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391.
B. Bialecki M. Ganesh K. Mustapha 《Numerical Methods for Partial Differential Equations》2006,22(5):1052-1069
We propose and analyze a Crank–Nicolson quadrature Petrov–Galerkin (CNQPG) ‐spline method for solving semi‐linear second‐order hyperbolic initial‐boundary value problems. We prove second‐order convergence in time and optimal order H2 norm convergence in space for the CNQPG scheme that requires only linear algebraic solvers. We demonstrate numerically optimal order Hk, k = 0,1,2, norm convergence of the scheme for some test problems with smooth and nonsmooth nonlinearities. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2006 相似文献
392.
The reaction mechanism between AlX and HX (X = Br, Cl, and F) have been characterized in detail using DFT as well as the ab initio method. The reaction yielding AlX3 and molecular hydrogen was calculated to be highly exothermic. The present calculations also show that the possible routes
to the trihalides species start more favorable with the primary insertion product AlX2H than with the biadduct AlX(HX)2 one.
相似文献
393.
Ulrich Maschke Xavier Coqueret Mustapha Benmouna 《Macromolecular rapid communications》2002,23(3):159-170
This paper deals with the electro‐optic (EO) properties of polymer‐dispersed liquid crystals (PDLCs). Several systems are considered to analyze the effects of preparation conditions and film characteristics on the EO response functions. Particular emphasis is put on systems based on mixtures of the commercial compound ASX‐95, the difunctional acrylate tripropylene diacrylate and the eutectic mixture of low‐molecular‐weight liquid crystals E7. Other systems are considered to assess the influence of monomer functionality on EO properties using for example the trifunctional glycerylpropoxytriacrylate. Various modes of preparing PDLCs are considered based on the mechanism of polymerization‐induced phase separation using either electron‐beam (EB) or UV radiation curing processes. The dose is changed in both techniques to improve film strength and determine which method leads to the best samples in terms of EO response functions. Other important parameters, such as film thickness, composition and applied voltage, are also considered to evaluate the impact on these functions. The article focuses on a comparison of EO performances of films elaborated by exposure to EB and UV radiations. Under similar conditions, one definitively finds a net superiority of the former technique. In addition this technique does not require any photoinitiator and leads to a higher conversion of the monomeric compounds, i.e. higher mechanical strength and less severe aging conditions. 相似文献
394.