全文获取类型
收费全文 | 103620篇 |
免费 | 17247篇 |
国内免费 | 11876篇 |
专业分类
化学 | 72735篇 |
晶体学 | 1140篇 |
力学 | 5885篇 |
综合类 | 669篇 |
数学 | 12662篇 |
物理学 | 39652篇 |
出版年
2024年 | 352篇 |
2023年 | 2077篇 |
2022年 | 3677篇 |
2021年 | 3777篇 |
2020年 | 4187篇 |
2019年 | 3977篇 |
2018年 | 3726篇 |
2017年 | 3346篇 |
2016年 | 5031篇 |
2015年 | 4941篇 |
2014年 | 6072篇 |
2013年 | 7797篇 |
2012年 | 9295篇 |
2011年 | 9497篇 |
2010年 | 6647篇 |
2009年 | 6379篇 |
2008年 | 6703篇 |
2007年 | 5988篇 |
2006年 | 5598篇 |
2005年 | 4674篇 |
2004年 | 3667篇 |
2003年 | 2944篇 |
2002年 | 2686篇 |
2001年 | 2245篇 |
2000年 | 1960篇 |
1999年 | 2057篇 |
1998年 | 1739篇 |
1997年 | 1560篇 |
1996年 | 1557篇 |
1995年 | 1366篇 |
1994年 | 1241篇 |
1993年 | 1004篇 |
1992年 | 903篇 |
1991年 | 779篇 |
1990年 | 652篇 |
1989年 | 503篇 |
1988年 | 378篇 |
1987年 | 338篇 |
1986年 | 335篇 |
1985年 | 262篇 |
1984年 | 188篇 |
1983年 | 153篇 |
1982年 | 126篇 |
1981年 | 78篇 |
1980年 | 59篇 |
1979年 | 26篇 |
1978年 | 22篇 |
1976年 | 22篇 |
1975年 | 22篇 |
1957年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
281.
QuanXiangwu YanPingSHI LiYANG 《中国化学快报》2004,15(12):1441-1444
From the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala, three novel eremophilane sesquiterpene lactones, 6α, 10α-dihydroxy- 1-oxoeremophila-7(11), 8(9)-dien-8, 12-olide, 613, 10α-dihydroxy-1-oxoeremophila-7 (ll), 8 (9)-dien-8, 12-olide and 10α-hydroxy-1-oxoeremophila-7(l 1), 8(9)-dien-8, 12-olide were isolated. Their structures were elucidated by various spectroscopic methods including intensive 2D NMR techniques (COSY,HMQC, HMBC and ^1H-^1H NOESY) and HR-MS. 相似文献
282.
NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
283.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
284.
Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products. 相似文献
285.
Ming Zhao WANG Guan Liang CAI Ling XIA Jun Jian YAO Hong Yan CHEN Zhao Xing MENG Bo Li LIUDepartment of Chemistry Beijing Normal University Beijing Chemical Defense Institute PLA Beijing 《中国化学快报》2004,15(4):495-497
The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents. 相似文献
286.
In this paper, we study a problem central to crossdocking that aims to eliminate or minimize storage and order picking activity using JIT scheduling. The problem is modelled naturally as a machine scheduling problem. As the problem is NP-hard, and for real-time applications, we designed and implemented two heuristics. The first uses Squeaky Wheel Optimization embedded in a Genetic Algorithm and the second uses Linear Programming within a Genetic Algorithm. Both heuristics offer good solutions in experiments where comparisons are made with the CPLEX solver. 相似文献
287.
288.
多小波子空间上的单小波表示 总被引:1,自引:0,他引:1
本文在较弱的条件下,建立了2重多小波子空间与单小波子空间的关系.即由2重多小波构造出单小波.一方面,这种单小波的平移伸缩与2重多小波的平移伸缩生成的子空间是完全相同的;另一方面,它具有插值性.因此通过构造出的单小波建立了多小波子空间上的Shannon型采样定理. 相似文献
289.
In this paper, we study the stability conditions of the MMAP[K]/G[K]/1/LCFS preemptive repeat queue. We introduce an embedded Markov chain of matrix M/G/1 type with a tree structure and identify conditions for the Markov chain to be ergodic. First, we present three conventional methods for the stability problem of the queueing system of interest. These methods are either computationally demanding or do not provide accurate information for system stability. Then we introduce a novel approach that develops two linear programs whose solutions provide sufficient conditions for stability or instability of the queueing system. The new approach is numerically efficient. The advantages and disadvantages of the methods introduced in this paper are analyzed both theoretically and numerically. 相似文献
290.
In-time motion adjustment in laser cladding manufacturing process for improving dimensional accuracy and surface finish of the formed part 总被引:2,自引:0,他引:2
This paper presents in-time motion adjustment in laser cladding manufacturing process as a means to improve dimensional accuracy and surface finish of the built part. Defects occurring during laser cladding degrade the part quality such as dimensional accuracy and surface finish. In this paper, in-time motion adjustment strategy was presented to remedy and eliminate defects occurring during laser cladding to improve the dimensional accuracy and surface finish. Based on the relationship between the motion of laser head relative to the growing part and other parameters in effects on clad profile, the laser traverse speed, stand-off distance and laser approach orientation to the existing clad layer were adjusted by instructions from a close-loop control system in real time to remedy and eliminate defects. The results of the experiments verified the effects of in-time motion adjustment on dimensional accuracy and surface finish. 相似文献