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141.
Ruiz-Hernandez SE Grau-Crespo R Almora-Barrios N Wolthers M Ruiz-Salvador AR Fernandez N de Leeuw NH 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(32):9828-9833
We have calculated the concentrations of Mg in the bulk and surfaces of aragonite CaCO(3) in equilibrium with aqueous solution, based on molecular dynamics simulations and grand-canonical statistical mechanics. Mg is incorporated in the surfaces, in particular in the (001) terraces, rather than in the bulk of aragonite particles. However, the total Mg content in the bulk and surface of aragonite particles was found to be too small to account for the measured Mg/Ca ratios in corals. We therefore argue that most Mg in corals is either highly metastable in the aragonite lattice, or is located outside the aragonite phase of the coral skeleton, and we discuss the implications of this finding for Mg/Ca paleothermometry. 相似文献
142.
Olivares M Vallejo A Irazola M Murelaga X Baceta JI Tarriño A Etxebarria N 《Talanta》2010,83(2):605-612
The analysis of hydrocarbons in chert rocks provides a worthwhile source of information regarding the geochemical features of a depositional setting. Since the typical analytical procedure requires long Soxhlet extractions and the use of large quantities of sample (30-50 g), in this work we have optimised the focused ultrasound extraction (FUSE) and the microwave-assisted extraction (MAE) to make available a less severe procedure. In both cases a full experimental design including solvent mixture composition (Dichloromethane/Hexane/Acetone) and process variables (sonication time and cycles, and extraction temperature and time) by means of D-optimal designs. In the extracted fractions hydrocarbons (C16-C40) were analysed by gas-chromatography-mass spectrometry. In the case of FUSE the process variables were the most sensitive variables and the optimum conditions were defined at 60:40 DCM/Hex mixture and a sonication time of 30 min and 9 cycles. In the case of MAE all the variables shown a significant effect on the extraction yield and the most adequate conditions (60:30:10 DCM/Hex/Ace mixture and an irradiation time of 15 min at 110 °C) were established from the analysis of the response surface. Both methods were systematically applied with different chert samples collected in Cucho (Trebiño County, Burgos, Spain) and we were able to assure quantitative extractions (>85%) in the first extraction. Additionally, from the distribution patterns of n-alkanes obtained in the different chert samples (nodular chert, laminar chert and massive-brechoid chert) collected in Cucho, we were able to distinguish different origins and diagenetic history. 相似文献
143.
Jone Omar Alfredo Sarmiento Maitane Olivares Ibone Alonso Nestor Etxebarria 《Journal of Raman spectroscopy : JRS》2012,43(8):1151-1156
In this work, virgin olive oil mixed with essential oils from rosemary has been analyzed by means of Raman spectroscopy. First of all, experimental design has been employed in order to define the Raman spectroscopy's parameters, final measuring conditions were: acquisition time of 30 s, five accumulations, and the intensity of the laser power at 75 mW. The Raman spectra were initially measured at full range (150–3000 cm−1), but a narrower window assured faster accumulations and more accurate predictions. The calibration solutions of eucalyptol and camphor in olive oil were prepared following a central composite design and different spectra pre‐processing algorithms were evaluated. To conclude, essential oils obtained by means of Supercritical Fluid Extraction, Ultrasounds, and hydrodistillation were mixed with virgin olive oil and quantified with Raman spectroscopy. Predicted concentrations of the olive oil mixtures were compared with concentrations obtained for the same samples by a Comprehensive Two‐Dimensional Gas Chromatographic (GC × GC) method. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献