全文获取类型
收费全文 | 615篇 |
免费 | 25篇 |
国内免费 | 4篇 |
专业分类
化学 | 396篇 |
晶体学 | 1篇 |
力学 | 10篇 |
数学 | 110篇 |
物理学 | 127篇 |
出版年
2023年 | 9篇 |
2022年 | 8篇 |
2021年 | 7篇 |
2020年 | 13篇 |
2019年 | 14篇 |
2018年 | 12篇 |
2017年 | 11篇 |
2016年 | 25篇 |
2015年 | 15篇 |
2014年 | 18篇 |
2013年 | 43篇 |
2012年 | 38篇 |
2011年 | 50篇 |
2010年 | 28篇 |
2009年 | 31篇 |
2008年 | 38篇 |
2007年 | 35篇 |
2006年 | 36篇 |
2005年 | 33篇 |
2004年 | 36篇 |
2003年 | 17篇 |
2002年 | 21篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 14篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 7篇 |
1994年 | 10篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有644条查询结果,搜索用时 31 毫秒
91.
Gielen E Smisdom N De Clercq B Vandeven M Gijsbers R Debyser Z Rigo JM Hofkens J Engelborghs Y Ameloot M 《Journal of fluorescence》2008,18(5):813-819
Many membrane proteins and lipids are partially confined in substructures ranging from tens of nanometers to micrometers in
size. Evidence for heterogeneities in the membrane of oligodendrocytes, i.e. the myelin-producing cells of the central nervous
system, is almost exclusively based on detergent methods. However, as application of detergents can alter the membrane phase
behaviour, it is important to investigate membrane heterogeneities in living cells. Here, we report on the first investigations
of the diffusion behavior of the myelin-specific protein MOG (myelin oligodendrocyte glycoprotein) in OLN-93 as studied by
the recently developed RICS (raster-scanning image correlation spectroscopy) technique. We implemented RICS on a standard
confocal laser-scanning microscope with one-photon excitation and analog detection. Measurements on FITC-dextran were used
to evaluate the performance of the system and the data analysis procedure.
Ellen Gielen and Nick Smisdom contributed equally to this work. 相似文献
92.
Stefanakis N Sarris J Cambourakis G Jacobsen F 《The Journal of the Acoustical Society of America》2008,123(1):33-36
The purpose of equalization in room acoustics is to compensate for the undesired modification that an enclosure introduces to signals such as audio or speech. In this work, equalization in a large part of the volume of a room is addressed. The multiple point method is employed with an acoustic power-output penalty term instead of the traditional quadratic source effort penalty term. Simulation results demonstrate that this technique gives a smoother decline of the reproduction performance away from the control points. 相似文献
93.
Dr. Peng Wang Dr. Chang-xin Huo Shuyao Lang Dr. Kyle Caution Dr. Setare Tahmasebi Nick Prof. Purnima Dubey Prof. Rajendar Deora Prof. Xuefei Huang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6513-6520
With the infection rate of Bordetella pertussis at a 60-year high, there is an urgent need for new anti-pertussis vaccines. The lipopolysaccharide (LPS) of B. pertussis is an attractive antigen for vaccine development. With the presence of multiple rare sugars and unusual glycosyl linkages, the B. pertussis LPS is a highly challenging synthetic target. In this work, aided by molecular dynamics simulation and modeling, a pertussis-LPS-like pentasaccharide was chemically synthesized for the first time. The pentasaccharide was conjugated with a powerful carrier, bacteriophage Qβ, as a vaccine candidate. Immunization of mice with the conjugate induced robust anti-glycan IgG responses with IgG titers reaching several million enzyme-linked immunosorbent assay (ELISA) units. The antibodies generated were long lasting and boostable and could recognize multiple clinical strains of B. pertussis, highlighting the potential of Qβ-glycan as a new anti-pertussis vaccine. 相似文献
94.
Dr. Jason C. Crack Prof. Nick E. Le Brun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(14):3675-3684
Nitric oxide (NO) can function as both a cytotoxin and a signalling molecule. In both cases, reaction with iron–sulfur (Fe–S) cluster proteins plays an important role because Fe–S clusters are reactive towards NO and so are a primary site of general NO-induced damage (toxicity). This sensitivity to nitrosylation is harnessed in the growing group of regulatory proteins that function in sensing of NO via an Fe–S cluster. Although information about the products of cluster nitrosylation is now emerging, detection and identification of intermediates remains a major challenge, due to their transient nature and the difficulty in distinguishing spectroscopically similar iron-NO species. Here we report studies of the NO-sensing Fe–S cluster regulators NsrR and WhiD using non-denaturing mass spectrometry, in which non-covalent interactions between the protein and Fe/S/NO species are preserved. The data provide remarkable insight into the nitrosylation reactions, permitting identification, for the first time, of protein-bound mono-, di- and tetranitrosyl [4Fe–4S] cluster complexes ([4Fe–4S](NO), [4Fe–4S])(NO)2 and [4Fe–4S](NO)4) as intermediates along pathways to formation of product Roussin's red ester (RRE) and Roussin's black salt (RBS)-like species. The data allow the nitrosylation mechanisms of NsrR and WhiD to be elucidated and clearly distinguished. 相似文献
95.
96.
Kimberley L. Anderson Wigen Nazarov Christopher S. A. Musgrave Nick Bazin Douglas Faith 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(2):969-975
PolyHIPE foams with densities of 0.05–0.1 g cm?3 have been prepared by the polymerisation of the continuous phase of high internal phase emulsions (HIPEs). The internal aqueous phase in HIPE occupies more than 74 % of the total volume, which leads to highly porous and open-cell morphologies. In this paper a method of preparing polyHIPE foams by using reversible addition-fragmentation chain transfer (RAFT) polymerisation has been investigated. Polystyrene-co-polymethyl methacrylate (PS-co-PMMA) has been studied and by using a variety of characterisation methods, it was possible to compare the polyHIPEs prepared by the conventional free radical polymerisation (FRP) to those by RAFT polymerisation. Scanning electron microscopy images have confirmed the presence of a cellular polyHIPE structure. PS-co-PMMA polyHIPEs made by RAFT have significantly narrower molecular weight distribution with values for the polydispersity index (PDI) for PS-co-PMMA between 1.46 and 2.08 compared to 4.68 observed by FRP. The effects of different concentrations of the RAFT agent on structure, glass transition temperature (T g) and PDI of PS-co-PMMA polyHIPE foams are presented. 相似文献
97.
Let T be a bounded linear operator in a complex Banach space.Our main result gives various characterizations of the condition:T is power-bounded and an estimate ||(I – T)Tn || cn–1/2 holds for all positive integers n. In particular, this conditionholds if and only if T = β S + (1 – β)I, forsome β (0, 1) and some power-bounded operator S; or ifand only if T is power-bounded and the discrete semigroup (Tn)is dominated by the continuous semigroup (e– t(I –T))t 0 in a natural sense. As a consequence of our main results,for 1/2 < 1 we characterize the condition that T is power-boundedand ||(I – T)Tn || c n– for all n, in terms ofestimates on the semigroup e–t(I – T). 相似文献
98.
Don Coppersmith Nick Howgrave-Graham S. V. Nagaraj. 《Mathematics of Computation》2008,77(261):531-545
Let be integers satisfying , , , and let . Lenstra showed that the number of integer divisors of equivalent to is upper bounded by . We re-examine this problem, showing how to explicitly construct all such divisors, and incidentally improve this bound to .
99.
Di Censo D Fantacci S De Angelis F Klein C Evans N Kalyanasundaram K Bolink HJ Grätzel M Nazeeruddin MK 《Inorganic chemistry》2008,47(3):980-989
Highly phosphorescent blue-light-emitting anionic iridium complexes (C4H9)4N[Ir(2-phenylpyridine)2(CN)2] (1), (C4H9)4N[Ir(2-phenyl-4-dimethylaminopyridine)2(CN)2] (2), (C4H9)4N[Ir(2-(2,4-difluorophenyl)-pyridine)2(CN)2] (3), (C4H9)4N[Ir(2-(2,4-difluorophenyl)-4-dimethylaminopyridine)2(CN)2] (4), and (C4H9)4N[Ir(2-(3,5-difluorophenyl)-4-dimethylaminopyridine)2(CN)2] (5) were synthesized and characterized using NMR, UV-vis absorption, and emission spectroscopy and electrochemical methods. In these complexes color and quantum yield tuning aspects are demonstrated by modulating the ligands with substituting donor and acceptor groups on both the pyridine and phenyl moieties of 2-phenylpyridine. Complexes 1-5 display intense photoluminescence maxima in the blue region of the visible spectrum and exhibit very high phosphorescence quantum yields, in the range of 50-80%, with excited-state lifetimes of 1-4 micros in acetonitrile solution at 298 K. DFT and time dependent-DFT calculations were performed on the ground and excited states of the investigated complexes to provide insight into the structural, electronic, and optical properties of these systems. 相似文献
100.
Efficient Blue‐Colored Solid‐State Dye‐Sensitized Solar Cells: Enhanced Charge Collection by Using an in Situ Photoelectrochemically Generated Conducting Polymer Hole Conductor
下载免费PDF全文
![点击此处可从《Chemphyschem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jinbao Zhang Dr. Nick Vlachopoulos Dr. Yan Hao Dr. Thomas W. Holcombe Prof. Gerrit Boschloo Dr. Erik M. J. Johansson Prof. Michael Grätzel Prof. Anders Hagfeldt 《Chemphyschem》2016,17(10):1441-1445
A high power conversion efficiency (PCE) of 5.5 % was achieved by efficiently incorporating a diketopyrrolopyrrole‐based dye with a conducting polymer poly(3,4‐ethylenediothiophene) (PEDOT) hole‐transporting material (HTM) that was formed in situ, compared with a PCE of 2.9 % for small molecular spiro‐OMeTAD‐based solid‐state dye solar cells (sDSCs). The high PCE for PEDOT‐based sDSCs is mainly attributed to the significantly enhanced charge‐collection efficiency, as a result of the three‐order‐of‐magnitude higher hole conductivity (0.53 S cm?1) compared with that of the widely used low molecular weight HTM spiro‐OMeTAD (3.5×10?4 S cm?1). 相似文献