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181.
An HPLC assay of hydroxyl radicals by the hydroxylation reaction of terephthalic acid 总被引:2,自引:0,他引:2
Linxiang L Abe Y Nagasawa Y Kudo R Usui N Imai K Mashino T Mochizuki M Miyata N 《Biomedical chromatography : BMC》2004,18(7):470-474
An HPLC assay for hydroxyl radicals is described. The hydroxyl radical was trapped by terephthalic acid (non-fluorescent), and 2-hydroxyl terephthalic acid (fluorescent) was quantitated by HPLC-fluorescence detection. At a terephthalic acid concentration of 4.25 mmol/L, the hydroxyl radical formed in the Fenton reaction was successfully assayed in the concentration range of hydrogen peroxide of 2.5-50 micro mol/L, where the concentration of Fe(II) was 50 micro mol/L. The fluorescence of 2-hydroxy terephthalate was stable at 24 h, and its detection limit by this method was 5 nmol/L (100 fmol). 相似文献
182.
The effect of temperature perturbation on a single-chain-collapse process was studied for poly(methyl methacrylate) with the molecular weight M(w)=1.05 x 10(7) in the mixed solvent of tert-butyl alcohol+water (2.5 vol %). In the chain-collapse process after a quench from the theta; temperature to a temperature T(1), the temperature was changed from T(1) to T(2) at the time t(1) after the quench and returned to T(1) at the time t(1)+t(2). In the three stages at T(1), T(2), and T(1), measurements of the mean-square radius of gyration of polymer chains were carried out by static light scattering and the chain-collapse process was represented by the expansion factor as a function of time. An effect of chain aggregation on the measurements was negligibly small because of the very slow phase separation. For the negative temperature perturbation (T(1)>T(2)), the chain-collapse processes observed in the first and third stages were connected smoothly and agreed with the collapse process due to a single-stage quench to T(1). A memory of the chain collapse in the first stage at T(1) was found to persist into the third stage at the same temperature T(1) without being affected by the temperature perturbation of T(2) during t(2). The memory effect was observed irrespective of the time period of t(2). The positive temperature perturbation (T(1)相似文献
183.
184.
185.
Wang NH Taniguchi M Tsuji D Doi M Ohishi H Yoza K Baba K 《Chemical & pharmaceutical bulletin》2003,51(1):68-70
Four new guaianolides, sinodielides A-D (1-4), were isolated from Sinodielsia yunnanensis WOLFF together with a known polyacetylene, falcarindiol, and two known coumarins, bergapten and scopoletin. Their structures were established by spectral and X-ray analyses. 相似文献
186.
Naoki Tanaka 《Archiv der Mathematik》2003,81(1):38-49
This paper is devoted to the approximation of a regularized evolution
operator by a sequence of regularized discrete parameter evolution operators,
and the results obtained here are applied to some degenerate partial differential
equation.Received: 4 December 2001 相似文献
187.
[reaction in text] A diastereocontrolled route to the eight aldohexoses has been developed starting from a common cyclohexanoid chiral building block. 相似文献
188.
Bose fluids restricted in one dimension (1D) are realized by adsorbing 4He atoms on the 1D pore walls with a diameter of about 18 A. The Bose fluid appears above an adsorbed amount after the pore walls are coated with the inert 4He atoms. Heat capacity of the fluid was observed to have a temperature-linear term at low temperatures. This corresponds to the phonon heat capacity of the Bose fluid in the 1D pores. We estimate the phonon velocity and the interaction of the 1D Bose fluid. 相似文献
189.
Galli F Ramakrishnan S Taniguchi T Nieuwenhuys GJ Mydosh JA Geupel S Ludecke J van Smaalen S 《Physical review letters》2000,85(1):158-161
We report the observation of a new type of charge-density wave (CDW) in the large magnetic-moment rare-earth intermetallic compound, Er5Ir4Si10, which then orders magnetically at low temperatures. Single crystal x-ray diffraction shows the development of a 1D incommensurate CDW at 155 K, which then locks into a purely commensurate state below 55 K. The well-localized Er3+ moments are antiferromagnetically ordered below 2.8 K. We observe very sharp anomalies in the specific heat at 145 and 2.8 K, signifying the bulk nature of these transitions. Our data suggest the coexistence of strongly coupled CDW with local-moment antiferromagnetism in Er5Ir4Si10. 相似文献
190.
H. Hayashi Y. Akita O. Suematsu M. Shibata M. Asai T. K. Sato S. Ichikawa I. Nishinaka Y. Nagame A. Osa K. Tsukada T. Ishii Y. Kojima A. Taniguchi 《The European Physical Journal A - Hadrons and Nuclei》2007,34(4):363-370
Q
β values of the neutron-rich isotopes of 160-165Eu and 163Gd were measured for the first time using a total absorption bismuth germanate (BGO) detector, and previously obtained data
on 158, 159Pm , 159, 161Sm and 166Tb were re-analyzed. These radioactive sources were prepared by an on-line mass separator (Tokai-ISOL) following the 238U (p,f reaction. The deduced Q
β values are the following: 6085(80)keV for 158Pm , 3805(65)keV for 159Sm , 5460(140)keV for 159Pm , 4705(60)keV for 160Eu , 5065(130)keV for 161Sm , 3705(60)keV for 161Eu , 5575(60)keV for 162Eu , 4690(70)keV for 163Eu , 3170(70)keV for 163Gd , 6430(70)keV for 164Eu , 5800(120)keV for 165Eu , and 4695(70)keV for 166Tb . Moreover, the deduced mass excesses and two-neutron separation energies ( S
2n values) were compared with those of the atomic mass evaluations and theoretical predictions. 相似文献