全文获取类型
收费全文 | 109篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 65篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 32篇 |
物理学 | 12篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 3篇 |
2020年 | 8篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 3篇 |
2015年 | 5篇 |
2014年 | 8篇 |
2013年 | 12篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 3篇 |
2009年 | 7篇 |
2008年 | 6篇 |
2007年 | 2篇 |
2006年 | 3篇 |
2005年 | 6篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 1篇 |
1999年 | 1篇 |
1927年 | 3篇 |
1926年 | 2篇 |
排序方式: 共有112条查询结果,搜索用时 31 毫秒
61.
Yuriy I. Horak Roman Z. Lytvyn Yevhen-Oleh V. Laba Yuriy V. Homza Vladimir P. Zaytsev Maryana A. Nadirova Tatiana V. Nikanorova Fedor I. Zubkov Alexey V. Varlamov Mykola D. Obushak 《Tetrahedron letters》2017,58(43):4103-4106
The reaction of readily accessible 3-(thien-2-yl)allylamines with maleic anhydride, followed by a domino sequence involving successive acylation/[4+2] cycloaddition steps, leads to the formation of the thieno[2,3-f]isoindole core. The key step, the intramolecular Diels-Alder vinylaren (IMDAV) reaction, proceeds with high level of diastereoselectivity and with formation of a single diastereoisomer of the target product 4,4a,5,6,7,7a-hexahydro-3aH-thieno[2,3-f]isoindole-4-carboxylic acids in excellent yields. If the reaction is carried out at room temperature, it occurs in 2–3 days and the proton migration (H-shift) does not take place at the last stage. In boiling benzene, the reaction is complete after three hours, but in this case a slight impurity of byproducts bearing aromatic thiophene ring – 4a,5,6,7,7a,8-hexahydro-4H-thieno[2,3-f]isoindole-4-carboxylic acids is formed. 相似文献
62.
Long-period fiber gratings as ultrafast optical differentiators 总被引:1,自引:0,他引:1
It is demonstrated that a single, uniform long-period fiber grating (LPFG) working in the linear regime inherently behaves as an ultrafast optical temporal differentiator. Specifically, we show that the output temporal waveform in the core mode of a LPFG providing full energy coupling into the cladding mode is proportional to the first derivative of the optical temporal signal (e.g., optical pulse) launched at the input of the LPFG. Moreover, a LPFG providing full energy recoupling back from the cladding mode into the core mode inherently implements second-order temporal differentiation. Our numerical results have confirmed the feasibility of this simple, all-fiber approach to processing optical signals with temporal features in the picosecond and subpicosecond ranges. 相似文献
63.
64.
65.
Vladyslav Polishchuk Mariia Filatova Dr. Eduard Rusanov Dr. Mykola Shandura 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202202168
Trianionic polymethines of the A′-π-A-π-A-π-A′ type comprising dioxaborine rings (A) and different electron-accepting end groups (A′) have been synthesized. The obtained dyes absorb and emit light in the near-infrared region with remarkably high molar attenuation coefficients (ϵ up to 495 000 M−1 cm−1 in DMF) and fluorescence quantum yields (Φf up to 0.73 in DMF). Thus, the novel trianionic dyes stand among the brightest individual fluorophores known to date – with a magnitude of fluorescence brightness (ϵ⋅Φf) of 313 000 M−1 cm−1 in DMF. The synthesized dyes demonstrate a minor negative solvatochromism and small Stokes shifts. X-ray data reveal the nearly planar geometry of the trianionic chromophore. All the obtained compounds are stable in the solid state and in a solution, although the relative stability is much higher in polar aprotic than in protic solvents. 相似文献
66.
Mykola Bratiichuk 《Statistics & probability letters》2012,82(3):496-504
In this paper, we present a new approach to the study of the Gerber-Shiu discounted function for the risk model with multi-layer dividend strategy. The formulae for the Gerber-Shiu discounted function and ruin probability were obtained and the special case where the claim size distribution is a combination of exponentials is considered in detail. 相似文献
67.
Vasyl S. Matiychuk Mykhaylo A. Potopnyk Mykola D. Obushak 《Journal of heterocyclic chemistry》2013,50(Z1):E43-E47
A new simple and convenient method of synthesis of ethyl 1‐aryl‐4‐formyl‐1H‐pyrazole‐3‐carboxylates from aromatic amines via diazonium salts has been developed. Hydrolysis and hydrazinolyization of these compounds has been investigated. 相似文献
68.
Taras O. Banakh Fedor A. Bogomolov Andrij I. Gatalevych Ihor J. Guran Yurij B. Ishchuk Mykola Ya. Komarnytskyi Igor S. Kuz Ivanna O. Melnyk Vasyl M. Petrychkovych Yaroslav G. Prytula Oleh M. Romaniv Oleh B. Skaskiv Ludmyla L. Stakhiv Georgiy T. Sullym Bohdan V. Zabavskyi Volodymir P. Zelisko Mykhajlo M. Zarichnyi 《Central European Journal of Mathematics》2013,11(9):1547-1551
69.