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21.
The reactions of IO radicals with CH3SCH3, CH3SH, C2H4, and C3H6 have been studied using the discharge flow method with direct detection of IO radicals by mass spectrometry. The absolute rate constants obtained at 298 K are the following: IO + CH3SCH3 → products (1): k1 = (1.5 ± 0.2) × 10?14; IO + CH3SH → products (2): k2 = (6.6 ± 1.3) × 10?16; IO + C2H4 →products (3): k3 < 2 × 10?16; IO + C3H6 → products (4): k4 < 2 × 10?16 (units are cm3 molecule?1 s?1). CH3S(O)CH3 and HOI were found as products of reactions (1) and (2), respectively. The present lower value of k1 compared to our previous determination is discussed. 相似文献
22.
23.
J. -F. Le Gall 《Probability Theory and Related Fields》1988,78(3):389-402
Summary We consider the following heat conduction problem. Let K be a compact set in Euclidean space 3. Suppose that K is held at the temperature 1, while the surrounding medium is at the temperature 0 at time 0. Following Spitzer we investigate the asymptotic behaviour of the integral E
K
(t) which represents the total energy flow in time t from the set K to the surrounding medium 3–K. An asymptotic expansion is given for E
K
(t) which refines a theorem due to Spitzer. This expansion also verifies and improves a formal calculation of Kac. Similar results are proved in higher dimensions. Up to the constant m(K), the quantity E
K
(t) can be interpreted as the expected value of the volume of the Wiener sausage associated with K and a d-dimensional Brownian motion. This point of view both plays a major role in the proofs and leads to a probabilistic interpretation of the different terms of the expansion. 相似文献
24.
25.
The thiochlorides Mo6Cl10Y (Y = S, Se, Te) have been prepared; they are isostructural with Nb6I11, space group Pccn, and have four formula units per unit cell. The X-ray structure of Mo6Cl10Se has been determined from three-dimensional single-crystal counter data and refined to a final R value of 0.053 for 3350 independent reflections. The most important result concerning this structure is a statistical distribution of the Se atom on the unit (Mo6X′8) with : so the compound Mo6Cl10Se must be formulated . The diamagnetic and dielectric behavior of these new thiochlorides is discussed. 相似文献
26.
27.
Summary The existence of a joint asymptotic distribution for the windings of a three-dimensional Brownian motion around a finite number of straight lines is obtained. This complements the recent studies, by Pitman- Yor, and the authors, of the joint asymptotic distribution for the windings of planar Brownian motion around a finite number of points.The following principle governs the passage from results in the plane to results in space:Let B be a three-dimensional Brownian motion, and P
1, ..., P
k, k planes which intersect two by two. Then, the convergences in distribution concerning the planar Brownian motions B
i (1ik), defined respectively as the orthogonal projections of B on P
i (1ik), take place jointly, and the corresponding limit variables are independent. 相似文献
28.
29.
J. Kuriplach L. Lešták M. Rotter B. Sedlák M. Trhlík M. Finger T. Lešner J. Dupák P. Novák M. Vobecký 《Hyperfine Interactions》1987,34(1-4):339-342
First experimental results of160Tb nuclear orientation in yttrium single crystal matrix are described. The influence of external magnetic field in combination with the crystal field interaction is discussed. 相似文献
30.
4-Hydroxythiazoles and N-acylimino 4-thiazolidinones show similar tautomeric behaviour to azlactones. However, the mechanism of their reaction with dimethylacetylenedicarboxylate or with ethyl vinyl ether differs fundamentally. In the thiazole series, the first step is the quaternization of the nitrogen atom. The mesoionic thiazole intermediate is then trapped by a second molecule of the dipolarophile. 相似文献