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排序方式: 共有354条查询结果,搜索用时 15 毫秒
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Fereshteh Chekin Nélida Leiva Jahan Bakhsh Raoof Lo Gorton Leif Bülow 《Analytical and bioanalytical chemistry》2010,398(4):1643-1649
In this study, direct electron transfer (ET) has been achieved between an immobilised non-symbiotic plant haemoglobin class II from Beta vulgaris (nsBvHb2) and three different screen-printed carbon electrodes based on graphite (SPCE), multi-walled carbon nanotubes (MWCNT-SPCE), and single-walled carbon nanotubes (SWCNT-SPCE) without the aid of any electron mediator. The nsBvHb2 modified electrodes were studied with cyclic voltammetry (CV) and also when placed in a wall-jet flow through cell for their electrocatalytic properties for reduction of H2O2. The immobilised nsBvHb2 displayed a couple of stable and well-defined redox peaks with a formal potential (E°′) of ?33.5 mV (vs. Ag|AgCl|3 M KCl) at pH 7.4. The ET rate constant of nsBvHb2, k s, was also determined at the surface of the three types of electrodes in phosphate buffer solution pH 7.4, and was found to be 0.50 s?1 on SPCE, 2.78 s?1 on MWCNT-SPCE and 4.06 s?1 on SWCNT-SPCE, respectively. The average surface coverage of electrochemically active nsBvHb2 immobilised on the SPCEs, MWCNT-SPCEs and SWCNT-SPCEs obtained was 2.85?×?10?10 mol cm?2, 4.13?×?10?10 mol cm?2 and 5.20?×?10?10 mol cm?2. During the experiments the immobilised nsBvHb2 was stable and kept its electrochemical and catalytic activities. The nsBvHb2 modified electrodes also displayed an excellent response to the reduction of hydrogen peroxide (H2O2) with a linear detection range from 1 μM to 1000 μM on the surface of SPCEs, from 0.5 μM to 1000 μM on MWCNT-SPCEs, and from 0.1 μM to 1000 μM on SWCNT-SPCEs. The lower limit of detection was 0.8 μM, 0.4 μM and 0.1 μM at 3σ at the SPCEs, the MWCNT-SPCEs, and the SWCNT-SPCEs, respectively, and the apparent Michaelis–Menten constant, $ {\hbox{K}}_{\rm{M}}^{\rm{app}} $ , for the H2O2 sensors was estimated to be 0.32 mM , 0.29 mM and 0.27 mM, respectively. 相似文献
34.
A simple and efficient methodology for Markovnikov addition of azoles with vinyl acetate catalyzed by potassium tert-butoxide is described.N-heterocyclic compounds are synthesized from simple and commercially available starting materials under mild conditions in high yields. 相似文献
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In this paper, locating some warehouses as distribution centers (DCs) in a real-world military logistics system will be investigated. There are two objectives: finding the least number of DCs and locating them in the best possible locations. The first objective implies the minimum cost of locating the facilities and the latter expresses the quality of the DCs locations, which is evaluated by studying the value of appropriate attributes affecting the quality of a location. Quality of a location depends on a number of attributes; so the value of each location is determined by using Multi Attribute Decision Making models, by considering the feasible alternatives, the related attributes and their weights according to decision maker’s (DM) point of view. Then, regarding the obtained values and the minimum number of DCs, the two objective functions are formed. Constraints imposed on these two objectives cover all centers, which must be supported by the DCs. Using Multiple Objective Decision Making techniques, the locations of DCs are determined. In the final phase, we use a simple set partitioning model to assign each supported center to only one of the located DCs. 相似文献
37.
Farzaneh Ahmadi Jahan Bakhsh Raoof Reza Ojani Mehdi Baghayeri Moslem Mansour Lakouraj Hamed Tashakkorian 《催化学报》2015,(3)
Ag nanoparticles were synthesized on the surface of a glassy carbon electrode modified with p‐tert‐butylcalix[4]arene and p‐tert‐butylcalix[6]arene by the deposition of Ag+at an open circuit potential ... 相似文献
38.
In this paper, an efficient method for solving nonlinear Stratonovich Volterra integral equations is proposed. By using Bernoulli polynomials and their stochastic operational matrix of integration, these equations can be reduced to the system of nonlinear algebraic equations with unknown Bernoulli coefficient which can be solved by numerical methods such as Newton’s method. Also, an error analysis is valid under fairly restrictive conditions. Furthermore, in order to show the accuracy and reliability of the proposed method, the new approach is compared with the block pulse functions method by some examples. The obtained results reveal that the proposed method is more accurate and efficient than the block pulse functions method. 相似文献
39.
Reza Ghiasi Taherh Jahan Ara Amir Hossein Hakimyoun 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(4):616-624
The electronic structure and properties of the platinanaphthalenes, and ring-fused B-N platinanaphthalenes isomers have been explored using the hybrid density functional mpw1pw91 theory. The energetic aspect shows that stability of Ptb and Pta isomers are isoenergetic in platinanaphthalenes. On the other hand, BNa1 isomer is the most stable isomer of ring-fused B-N platinanaphthalenes. This is compatible with principles of minimum energy and minimum polarizability in ring-fused B-N platinanaphthalenes. Molecular orbital analysis shows increasing of hardness in ring-fused B-N platinanaphthalenes isomers. Also, electronic spectra analysis indicates that, in all the molecules HOMO-1 → LUMO transition makes the major contribution in most intense electronic transition. 相似文献
40.
An efficient tissue culture technology has been designed for mass multiplication of Nyctanthes arbor-tristis L. by preculturing nodal explants in thidiazuron (TDZ)-supplemented liquid Murashige and Skoog (MS) media. Direct inoculation
of nodal segments on semi-solid MS medium augmented with various concentrations of TDZ (0.1 to 0.9 μM) produced shoots but
with low regeneration response and few shoots per explant. Hence, nodal explants were pretreated with greater concentrations
of TDZ (5 to 100 μM) in liquid MS media for different durations (4, 8, 12, and 16 days) with the aim of improving shoot regeneration
response from cultured explants. After pretreatment, explants were transferred to agar-solidified hormone-free MS medium.
Best response in terms of percent regeneration (94%), number of shoots per explant (20.00 ± 1.15), and greatest shoot length
(7.23 ± 0.83 cm) were obtained with nodal segments pretreated in75 μM TDZ for 8 days. Similarly, root induction was obtained
from pulse-treated microshoots for 24 h with 200 μM indole-3-butyric acid (IBA) followed by their transfer to 1/2 MS medium
which produced an average of 5.50 ± 0.92 roots per microshoot. The rooted plantlets were transplanted to soil with 80% success
rate. 相似文献