-1)); the IRMPD spectrum gives ν(OH) = 3630 cm(-1). The [HO-Co-CH(3)](+)(Ar) complex has been synthesized and its vibrational spectrum measured in the O-H stretching region. The resulting spectrum is sharper than that obtained via IRMPD and gives ν(OH) = 3642 cm(-1). Also, an improved potential energy surface for the reaction of CoO(+) with methane has been developed using single point energies calculated by the CBS-QB3 method for reactants, intermediates, transition states and products.  相似文献   
26.
27.
Fluorescence liftime imaging (FLIM) of modified hydrophobic bodipy dyes that act as fluorescent molecular rotors shows that the fluorescence lifetime of these probes is a function of the microviscosity of their environment. Incubating cells with these dyes, we find a punctate and continuous distribution of the dye in cells. The viscosity value obtained in what appears to be endocytotic vesicles in living cells is around 100 times higher than that of water and of cellular cytoplasm.Time-resolved fluorescence anisotropy measurements also yield rotational correlation times consistent with large microviscosity values. In this way, we successfully develop a practical and versatile approach to map the microviscosity in cells based on imaging fluorescent molecular rotors.  相似文献   
28.
In this paper, we present a novel macro-scale analytical model that allows the prediction of how the population size will change in a cell culture starting from an arbitrary initial value. General biological knowledge and some empirical observations are used to design an agent-based discrete-time model at the meso-scale, which then serves as a simulation environment and provides the necessary insights for the development of the continuous-time, differential equation-based, compact macro-scale model. This model can be parameter-tuned and employed for predicting how the population size changes. The paper gives a procedure for the estimation of parameter values of the macro-scale model via some simple tests to be conducted on the cell culture at hand. The performance of the macro-scale model is validated via simulation results that show how well the macro-scale model captures the population dynamics as obtained from the meso-scale model, while the biological plausibility of the meso-scale model is taken for granted.  相似文献   
29.
Amitraz is a non-systemic acaracide and insecticide. Current maximum residue limits for amitraz are stated as ‘Amitraz including the metabolites containing the 2,4-dimethylaniline moiety’. Therefore, determination of amitraz and its all degradation products are important. In this study, we develop a gas chromatography/mass spectrometry (GC/MS) method for determination of amitraz and its degradation products 2,4 dimethylaniline (DMA), 2,4 dimethylformamidine (DMF) and N-(2,4-dimethyl phenyl)-N’-methylformamidine (DMPF) in cucumber and quince. The mechanism of the degradation process was monitored at different temperatures. Amitraz and its degradation products were extracted using the QuEChERS method. To determine amitraz and its degradation products, we used GC/MS. Quantification was carried out by using selected ion monitoring, and total ion chromatogram was used to monitor additional degradation products. The method was validated by studying linearity, limit of detection (LOD) and limit of quantification (LOQ), recovery and precision. The mechanism of the degradation process was monitored at different temperatures. Degradation of amitraz mainly to three degradation products, namely DMA, DMF and DMPF, increased with temperature. Besides these three main degradation products, two other new degradation products were detected.  相似文献   
30.
A new flavone glucoside, 4′,5-dihydroxy-3′,5′,6-trimethoxyflavone-7-O-β-D-glucoside was obtained from aerial parts of Artemisia juncea, together with the known flavone eupatilin (5,7-dihydroxy-3′,4′,6-trimethoxyflavone). The compounds were comprehensively analytically characterized by IR, UV, NMR and HR-MS, and their chemical structures ascertained. The EtOAc fraction of A. juncea showed the strongest DPPH radical scavenging ability as well as reducing power (in CUPRAC and FRAP assays) and phosphomolybdenum activity. This fraction also exhibited the strongest inhibitory effects on tyrosinase. Additionally, the best antidiabetic effects were observed for eupatilin and the CHCl3 fraction.  相似文献   
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