Degeneracy in Heteroscedastic Regression Models

The maximum likelihood estimation in a regression model with heteroscedastic errors is considered. When the design matrices in the model are inappropriately specified, the maximum likelihood estimates of the variances of certain observations are found to be zero irrespective of the observed values, resulting in degeneracy. Necessary and sufficient conditions for degeneracy are given and used for its avoidance.     

Didodecyldimethylammonium Bromide Films Containing Cobalt Phthalocyanine Tetrasulfonate for Electrochemical Catalysis

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离散PH分布的一个封闭性质及其应用

本证明了离散PH分布的一个封闭性质并讨论了它在离散时间排队研究中的应用。     

Yb3+:YVO4晶体的生长及光谱性能研究

采用提拉法生长出光学质量优良的Yb3+:YVO4晶体,研究生长过程中工艺参数的控制.测得掺杂浓度为18.1;Yb3+:YVO4晶体中Yb3+离子的有效分凝系数Keff为0.96.测定了不同Yb3+离子掺杂浓度晶体的吸收光谱和荧光光谱,并分别计算了不同掺杂浓度下Yb3+:YVO4晶体的光谱参数.本文总结和解释了掺杂浓度影响其性能的规律,讨论了Yb3+:YVO4晶体作为激光晶体的优点.     

卵磷脂涂敷生物膜色谱固定相的制备及其稳定性的考察

 将卵磷脂涂敷的硅胶作为生物膜固定相 ,并以此研究了药物与生物膜的相互作用。实验发现 ,卵磷脂涂敷的硅胶固定相的适宜使用温度为 2 0℃～ 30℃ ,而且卵磷脂中合适的胆固醇含量会使制备的生物膜固定相的稳定性有所增加。对药物在这种生物膜色谱固定相上的保留行为的研究表明 ,胆固醇含量、缓冲试剂组成、流动相中盐浓度及pH值等都会影响色谱柱对药物的选择性。卵磷脂涂敷生物膜色谱固定相的制备方法简便 ,通过固定相及流动相的改变可以很方便地模拟人体的生理环境 ,因而可以用于研究药物在体内的吸收和分布状况以及药物的初步筛选。     

β二酮钛配合物/MAO催化合成间规聚苯乙烯及其热性能

间规聚合;β二酮钛配合物/MAO催化合成间规聚苯乙烯及其热性能     

时效处理对低溶质Cu—Cr—Zr合金力学和电滑动磨损性能的影响

在销－盘式摩控擦磨损试验机上进行了Cu-Zr-Zr合金的电滑动摩擦磨损试验,考察了时效处理对其力学和电磨损性能的影响,并采用扫描电子显微镜对其磨损表面进行观察分析,结果表明：Cu-Cr-Zr合金的损随时效温度的升高逐渐降低,在500℃时达到最低值;随着时效温度的进一步升高,磨损率又开始增大,在电流作用下,合金的磨损机制主要有粘着磨损、磨粒磨损与电侵蚀磨损,在相同的摩擦磨损试验条件下,Cu-Cr-Zr合金的耐磨损性能明显优于Cu-Ag合金。     

The Entropic Uncertainty Relation for Two Qubits in the Cavity‐Based Architecture

Based on a simple cavity‐engineered architecture, the dynamics of quantum memory–assisted entropic uncertainty relation (QMA‐EUR) for two qubits initially prepared in a generic Werner state is investigated. The effects of cavity decay rate, qubit–cavity couplings, and cavity–cavity couplings on the uncertainty are explored. It is found that the damped oscillation of uncertainty can be induced by the increase of two types of coupling strengths mentioned above. It is demonstrated that the maximum value of uncertainty is closely related to the purity of the initial state. The uncertainty can be either increased or decreased, depending on the threshold value of coupling strength between the two cavities. Finally, in agreement with a recent observation, an asynchronous relation between uncertainty and mixedness is found during the initial time evolution.     

原位分散紫外光固化SiO_2纳米复合材料的性质

紫外光固化技术是以紫外光为辐射光源使体系快速固化的技术 ,具有易散热、快速固化成型、百分之百转化率、固化材料质量高等诸多优点 ,可用来制备各种功能材料 [1～ 3] .Adrian等[4] 在紫外光可固化材料中利用分散法填充各种传统填料 ,提高了固化材料的力学性能 .本文将 Si O2 纳米粒子分散在环氧丙烯酸酯齐聚体等构成的紫外光可固化溶液中 ,制得了 Si O2纳米复合材料 .试验表明 :原位分散紫外光固化合成纳米复合材料具有快速固化、容易成型、基体可选等优点 ,所得 Si O2 纳米复合材料具有良好的力学和光学性能 .试剂与仪器 :双酚 A环氧…     

Two neolignan glucosides and antihistamine release activities from Bidens parviflora WILLD

Two new neolignan glucosides, bidenlignasides A (1) and B (2), were isolated from the whole plant of Bidens parviflora WILLD. The structures of the two new compounds 1 and 2 established to be 3-hydroxy-1-(4-hydroxy-3-methoxyphenyl)-3-[5E-(3-hydroxypropenyl)-3-methoxy-2-O-beta-D-glucosyl)phenyl] propan-1-one and 3-{3-[1,3-dihydroxy-3-(4-hydroxy-3-methoxyphenyl)propyl]-4-hydroxy-5-methoxyphenyl}-allyl-O-beta-D-glucuside, respectively, on the basis of spectral and chemical evidence. Compounds 1 and 2 were found to inhibit histamine release from peritoneal exudate mast cells induced by antigen-antibody reaction.