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61.
Polymer stabilized cholesteric texture cells with various chiral and monomer concentrations were fabricated. Electro-optical measurement indicates that the chiral concentration and the monomer concentration significantly influence the hysteresis, threshold voltage and field-on and field-off response times of the cell. The chiral dopant is found to increase the hysteresis width and to decrease the field-off response time of the cell. The monomer is found to decrease the hysteresis width and to increase the field-off response time of the cell. The field-on response time is independent of the monomer concentration and the chiral concentration of the cell. A thinner cell has a smaller hysteresis width. PACS 61.30.-v; 42.70.Df; 42.79.Kr  相似文献   
62.
    
Luminescence thermometry has substantially progressed in the last decade, rapidly approaching the performance of concurrent technologies. Performance is usually assessed through the relative thermal sensitivity, Sr, and temperature uncertainty, δT. Until now, the state-of-the-art values at ambient conditions do not exceed maximum Sr of 12.5% K−1 and minimum δT of 0.1 K. Although these numbers are satisfactory for most applications, they are insufficient for fields that require lower thermal uncertainties, such as biomedicine. This has motivated the development of materials with an improved thermal response, many of them responding to the temperature through distinct photophysical properties. This paper demonstrates how the performance of multiparametric luminescent thermometers can be further improved by simply applying new analysis routes. The synergy between multiparametric readouts and multiple linear regression makes possible a tenfold improvement in Sr and δT, reaching a world record of 50% K−1 and 0.05 K, respectively. This is achieved without requiring the development of new materials or upgrading the detection system as illustrated by using the green fluorescent protein and Ag2S nanoparticles. These results open a new era in biomedicine thanks to the development of new diagnosis tools based on the detection of super-small temperature fluctuations in living specimens.  相似文献   
63.
Quantum dot thermal imaging has been used to analyse the chromatic dependence of laser-induced thermal effects inside optofluidic devices with monolithically integrated near-infrared waveguides. We demonstrate how microchannel optical local heating plays an important role, which cannot be disregarded within the context of on-chip optical cell manipulation. We also report on the thermal imaging of locally illuminated microchannels when filled with nano-heating particles such as carbon nanotubes.  相似文献   
64.
    
Optical applications of lanthanide-doped nanoparticles require materials with low phonon energies to minimize nonradiative relaxation and promote nonlinear processes like upconversion. Heavy halide hosts offer low phonon energies but are challenging to synthesize as nanocrystals. Here, we demonstrate the size-controlled synthesis of low-phonon-energy KPb2X5 (X=Cl, Br) nanoparticles and the ability to tune nanocrystal phonon energies as low as 128 cm−1. KPb2Cl5 nanoparticles are moisture resistant and can be efficiently doped with lighter lanthanides. The low phonon energies of KPb2X5 nanoparticles promote upconversion luminescence from higher lanthanide excited states and enable highly nonlinear, avalanche-like emission from KPb2Cl5 : Nd3+ nanoparticles. The realization of nanoparticles with tunable, ultra-low phonon energies facilitates the discovery of nanomaterials with phonon-dependent properties, precisely engineered for applications in nanoscale imaging, sensing, luminescence thermometry and energy conversion.  相似文献   
65.
Er-doped Si-yttria-stabilized zirconia (YSZ) thin film samples were prepared by rf co-sputtering. Chemical composition of the samples was determined using energy-dispersive spectroscopy (EDS) and the structure of the films by X-ray diffraction (XRD). The samples were annealed to 700 °C. Photoluminescence (PL) measurements were performed for the visible and infrared. By exciting with the 488-nm-laser line the Er3+ emissions 2H11/24I15/2, 4S3/24I15/2, 4F9/24I15/2 and a narrow 4I13/24I15/2 emission were observed. The 4I11/24I15/2 emissions for the same excitation wavelength were weak. Excitation wavelength dependence of the 4I13/24I15/2 emissions indicated that the emissions were due to a combination of energy transfer from Si nanoparticles (np) to Er ions and energy transfer from defects in the matrix to the Er ions for excitations resonant with the energy levels of such defects. 4I13/24I15/2 emission decay measurements show two decaying populations of Er ions according to their locations with respect to other ions or any non-radiative defects. 4I11/24I15/2 emission dependence on 4I13/24I15/2 emission showed that the former was possibly due to a combination of downconversion from higher levels of the Er ions, energy transfer from Si nanoparticles and upconversion transfer processes. We concluded that Er-doped Si-YSZ is a promising material for photonic applications being easily broadband excited using low-pumping powers.  相似文献   
66.
Zinc-diffused channel waveguides fabricated in thulium-doped LiNbO3 have been analyzed by means of confocal micro-luminescence techniques. Modifications induced by Zn2+ ions in the doped-crystal substrate are characterized following the evolution of the 3H43H6 luminescence of thulium ions at 795 nm, showing the existence of two different regions in the waveguide. Several Raman modes of LiNbO3 have been used as well to study the differences between the waveguide and the bulk material.  相似文献   
67.
68.
In this Letter we have used the optical pump induced thermal loading to drive Nd(3+) a doped Sr(0,47)Ba(0.53)(Nb)(3))(2) laser crystal during laser operation through its ferroelectric phase transition. We demonstrate that lasing is possible below, at, and above phase transition. For temperatures close to (approximately 105 degrees C) the spatial distribution of laser radiation is remarkably affected. This feature, which leads to a laser gain depression, can be explained in terms of the strong temperature dependence of the thermo-optic coefficient during phase transition. Additionally, the visible radiation generated by intracavity self-frequency doubling disappears when the phase transition is undergone, showing a bistable behavior. The results provide fundamental information on physical parameters along the phase transition and will stimulate further work in the fields of nonlinear optics, optical switching, and data storage.  相似文献   
69.
The luminescence properties of Neodymium ions in Zn diffused LiNbO3 channel waveguides have been studied with sub-micrometric spatial resolution. The analysis of the luminescence spectra suggests the existence of a local expansion and disordering associated to the presence of Zn in the LiNbO3 lattice after the diffusion process. By taking this cause–effect relation into account, it has been possible to determine both the in-depth and lateral Zn diffusion lengths, as well to elucidate the spatial location of the channel waveguide. PACS 42.65.Wi; 87.64.Tt; 42.55.Rz  相似文献   
70.
The simulation of light propagation using standard beam propagation techniques, in periodically inverted domains in Ba2NaNb5O12 crystals is presented. The poled domains pattern gives rise to periodic modulation of the refractive index in the crystal, which can be observed with diffraction experiments and simulated by one-dimensional beam propagation methods. The micro-domains are characterized by Scanning Near Field Microscopy, using both transmission and collection modes. In particular, under the collection mode, micro- pictures have been obtained with unexpected high optical contrast between positive and negative domains of up to 80%. Using a beam simulation method, the results are explained considering that the ferroelectric domains operate as a periodic array of planar waveguides.  相似文献   
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