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991.
Alexander Linkov Liliana Rybarska-Rusinek 《Archive of Applied Mechanics (Ingenieur Archiv)》2008,78(10):821-831
The paper presents a general method to find asymptotics for a (multi-)wedge system containing a thin wedge. It employs separation
of the symmetric and anti-symmetric parts of the boundary displacements and tractions of the wedge. The method is applicable
when the angle of the thin wedge turns to zero. A physical interpretation of the derived equations is obtained by using power
expansions of non-polynomial functions, which appear after the Mellin transform. We establish that the first term in the expansion
of the symmetric part corresponds to shear, while the first term of the anti-symmetric part describes deflection of the wedge
axis. Numerical experiments, performed by using a code developed on the basis of the theory, show that using only the first
terms of the expansions insignificantly influence accuracy: the approximate results coincide with the exact values of roots
to the third significant digit even for the wedge angle of 30°. 相似文献
992.
L. A. Oparina O. V. Vysotskaya A. V. Stepanov I. V. Rodionova G. F. Myachina N. K. Gusarova B. A. Trofimov 《Russian Journal of Organic Chemistry》2008,44(1):120-123
2-Hydroxymethylfuran reacted with acetylene in superbasic catalytic systems MOH-DMSO (M = Na, K) under mild temperature conditions (75–85°C, 1–2 h), yielding 80% of 2-vinyloxymethylfuran. The product, as well as acetaldehyde acetals derived therefrom, turned out to be promising as modifiers for electrolyte in lithium-sulfur rechargeable batteries. 相似文献
993.
Multiwalled carbon nanotubes were modified by carboxy groups. Four independent methods for the determination of the degree
of functionalization of the surface were proposed: 13C NMR spectroscopy, thermogravimetry, titrimetry, and fluorimetry. The first two methods show the total content of carboxy
groups in the sample, and the latter two methods give information about the content of the surface groups only.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 291–295, February, 2008. 相似文献
994.
995.
996.
S. N. Shagabutdinova M. A. Fedotov A. V. Belyaev V. D. Il’yashevich E. I. Pavlova 《Russian Journal of Coordination Chemistry》2008,34(12):917-923
Solid-state rhodium(III) sulfates and their aqueous solutions were examined by IR and electronic absorption spectroscopy, thermogravimetry, X-ray powder diffraction analysis, and 103Rh and 17O NMR spectroscopy. A study of the spontaneous aquation of freshly prepared solutions showed that this process results in an equilibrium between the subsystems of monomeric and oligomeric complexes. It was found that solid-state rhodium(III) sulfates vary in phase composition, basically consisting of dimeric and trimeric complexes. 相似文献
997.
G. I. Nikishin L. L. Sokova V. D. Makhaev N. I. Kapustina 《Russian Chemical Bulletin》2008,57(1):118-123
The solid-phase oxidation of cinnamic, 4-methoxy- and 3,4-dimethoxycinnamic acids with Ce(NH4)2(NO3)6—MHal system leads to β-halostyrenes. Similar procedure in the absence of a metal halide results in a cleavage of the C=C
bond giving the corresponding benzaldehydes.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 114–118, January, 2008. 相似文献
998.
N. A. Anikin A. S. Mendkovich M. B. Kuzminskiy A. M. Andreev 《Russian Chemical Bulletin》2008,57(2):428-430
A new fast computational method for mass calculations of docking complexes by the AM1/PM3 semiempirical methods is proposed.
The computation time is shortened by at least an order of magnitude compared to alternative schemes of quantum chemical calculations.
The root-mean-square deviation of the AM1 calculated energies of formation of complexes from the results obtained by conventional
diagonalization procedure is at most 0.4 kcal mol−1.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 418–420, February, 2008. 相似文献
999.
A. G. Zhigotskii E. F. Rynda N. A. Mishchuk V. M. Kochkodan A. V. Ragulya V. P. Klimenko M. N. Zagornyi 《Russian Journal of Applied Chemistry》2008,81(12):2056-2061
Photodestruction and adsorption of dyes in aqueous suspensions of nanopowders of titanium dioxide of anatase modification was studied. The photocatalytic activity of titanium dioxide nanopowders was examined in relation to the dispersity of particles and pH of the medium. 相似文献
1000.