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51.
Pajewski R Ferdani R Pajewska J Djedovic N Schlesinger PH Gokel GW 《Organic & biomolecular chemistry》2005,3(4):619-625
Heptapeptides having dioctadecyl, N-terminal hydrocarbon chains insert in phospholipid bilayer membranes and form pores through which at least chloride ions pass. Although amphiphilic, these compounds do not typically form vesicles themselves. They insert in the bilayers of phospholipid vesicles and mediate the release of carboxyfluorescein. Hill analysis indicates that at least two molecules of the amphiphile are involved in pore formation. In CD2Cl2, dimer formation is detected by NMR chemical shift changes. The anion release activity of individual anion transporters is increased by linking them covalently at the C-terminus or, even more, by linking them at the N-terminus. Evidence is presented that either linked molecule releases chloride from liposomes more effectively and rapidly than the individual transporter molecule at a comparable concentration. 相似文献
52.
Yaschenko S Dymov S Kacharava A Komarov V Macharashvili G Rathmann F Barsov S Gebel R Hartmann M Khoukaz A Kulessa P Kulikov A Kurbatov V Lang N Lehmann I Lorentz B Mersmann T Merzliakov S Mikirtytchiants S Mussgiller A Nioradze M Ohm H Prasuhn D Schleichert R Seyfarth H Steffens E Stein HJ Ströher H Uzikov Y Zalikhanov B Zhuravlev N 《Physical review letters》2005,94(7):072304
A measurement of the analyzing power A(y) of the p-->d--> (p p) + n reaction was carried out at the ANKE spectrometer at COSY at beam energies of 0.5 and 0.8 GeV by detection of a fast forward proton pair of small excitation energy E(pp) < 3 MeV. The S-wave dominance in the fast diproton is experimentally demonstrated in this reaction. While at T(p) = 0.8 GeV the measured analyzing power almost vanishes, it rises to nearly unity at T(p) = 0.5 GeV for neutrons emitted at theta(c.m.)(n) = 167 degrees. The results are compared with a model taking into account one-nucleon exchange, single scattering, and Delta(1232) excitation in the intermediate state. The model describes fairly well the unpolarized cross section obtained earlier and the analyzing power at 0.8 GeV; it fails to reproduce A(y) at 0.5 GeV. 相似文献
53.
L. Krupnik A. Alonso E. Ascasibar T. Estrada C. Hidalgo B. van Milligen M. Ochando M. Pedrosa J. L. de Pablos V. Tribaldos A. Chmyga N. Dreval G. Deshko S. Khrebtov A. Komarov A. Kozachok V. Tereshin L. Eliseev A. Melnikov C. Silva 《Czechoslovak Journal of Physics》2005,55(3):317-339
Radial plasma potential profiles have been obtained in the TJ-II by the Heavy Ion Beam Probing (HIBP) diagnostics. Results show that the potential increases up to 1 kV near the magnetic axis in ECRH low-density plasmas. The secondary ion current profiles, which directly reflect the plasma density, are hollow. In low-density ECRH operation, radial electric fields are found to be positive in the plasma core, however, a reduction in these fields is observed with increasing density. Radial plasma potential profiles show evidence of structures in configurations with low-order rational surfaces. In particular, HIBP measurements have permitted characterization of the plasma potential profile during e-ITB formation. Experiments in TJ-II have shown that it is possible to modify the global confinement and edge plasma parameters with limiter biasing, illustrating the direct impact of radial electric fields on confinement properties. Plasma potential measurements by the HIBP diagnostic show a strong impact of heating method (ECRH versus NBI) on radial electric fields.Presented at the Workshop Electric Fields Structures and Relaxation in Edge Plasmas, Nice, France, October 26–27, 2004. 相似文献
54.
55.
Smits R Warner N McQueen JM Cutler A 《The Journal of the Acoustical Society of America》2003,113(1):563-574
We present the results of a large-scale study on speech perception, assessing the number and type of perceptual hypotheses which listeners entertain about possible phoneme sequences in their language. Dutch listeners were asked to identify gated fragments of all 1179 diphones of Dutch, providing a total of 488,520 phoneme categorizations. The results manifest orderly uptake of acoustic information in the signal. Differences across phonemes in the rate at which fully correct recognition was achieved arose as a result of whether or not potential confusions could occur with other phonemes of the language (long with short vowels, affricates with their initial components, etc.). These data can be used to improve models of how acoustic-phonetic information is mapped onto the mental lexicon during speech comprehension. 相似文献
56.
Schlesinger PH Djedovic NK Ferdani R Pajewska J Pajewski R Gokel GW 《Chemical communications (Cambridge, England)》2003,(3):308-309
Two membrane-anchored heptapeptides have been prepared and their pore-formation behavior in phospholipid bilayer membranes has been found to differ profoundly as a result only of alkyl chain length. 相似文献
57.
Chernyshev E. A. Belyakova Z. V. Komarov E. A. Bykovchenko V. G. 《Russian Journal of General Chemistry》2001,71(7):1038-1040
The kinetics of etherification of organochlorosilanes with various substituents on the silicon atom with ethanol were studied. The etherification rate is mostly controlled by the inductive constants of the substituents and increases as the electron-acceptor power of the substituents increases. The * value in the Taft equation for etherification of organochlorosilanes with ethanol was determined. 相似文献
58.
59.
A. A. Andreev V. M. Komarov A. V. Charukhchev K. Yu. Platonov 《Optics and Spectroscopy》2007,102(6):944-948
The results of experimental measurement and analytical estimation of the coefficient of backward reflection from targets made of various materials upon their irradiation by a picosecond laser pulse having the intensity of (0.8–4) × 1018 W/cm2 are presented. It is shown that the induced surface instability leads to the formation of a profile backscattering the incident radiation. The coefficient of backward reflection achieves a few percent and has an intensity optimum depending on the target material. 相似文献
60.