Evidence and mechanisms of filling polymerization by plasma-induced graft polymerization

Using a plasma-induced graft polymerization technique, which is well known as a surface modification method, the grafted polymer was formed in pores of the porous material. This study examined the filling mechanism. Five thin porous films were sandwiched together, and employed as the substrate. The substrate was treated by plasma, and the change in surface tension and radical formation was measured for each sheet after the sheet was separated. The only surface on which surface-tension change was detected, was that of the sheet directly exposed to the plasma. Although plasma treatment made polymer radicals primarily on the outer surface of the sheet, the treatment also formed a few radicals inside the sheets. The radicals inside the sheets reacted with methylacrylate and grafted polymer formed in the pores. The location of grafted polymer depended on the balance between monomer diffusivity and reactivity. The grafting rate depended on which monomer solvent was used for the polymerization. Thus, the grafted membrane morphology could be controlled by varying the grating solvent composition. © 1996 John Wiley & Sons, Inc.     

Preparation and characterization of conducting trimetallic nickel-dithiolene complexes with bridging tetrathiooxalate ligands

Trimetallic nickel dithiolene complexes with two tetrathiooxalate (tto) ligands were obtained by a reaction monitored by ESI-mass spectrometry followed by HPLC separation and were characterized by elemental or crystal structural analysis, MO calculations, and electrical conductivity measurements.     

On the critical nonlinear damped wave equation with large initial data

We study the nonlinear damped wave equation

(0.1)     

Nickel-catalyzed arylcyanation of alkynes

A nickel catalyst coordinated by trimethylphosphine is found to effect the addition reaction of Ar-CN bonds in aromatic nitriles across alkynes to give rise to various beta-arylalkenenitriles.     

On computational proofs of the existence of solutions to nonlinear parabolic problems

This paper is an extension of the preceding study (Nakao, this journal, 1991) in which we described a numerical verification method of the solution for one-space dimensional parabolic problems, to the several-space dimensional case. Here, numerical verification means the automatic proof of the existence of solutions to the problems by some numerical techniques on a computer. We reformulate the verification condition for nonlinear parabolic initial boundary value problems using the fixed-point problem of a compact operator on certain function spaces. As in the preceding study based upon a simple C⁰ finite-element approximation and its constructive a priori error estimates, a numerical verification procedure is presented with some numerical examples.     

Silicon-based cross-coupling reaction: an environmentally benign version

Much attention has been paid to the cross-coupling reaction of organosilicon compounds due to their stability, non-toxicity, and natural abundance of silicon. In addition, the silicon-based cross-coupling has many advantages over other cross-coupling protocols. Successful examples of the silicon-based cross-coupling reaction are reviewed, focusing especially on the advances made in the last decade. Having had a number of highly effective palladium catalysts developed mainly for other cross-coupling reactions, the development of the silicon-based protocol owes heavily to the design of organosilicon reagents which effectively undergo transmetalation, a key elemental step of the silicon-based cross-coupling reaction. This tutorial review thus classifies various organosilicon reagents depending on substituents on silicon and surveys their cross-coupling reactions with various electrophiles.     

Reinvestigation of the synthesis of isoliquiritigenin: application of Horner-Wadsworth-Emmons reaction and Claisen-Schmidt condensation

Isoliquiritigenin [ILG, (E)-1] was readily prepared via the Horner-Wadsworth-Emmons reactions using β-ketophosphonates 5a, b. An improved protocol for the synthesis of (E)-1 via the Claisen-Schmidt condensation was also presented.     

Influence of particle design on oral absorption of poorly water-soluble drug in a silica particle-supercritical fluid system

The physicochemical characteristics and oral absorption of a poorly water-soluble drug, K-832, adsorbed onto porous silica (Sylysia 350), were compared with those of K-832 adsorbed onto non-porous silica (Aerosil 200). K-832 and silica were treated with supercritical CO(2) (scCO(2)) to produce K-832-Sylysia 350 and K-832-Aerosil 200 formulations. Scanning electron microscopy, polarizing microscopy, powder X-ray diffraction, and differential scanning calorimetry results suggested that K-832 mainly existed in an amorphous state in both formulations. The specific surface area of both formulations was much larger than that of pure K-832 crystals. The dissolution rate of K-832 from both formulations was considerably greater than that from corresponding physical mixtures due to rapid wetting of the hydrophilic carrier surfaces and amorphous state, the dissolution from the K-832-Sylysia 350 formulation being the fastest. In vivo absorption tests on the two formulations indicated no significant differences in their peak concentration (C(max)) and the area under their plasma concentration-time curve (AUC), while the concentrations of K-832 in the K-832-Sylysia 350 formulation were significantly higher than those in the K-832-Aerosil 200 formulation 1 h and 1.5 h after administration of these formulations (p<0.05). This could be attributed to the different dispersion states of K-832 in the formulations due to their different three-dimensional structures (porous and non-porous). In physical stability tests, the amorphous drugs in both formulations were stable at room temperature for at least 14 months. Thus, the absorption of poorly water-soluble drugs could be greatly improved by adsorption onto porous silica using scCO(2).     

Quadratic derivative nonlinear Schrödinger equations in two space dimensions

We study the global in time existence of small classical solutions to the nonlinear Schrödinger equation with quadratic interactions of derivative type in two space dimensions $\left\{\begin{array}{l@{\quad}l}i \partial _{t} u+\frac{1}{2}\Delta u=\mathcal{N}\left( \nabla u,\nabla u\right),&;t >0 ,\;x\in {\bf R}^{2},\\ u\left( 0,x\right) =u_{0} \left( x\right),&;x\in {\bf R}^{2}, \end{array}\right.\quad\quad\quad\quad\quad\quad (0.1)$ where the quadratic nonlinearity has the form ${\mathcal{N}( \nabla u,\nabla v) =\sum_{k,l=1,2}\lambda _{kl} (\partial _{k}u) ( \partial _{l}v) }We study the global in time existence of small classical solutions to the nonlinear Schr?dinger equation with quadratic interactions of derivative type in two space dimensions

$\left\{{l@{\quad}l}i \partial _{t} u+\frac{1}{2}\Delta u=\mathcal{N}\left( \nabla u,\nabla u\right),&t >0 ,\;x\in {\bf R}^{2},\\ u\left( 0,x\right) =u_{0} \left( x\right),&x\in {\bf R}^{2}, \right.\quad\quad\quad\quad\quad\quad (0.1)$\left\{\begin{array}{l@{\quad}l}i \partial _{t} u+\frac{1}{2}\Delta u=\mathcal{N}\left( \nabla u,\nabla u\right),&t >0 ,\;x\in {\bf R}^{2},\\ u\left( 0,x\right) =u_{0} \left( x\right),&x\in {\bf R}^{2}, \end{array}\right.\quad\quad\quad\quad\quad\quad (0.1)      60. Remark on the global existence and large time asymptotics of solutions for the quadratic NLS      Nakao Hayashi  Pavel I. Naumkin 《Nonlinear Analysis: Theory, Methods & Applications》2011,74(18):6950-6964 We study the global in time existence of small solutions to the nonlinear Schrödinger equation with quadratic interactions (0.1) We prove that if the initial data u0 satisfy smallness conditions in the weighted Sobolev norm, then the solution of the Cauchy problem (0.1) exists globally in time. Furthermore, we prove the existence of the usual scattering states and find the large time asymptotics of the solutions.      [首页] « 上一页 [1] [2] [3] [4] [5] 6 [7] [8] [9] [10] [11] 下一页 » 末  页»

Remark on the global existence and large time asymptotics of solutions for the quadratic NLS

We study the global in time existence of small solutions to the nonlinear Schrödinger equation with quadratic interactions (0.1) We prove that if the initial data u₀ satisfy smallness conditions in the weighted Sobolev norm, then the solution of the Cauchy problem (0.1) exists globally in time. Furthermore, we prove the existence of the usual scattering states and find the large time asymptotics of the solutions.