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排序方式: 共有143条查询结果,搜索用时 250 毫秒
21.
Ysaías J. Alvarado José Caldera-Luzardo Carlos De La Cruz Gladys Ferrer-Amado Elba Michelena Pedro Silva 《Journal of solution chemistry》2006,35(1):29-49
High-precision densitometry measurements of solutions of thioxanten-9-one (TX) in 1,4-dioxane, DMSO, toluene, and benzene
have been obtained at 293.15, 303.15, 313.15, 323.15, 333.15, and 343.15K. The partial molar volumes of TX (
) and the corresponding values at infinite dilution (
) were determined. The partial molar expansibility (
) of TX at infinite dilution in each solvent is temperature independent. Dynamic electronic polarizabilities
of TX in each aprotic solvent were determined by the Singer–Garito approach. These values are in excellent concordance with
the theoretical value for TX of 2.611×10−23cm3 estimated here using DFT/B3LYP/6-311++G(d,p). The partial molar volumes of TX at infinite dilution were calculated and interpreted
in terms of the Scale Particle Theory (SPT). The solvent influence on the partial molar volume of TX was found to be due mainly
to cavity formation and intermolecular dispersion forces. 相似文献
22.
Claudio Darıo Archubi Nestor R. Arista 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(1):18
A comparative study of the energy loss, mean free path and straggling of protons, positrons and electrons in an electron gas is performed using three dielectric models which represent the case of metals (Lindhard model for a free electron gas) and the cases of semiconductors and insulators (Levine and Louie model and Brandt and Reinheimer model for systems with a band gap). The properties of individual and collective contributions according to each model and for each of the particles are analyzed. In particular, the effects produced by the band gap of the material and by the properties of the incident particle are analyzed in detail. Significant differences related to the mass and to the indistinguishability (in the case of electrons) are described. Analytical expressions for the high-energy limit are derived in a simple way using the plasmon-pole approximation. 相似文献
23.
Ebenezer O. Oniya George S. Polymeris Nestor C. Tsirliganis George Kitis 《Radiation measurements》2012,47(9):864-869
Pre-dose sensitization of various components of LM-OSL signal of a Nigerian annealed quartz sample has been investigated along side with that of 110 °C TL peak in this work. Successive cycles of irradiations and TL/OSL readings using different heating rates were employed to attain pre-dose sensitization. The results showed that the pre-dose sensitization factor of 110 °C TL peak depends strongly on the heating rate of thermal activation. The pre-dose sensitization of 110 °C TL and all components of RT LM-OSL yield HR dependence on the sensitization after TA. This dependence was ascribed to the different heating time associated with each HR. Sensitization of LM-OSL measured at 125 °C generally does not show dependence on HR of TA. This was with the exception of components C1 and C3. Increasing sensitization pattern with increasing HR suggests a correlation between the TL glow-peak at 110 °C, the component C4 of RT LM-OSL and the component C3 of the LM-OSL signal at 125 °C. Extension of the present investigation to diverse quartz kinds from different origins was suggested in order to study the prevalence of the pre-dose sensitization on component C4 of RT LM-OSL. Finally fast heating is suggested for lower sensitization of fast component while applying OSL dating protocols. 相似文献
24.
25.
H. H. Sutherland Z. Ali Adib G. W. Gray D. Lacey G. Nestor K. J. Toyne 《Liquid crystals》1988,3(10):1293-1300
A series of terminally cyano substituted side chain polysiloxanes have been characterized using optical microscopy, D.S.C., and X-ray diffraction. Values for the lamellar spacings, d, of the interdigitated smectic A phases were obtained, and the variations in d with temperature and length of the flexible aliphatic spacer are discussed. The spacing for m = 4, 5, and 6 increased regularly with m whereas the short m = 3 spacer gave an anomalously high value. 相似文献
26.
Ho DG Ismail R Franco N Gao R Leverich EP Tsyba I Ho NN Bau R Selke M 《Chemical communications (Cambridge, England)》2002,(6):570-571
Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety. 相似文献
27.
The kinetics of piperidine replacement by pyridine at the pentacyano(piperidine)-ferrate(II) complex ion was studied under pseudo-first order conditions in binary aqueous mixtures of methanol, t-butanol, p-dioxane, and glycerol, from a mole fraction of co-solvent from 0 to about 0.15. The observed variations can be explained considering the degree of hydrophobic interaction between released ligand and water molecules which changes according to the structure-forming or struucture-breaking effect of added co-solvent on water. 相似文献
28.
Spyros Nikas Nestor A. Rodios Anastasios Varvoglis Aristidis Terzis Catherine R. Raptopoulou 《Journal of heterocyclic chemistry》1996,33(3):997-999
The reaction between dimedone anion and trimethylsilylethynyl phenyliodonium triflate leads to the formation of 4,4-dimethyl-6-(1,5-bistrimethylsilylpentane-1,4-diyne-3-ylidene)-δ-valerolactone, whose crystal structure has been determined. 相似文献
29.
H. H. Sutherland Z. Ali Adib G. W. Gray D. Lacey G. Nestor K. J. Toyne 《Liquid crystals》2013,40(10):1293-1300
Abstract A series of terminally cyano substituted side chain polysiloxanes have been characterized using optical microscopy, D.S.C., and X-ray diffraction. Values for the lamellar spacings, d, of the interdigitated smectic A phases were obtained, and the variations in d with temperature and length of the flexible aliphatic spacer are discussed. The spacing for m = 4, 5, and 6 increased regularly with m whereas the short m = 3 spacer gave an anomalously high value. 相似文献
30.
Ramon Tejada-Oliveros Rafael Balart Juan Ivorra-Martinez Jaume Gomez-Caturla Nestor Montanes Luis Quiles-Carrillo 《Molecules (Basel, Switzerland)》2021,26(1)
This research work reports the potential of maleinized linseed oil (MLO) as biobased compatibilizer in polylactide (PLA) and a thermoplastic elastomer, namely, polystyrene-b-(ethylene-ran-butylene)-b-styrene (SEBS) blends (PLA/SEBS), with improved impact strength for the packaging industry. The effects of MLO are compared with a conventional polystyrene-b-poly(ethylene-ran-butylene)-b-polystyrene-graft-maleic anhydride terpolymer (SEBS-g-MA) since it is widely used in these blends. Uncompatibilized and compatibilized PLA/SEBS blends can be manufactured by extrusion and then shaped into standard samples for further characterization by mechanical, thermal, morphological, dynamical-mechanical, wetting and colour standard tests. The obtained results indicate that the uncompatibilized PLA/SEBS blend containing 20 wt.% SEBS gives improved toughness (4.8 kJ/m2) compared to neat PLA (1.3 kJ/m2). Nevertheless, the same blend compatibilized with MLO leads to an increase in impact strength up to 6.1 kJ/m2, thus giving evidence of the potential of MLO to compete with other petroleum-derived compatibilizers to obtain tough PLA formulations. MLO also provides increased ductile properties, since neat PLA is a brittle polymer with an elongation at break of 7.4%, while its blend with 20 wt.% SEBS and MLO as compatibilizer offers an elongation at break of 50.2%, much higher than that provided by typical SEBS-g-MA compatibilizer (10.1%). MLO provides a slight decrease (about 3 °C lower) in the glass transition temperature (Tg) of the PLA-rich phase, thus showing some plasticization effects. Although MLO addition leads to some yellowing due to its intrinsic yellow colour, this can contribute to serving as a UV light barrier with interesting applications in the packaging industry. Therefore, MLO represents a cost-effective and sustainable solution to the use of conventional petroleum-derived compatibilizers. 相似文献