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81.
Template-derived mesoporous carbons with highly dispersed transition metals as media for the reactive adsorption of dibenzothiophene 总被引:1,自引:0,他引:1
Mesoporous carbons with highly dispersed copper, cobalt, and iron were obtained from an organic polymer within amorphous silica powder, alumina, and zeolite 13X. The materials were characterized using the adsorption of nitrogen, potentiometric titration, and elemental analysis. The small metal content (less than 1%) and its chelation in the precursor polymers ensure a high dispersion of metallic centers. The materials obtained are mainly mesoporous but differ significantly in their porosity and surface chemistry, which is linked to the effect of template constraints and chemistry and the kind of metal and is related to the differences in the carbonization mechanism. On the carbon obtained, the adsorption of dibenzothiophene (DBT) from hexane was carried out. The high capacities (up to 130 mg S/g) obtained were linked to the high volume of mesopores and specific interactions of DBT with surface acidic groups and strong interactions of metals with dibenzothiophene via S-M sigma bonds or, in the case of copper, via interaction of metals with disturbed pi electrons of aromatic rings of DBT. 相似文献
82.
Vasyl S. Matiychuk Mykola D. Obushak Andrzej Gzella Yuri V. Ostapiuk 《Tetrahedron letters》2008,49(31):4648-4651
Various novel 3,5a,6,11b-tetrahydro-2H,5H-chromeno[4′,3′:4,5]thiopyrano[2,3-d][1,3]thiazol-2-ones were synthesized in 60-80% yields via domino-Knoevenagel-hetero-Diels-Alder reactions of 4-thioxo-1,3-thiazolidin-2-one with 3,7-dimethyl-6-octenal, 2-allyloxybenzaldehydes and 2-formylphenyl (E)-3-aryl-2-propenoates with base catalysis. The possibility of stereo- and regioselective cycloaddition was investigated. 相似文献
83.
Faranak Bahrami Mykola Abramchuk Oleg Lebedev Fazel Tafti 《Molecules (Basel, Switzerland)》2022,27(3)
Nearly two decades ago, Alexei Kitaev proposed a model for spin- particles with bond-directional interactions on a two-dimensional honeycomb lattice which had the potential to host a quantum spin-liquid ground state. This work initiated numerous investigations to design and synthesize materials that would physically realize the Kitaev Hamiltonian. The first generation of such materials, such as NaIrO, -LiIrO, and -RuCl, revealed the presence of non-Kitaev interactions such as the Heisenberg and off-diagonal exchange. Both physical pressure and chemical doping were used to tune the relative strength of the Kitaev and competing interactions; however, little progress was made towards achieving a purely Kitaev system. Here, we review the recent breakthrough in modifying Kitaev magnets via topochemical methods that has led to the second generation of Kitaev materials. We show how structural modifications due to the topotactic exchange reactions can alter the magnetic interactions in favor of a quantum spin-liquid phase. 相似文献
84.
Andriy O. Bryhas Vasyl S. Matiychuk Tadeusz Lis Vasyl Kinzhybalo Victor V. Smalius Mykola D. Obushak 《Tetrahedron letters》2013
A new, catalyst-free, domino Knoevenagel–hetero-Diels–Alder elimination oxidation reaction is reported. 5-Aryl-2H,6H-chromeno[4′,3′:4,5]thiopyrano[2,3-d][1,3]thiazol-2-ones are formed in moderate to good yields via reaction of 2-(3-aryl-3-chloro-2-propenyloxy)benzaldehydes with 4-thioxo-1,3-thiazolidin-2-one. 相似文献
85.
Shalimov Aleksandr A. Kolotylo Mykola V. Babiy Lyubov V. Muzychka Oksana V. Onys’ko Petro P. Rozhkov Vladimir V. 《Chemistry of Heterocyclic Compounds》2018,54(11):1033-1039
Chemistry of Heterocyclic Compounds - A convenient methodology for the synthesis of previously unreported (1H-indol-6-yl)phosphonic acid derivatives has been described. Reaction of... 相似文献
86.
87.
Composition-nominative logics (CNL) are program-oriented logics. They are based on algebras of partial predicates which do not have fixed arity. The aim of this work is to present CNL as institutions. Homomorphisms of first-order CNL are introduced, satisfaction condition is proved. Relations with institutions for classical first-order logic are considered. Directions for further investigation are outlined. 相似文献
88.
A new, simple, one-step synthesis of 3-substituted 3,4-dihydroisocoumarins is developed. The products are obtained by the reaction of o-methoxycarbonyl arenediazonium bromides with unsaturated compounds in the presence of CuBr as a catalyst. 相似文献
89.
Mykola Tkach Julia Seti Oxana Voitsekhivska Vasyl Gutiv Evgenia Vereshko 《Molecular Crystals and Liquid Crystals》2020,701(1):48-58
AbstractThe quantum theory of renormalized energy spectrum of the system of localized two-level quasiparticle, with degenerated spectrum, interacting with polarization phonons, being the model of multilayered nanostructure, is developed within the modified Feynman-Pines diagram technique. Effectively taking into account the multi-phonon processes, the theory is valid in a wide range of energies which contains the main states and the satellite groups of energies produced by the resonant bound-to-phonons states of quasiparticle in the vicinity of the threshold energies of their radiation. The properties of renormalized spectrum of the system are analyzed and dependences of the widths of groups of energy levels (main and satellite) on the magnitudes of inter-level coupling constants are obtained. 相似文献
90.