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51.
Ji Kaifang Chen Xuegao Aldahan Ala Yi Peng Murad Ahmed Hussein Saber Alshamsi Dalal Ahmed Mohamad M. Yu Zhongbo 《Journal of Radioanalytical and Nuclear Chemistry》2020,323(3):1055-1070
Journal of Radioanalytical and Nuclear Chemistry - Estimating groundwater recharge rate is essential for water sustainability of the arid region of the United Arab Emirates that receives most... 相似文献
52.
Muhammad Ismail M.I. Khan Murad Ali Khan Kalsoom Akhtar Abdullah M. Asiri Sher Bahadar Khan 《应用有机金属化学》2019,33(8)
Ginger rhizome powder was used for the synthesis of supported metallic nanoparticle catalysts. A simple and novel adsorption method was used for the synthesis of silver nanoparticles loaded on ginger powder (Ag/GP), copper on ginger powder (Cu/GP) and nickel on ginger powder (Ni/GP). Among these, Ag/GP showed selective reduction of methyl orange and was used for further reactions. The prepared nanomaterials were characterized through X‐ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, fourier transform infrared spectroscopy and energy‐dispersive X‐ray spectroscopy. The prepared Ag/GP catalyst was employed in the catalytic reduction of 4‐nitrophenol (4‐NP), 2‐nitrophenol (2‐NP), rhodamine B, methyl red and congo red. Ag/GP showed excellent catalytic reduction activity, the rate constants being 1.26 × 10?3 and 2.38 × 10?3 s?1 for 2‐NP and 4‐NP, respectively. The turnover frequency reached 1.06 min?1 for 2‐NP and 1.16 min?1 for 4‐NP when using the Ag/GP catalyst. The prepared Ag/GP catalyst demonstrated outstanding activity for the degradation of a mixed solution of dyes. Also, stability and reusability of the prepared catalyst were investigated, which showed outstanding reusability up to five times and was stable up to five days. 相似文献
53.
We want to compute the cumulative distribution function of a one-dimensional Poisson stochastic integral I(g) = ò0T g(s) N(ds)I(g) = \displaystyle \int_0^T g(s) N(ds), where N is a Poisson random measure with control measure n and g is a suitable kernel function. We do so by combining a Kolmogorov–Feller equation with a finite-difference scheme. We provide
the rate of convergence of our numerical scheme and illustrate our method on a number of examples. The software used to implement
the procedure is available on demand and we demonstrate its use in the paper. 相似文献
54.
P. S. Pereira Silva Raza Murad Ghalib Sayed Hasan Mehdi Rokiah Hashim Othman Sulaiman Ali Jawad 《Journal of chemical crystallography》2010,40(12):1150-1154
Abstract
Cyclohexyl N-phenylcarbamate, C13H17NO2 (I), which is a useful target for biotransformations by fungi, has been synthesized and the structure has been solved by X-ray diffraction. The crystals are triclinic, space group P [`1] \bar{1} , with a = 5.2581 (2) ?, b = 9.5080 (3) ?, c = 12.6165 (4) ?, α = 70.544 (2)°, β = 89.075 (2)°, γ = 80.447 (2)°, M r = 219.28, V = 585.96 (3) ?3, Z = 2 and R = 0.065. In the title compound the phenyl ring makes a dihedral angle of 30.68(7)° with the carbamate group The molecules are linked into infinite chains via N–H···O hydrogen bonds along the a axis. These hydrogen-bonded chains are further linked by weaker C–H···π interactions. Quantum-mechanical ab initio calculations for the free molecule reproduce well the observed bond lengths and valency angles but show that the crystal packing might be responsible for the rotation of the phenyl ring out of the carbamate plane in the solid state conformation. 相似文献55.
Molecular dynamics simulations are carried out to investigate the permeation of ions and water in a membrane consisting of single wall carbon nanotubes possessing no surface charges connecting two reservoirs. Our simulations reveal that there are changes in the first hydration shell of the ions upon confinement in tubes of 0.82 or 0.90 nm effective internal diameter. Although the first minimum in the g(r) is barely changed in the nanotube compared to in the bulk solution, the hydration number of Na(+) ion is reduced by 1.0 (from 4.5 in bulk to 3.5 in the 0.90 nm tube) and the hydration number is reduced further in the 0.82 nm tube. The changes in the hydration shell of Cl(-) ion are negligible, within statistical errors. The water molecules of the first hydration shell of both ions exchange less frequently inside the tube than in the bulk solution. We compare ion trajectories for ions in the same tube under identical reservoir conditions but with different numbers of ions in the tubes. This permits investigation of changes in structure and dynamics which arise from multiple ion occupancy in a carbon nanotube possessing no surface charges. We also investigated the effects of tube flexibility. Ions enter the tubes so as to form a train of ion pairs. We find that the radial distribution profiles of Na(+) ions broaden significantly systematically with increasing number of ion pairs in the tube. The radial distribution profiles of Cl(-) ions change only slightly with increasing number of ions in the tube. Trajectories reveal that Na(+) ions do not pass each other in 0.90 nm tubes, while Cl(-) ions pass each other, as do ions of opposite charge. An ion entering the tube causes the like-charged ions preceding it in the tube to be displaced along the tube axis and positive or negative ions will exit the tube only when one or two other ions of the same charge are present in the tube. Thus, the permeation mechanism involves multiple ions and Coulomb repulsion among the ions plays an essential role. 相似文献
56.
The multifractional Brownian motion (MBM) processes are locally self-similar Gaussian processes. They extend the classical fractional Brownian motion processes BH={BH(t)}t∈R by allowing their self-similarity parameter H∈(0,1) to depend on time. 相似文献
57.
58.
59.
Estimating the Heavy Tail Index from Scaling Properties 总被引:4,自引:0,他引:4
This paper deals with the estimation of the tail index for empirical heavy-tailed distributions, such as have been encountered in telecommunication systems. We present a method (called the scaling estimator) based on the scaling properties of sums of heavy-tailed random variables. It has the advantages of being nonparametric, of being easy to apply, of yielding a single value, and of being relatively accurate on synthetic datasets. Since the method relies on the scaling of sums, it measures a property that is often one of the most important effects of heavy-tailed behavior. Most importantly, we present evidence that the scaling estimator appears to increase in accuracy as the size of the dataset grows. It is thus particularly suited for large datasets, as are increasingly encountered in measurements of telecommunications and computing systems. 相似文献
60.
Let α? (1,2) and X
α
be a symmetric α-stable (S α S) process with stationary increments given by the mixed moving average
where is a standard Lebesgue space, is some measurable function and M
α
is a SαS random measure on X ×ℝ with the control measure m
α
(dx, du) = μ(dx)du. We show that if X
α
is self-similar, then it is determined by a nonsingular flow, a related cocycle and a semi-additive functional. By using
the Hopf decomposition of the flow into its dissipative and conservative components, we establish a unique decomposition in
distribution of X
α
into two independent processes
where the process X
α
D
is determined by a nonsingular dissipative flow and the process X
α
C
is determined by a nonsingular conservative flow. In this decomposition, the linear fractional stable motion, for example,
is determined by a conservative flow.
Received: 20 June 2000 / Revised version: 6 September 2001 / Published online: 14 June 2002 相似文献