The 58Ni(d, 3He)57Co reaction was measured at a bombarding energy of 78 MeV. Energy levels up to 7.0 MeV excitation energy in 57Co were studied. Angular distributions of the 3He particles, corresponding to transitions to the ground state and to 42 excited states in 57Co, were analyzed in the range of θlab = 2.7° to 25°. Exact finite-range DWBA calculations were employed to extract l-values and spectroscopic factors. Shell-model calculations were carried out in an fp-shell model space. In addition, calculations of the energy levels in 57Co were performed in the SU(6) particle-vibration model (PTQM). Satisfactory agreement is observed between the experimental results and both theoretical predictions. 相似文献
Spores of Dicksonia sellowiana (Presl.) Hook., an endangered tree fern, were stored in liquid nitrogen. Surface sterilized spores were placed in 1 ml sterile polypropylene cryotubes and were plunged into liquid nitrogen cryo-cans for 15 minutes, 15 days, 1 month and 3 months. In all, of the treatments the percentage of germination was higher than the control (fresh spores). Germination in Dyer and MS media supplement with 10 (-7) M and 5 x 10(-7) M BA was also promoted as comparing to control. There was no difference between the germination of spores thawed rapidly in a water bath at 45 degree C during 5 minutes or slowly at room temperature. Cryopreservation seems to promote germination of some dormant spores of D. sellowiana. The pre-treatment in cryoprotective solution of dimethyl sulphoxide 15%(v/v) in 1 M glycerol inhibited the germination of cryopreserved spores 相似文献
Enantioseparation of chiral products has become increasingly important in a large diversity of academic and industrial applications. The separation of chiral compounds is inherently challenging and thus requires a suitable analytical technique that can achieve high resolution and sensitivity. In this context, CE has shown remarkable results so far. Chiral CE offers an orthogonal enantioselectivity and is typically considered less costly than chromatographic techniques, since only minute amounts of chiral selectors are needed. Several CE approaches have been developed for chiral analysis, including chiral EKC and chiral CEC. Enantioseparations by EKC benefit from the wide variety of possible pseudostationary phases that can be employed. Chiral CEC, on the other hand, combines chromatographic separation principles with the bulk fluid movement of CE, benefitting from reduced band broadening as compared to pressure-driven systems. Although UV detection is conventionally used for these approaches, MS can also be considered. CE-MS represents a promising alternative due to the increased sensitivity and selectivity, enabling the chiral analysis of complex samples. The potential contamination of the MS ion source in EKC-MS can be overcome using partial-filling and counter-migration techniques. However, chiral analysis using monolithic and open-tubular CEC-MS awaits additional method validation and a dedicated commercial interface. Further efforts in chiral CE are expected toward the improvement of existing techniques, the development of novel pseudostationary phases, and establishing the use of chiral ionic liquids, molecular imprinted polymers, and metal-organic frameworks. These developments will certainly foster the adoption of CE(-MS) as a well-established technique in routine chiral analysis. 相似文献
Transition Metal substituted Gallanes: Synthesis and X-Ray Structures of [(CO)4CoGaEt2(NC7H13)], [(PMe3)(CO)3CoGaCl2(NMe3)], [(CO)4CoGaCl3]K, and [(CO)5MnGaEt2(NC7H13)] The transition metal substituted gallanes [(CO)5MnGaEt2(NC7H13)] ( 1 ), [(PMe3)(CO)3CoGaCl2 · (NMe3)] ( 2 ), [(CO)4CoGaEt2(NC7H13)] ( 3 ), and [(CO)4CoGaCl3]K ( 4 ) were obtained by the reaction of the potassium/sodium salts of the manganese- and cobaltcarbonylmetallates with the chlorogallium species ClGaEt2(NC7H13), Cl3Ga(NMe3), and GaCl3. The structures were established by single crystal X-ray analysis 1 : space group P21/c (I.T.-No.: 14); Z = 4; a = 1425.4(2) pm, b = 1007.4(1) pm, c = 1429.9(3) pm; β = 113.92(1)°; 2 : space group P21/m (I.T.-No.: 11); Z = 2; a = 746.1(1) pm, b = 1131.2(1) pm, c = 1061.5(1) pm; β = 101.87(1)°; 3 : space group P21/c (I.T.-No.: 14); Z = 8; a = 1405.9(2) pm, b = 1786.2(2) pm, c = 1430.9(2) pm; β = 91.47(1)°; 4 : space group P21/c; Z = 4; a = 1185.7(1) pm, b = 895.4(1) pm, c = 1144.7(3) pm; β = 106.47(2)°. The model compounds [{L′(CO)3Co}GaX2L] (L′ = CO, PH3; L = NH3, X = H, Cl) with polar σ(Co–Ga) bonds and the effect of the substituent on the bond length are characterized with DFT-calculations. 相似文献
Double ruthenium(II)-catalyzed alkyne annulations of quinones were accomplished. Thus, a strategy is reported that provides step-economical access to valuable quinones with a wide range of applications. C−H/N−H activations for alkyne annulations of naphthoquinones provided challenging polycyclic quinoidal compounds by forming four new bonds in one step. The singular power of the thus-obtained compounds was reflected by their antileukemic activity. 相似文献
Hard data alone are not sufficient to evaluate local police effectiveness in the new age of community policing. Citizens can provide useful feedback regarding strengths and weaknesses of police operations. However, citizen satisfaction indicators typically fail to accurately convey the multidimensional nature of local policing and account for characteristics that are non-controllable for the local police departments. In this paper, we construct a measure of perceived effectiveness of community oriented police forces that accounts for both multidimensional aspects of local policing and exogenous influences. In specific, this paper suggests the use of a multivariate conditional, robust order-m version of a non-parametric Data Envelopment Analysis approach with no inputs. We show the potentiality of the method by constructing and analyzing perceived effectiveness indicators of local police forces in Belgium. The findings suggest that perceived police effectiveness is significantly conditioned by the demographic and socioeconomic environment. 相似文献
The synthesis, tunable thermoresponsive properties, and self‐assembly of dual redox and thermoresponsive double hydrophilic block copolymers having pendant disulfide linkages (DHBCss) are reported. Well‐defined DHBCss composed of a hydrophilic poly(ethylene oxide) block and a dual thermo‐ and reduction‐responsive random copolymer block containing pendant disulfide linkages are synthesized by atom transfer radical polymerization. Their lower critical solution temperature (LCST) transitions are adjusted through modulating pendant hydrophobic–hydrophilic balance with disulfide–thiol–sulfide chemistry. Further, these DHBCss derivatives are converted to disulfide‐crosslinked nanogels at temperatures above LCST through temperature‐driven self‐assembly and in situ disulfide crosslinking. They exhibit enhanced colloidal stability and further reduction‐responsive degradability, thus demonstrating versatility of dual thermo‐ and reduction‐responsive smart materials.