Interfacial microgels formed by oppositely charged polyelectrolytes and surfactants. Part 2. Influence of surfactant chain length and surfactant/polymer ratio

The adsorption and complexation of polystyrene sulfonate (a highly charged anionic polyelectrolyte) and a series of cationic surfactants, alkyltrimethylammonium bromide, CnTAB, n = 8-16, at the air-water interface has been studied by combining surface tension and ellipsometry measurements. We find that increasing the chain length of the surfactant from 8 to 10 carbons leads to a sharp increase in adsorption of PSS/CnTAB complexes. When the surfactant tail length is further increased to 12 and 14 carbons, surface adsorption becomes less favored than macroscopic phase separation, resulting in a partial surface depletion. Furthermore, we find that when surface tensions are plotted against surfactant/monomer molar concentration ratio, all data collapse to a single curve. This result shows that the surfactant-polymer molar ratio, s/p, is a key parameter for tuning the surface activity of the complexes formed.     

Ermittelung metallischer Gifte

Ohne Zusammenfassung     

Ueber die Vertheilung des Arsens im thierischen Organismus nach Einverleibung von arseniger S?ure

Ohne Zusammenfassung     

Introduction to session 5

Applied Biochemistry and Biotechnology -     

A filtration of -Catalan numbers

The operator of F. Bergeron, Garsia, Haiman and Tesler [F. Bergeron, A. Garsia, M. Haiman, G. Tesler, Identities and positivity conjectures for some remarkable operators in the theory of symmetric functions, Methods Appl. Anal. 6 (1999) 363–420] acting on the k-Schur functions [L. Lapointe, A. Lascoux, J. Morse, Tableaux atoms and a new Macdonald positivity conjecture, Duke Math. J. 116 (2003) 103–146; L. Lapointe, J. Morse, Schur functions analogs for a filtration of the symmetric functions space, J. Combin. Theory Ser. A 101 (2003) 191–224; L. Lapointe, J. Morse, Tableaux on k+1-cores, reduced words for affine permutations and k-Schur expansion, J. Combin. Theory Ser. A 112 (2005) 44–81] indexed by a single column has a coefficient in the expansion which is an analogue of the (q,t)-Catalan number with a level k. When k divides n we conjecture a representation theoretical model in this case such that the graded dimensions of the module are the coefficients of the (q,t)-Catalan polynomials of level k. When the parameter t is set to 1, the Catalan numbers of level k are shown to count the number of Dyck paths that lie below a certain Dyck path with q counting the area of the path.     

Integral quantizations with two basic examples

The paper concerns integral quantization, a procedure based on operator-valued measure and resolution of the identity. We insist on covariance properties in the important case where group representation theory is involved. We also insist on the inherent probabilistic aspects of this classical–quantum map. The approach includes and generalizes coherent state quantization. Two applications based on group representation are carried out. The first one concerns the Weyl–Heisenberg group and the euclidean plane viewed as the corresponding phase space. We show that a world of quantizations exist, which yield the canonical commutation rule and the usual quantum spectrum of the harmonic oscillator. The second one concerns the affine group of the real line and gives rise to an interesting regularization of the dilation origin in the half-plane viewed as the corresponding phase space.     

Physical characterization of uranium oxide pellets and powder applied in the Nuclear Forensics International Technical Working Group Collaborative Materials Exercise 4

Journal of Radioanalytical and Nuclear Chemistry - Physical characterization is one of the most broad and important categories of techniques to apply in a nuclear forensic examination. Physical...     

Electronic spectroscopy of the E<--X transition of NO-Kr and shielding/penetration effects in Rydberg states of NO-Rg complexes

We report the results of a (2+1) resonance-enhanced multiphoton ionization (REMPI) study of the E2Sigma+(4ssigma) Rydberg state of NO-Kr. We present an assignment of the two-photon spectrum based on a simulation, and discuss it in the context of previously-reported spectra of NO-Ne and NO-Ar. In addition, we report on spectra in the region of the vNO=1 level of the E, F and H' 4s and 3d Rydberg states of NO-Rg (Rg=Ne-Kr). Since the NO vibrational frequency is affected by electron donation from the rare-gas (Rg) atom to the NO+ core, as well as by the penetration of the Rydberg electron, the fundamental NO-stretch frequency reflects the interactions in the complex. The results indicate that the 4s Rydberg state has a strong interaction between the NO+ core and the Kr atom, as was the case for NO-Ar and NO-Ne. For the 3d Rydberg states, although penetration is not as significant as for the 4s Rydberg states, it does play an important role, with subtle angular effects being notable.     

A low-cost, disposable card for rapid polymerase chain reaction

A low-cost, disposable card for rapid polymerase chain reaction (PCR) was developed in this work. Commercially available, adhesive-coated aluminum foils and polypropylene films were laminated with structured polycarbonate films to form microreactors in a card format. Ice valves [1] were employed to seal the reaction chambers during thermal cycling and a Peltier-based thermal cycler was configured for rapid thermal cycling and ice valve actuation. Numerical modeling was conducted to optimize the design of the PCR reactor and investigate the thermal gradient in the reaction chamber in the direction of sample thickness. The PCR reactor was experimentally characterized by using thin foil thermocouples and validated by a successful amplification of 10 copy of E. coli tuf gene in 27 min.