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911.
Iqbal K Malik A Mukhtar N Anis I Khan SN Choudhary MI 《Chemical & pharmaceutical bulletin》2004,52(7):785-789
Three C-alkylated flavonoids 7-O-alpha-D-glucopyranosyl-3,5-dihydroxy-3'-(4"-acetoxyl-3"-methylbutyl)-6,4'-dimethoxyflavone (1), 7-O-alpha-D-glucopyranosyl-3,4'-dihydroxy-3'-(4"-acetoxyl-3"-methylbutyl)-5,6-dimethoxyflavone (2), 3,7,4'-trihydroxy-3'-(8"-acetoxy-7"-methyloctyl)-5,6-dimethoxyflavone (3) and a trans-clerodane type diterpenoid (-)-6beta-hydroxy-5beta,8beta,9beta,10alpha-cleroda-3,13-dien-16,15-olid-18-oic acid (4) are reported from Duranta repens along with (+)-hardwickiic acid (5) and (+)-3,13-clerodadien-16,15-olid-18-oic acid (6), isolated for the first time from this species. Their structures were established on the basis of the spectral methods, especially two dimensional (2D) NMR spectroscopy. 相似文献
912.
The ethyl acetate soluble part of the chloroform extract of Pulicaria gnaphalodes belonging to the family Asteraceae afforded a new sesquiterpene-dimer of guaiane class named as gnapholide and anabsinthin of the same skeleton. The structures of both the compounds were elucidated with the aid of spectroscopic techniques including 2D NMR. 相似文献
913.
A new triterpene named as alysinol 3alpha, 22beta-dihydroxyolean-12-ene [structure: see text] along with known compounds usnic acid, methyl 2,4-dihydroxy-3,6-dimethyl benzoate, 3-hydroxy benzoic acid, stigmasterol, poriferasterol and ursolic acid have been isolated from Alysicarpus monolifer. The structure of [structure: see text] has been established through spectroscopic techniques. 相似文献
914.
We have developed an accurate and highly efficient method for upscaling and simulation of immiscible displacements in three-dimensional
(3D) heterogeneous reservoirs, which is an extension of the technique that we developed previously for 2D systems. The method
utilizes wavelet transformations (WTs) to upscale the geological model of a reservoir, based on the spatial distribution of
the single-phase permeabilities and the locations of the wells in the reservoir. It generates a non-uniform grid in which
the resolved structure of the fine grid around the wells, as well as in the high-permeability sectors, are preserved, but
the rest of the grid is upscaled. A robust uplayering procedure is used to reduce the number of the layers, and the WTs are
used to upscale each layer areally. To demonstrate the method’s accuracy and efficiency, we have applied it to the geological
model of a highly heterogeneous reservoir put forward in the tenth Society of Petroleum Engineers comparative solution project
(the SPE-10 model), and carried out simulation of waterflooding in the upscaled model. Various upscaling scenarios were examined,
and although some of them resulted in efficient simulations and accurate predictions, the results when non-uniform upscaling
is used based on the WT technique are in excellent agreement with the solution of the same problem in the fine grid of the
SPE-10 model. Most importantly, the speed-up factors that we obtain are several orders of magnitude. Hence, the method renders
it unnecessary to use massively parallel computations for such problems. 相似文献
915.
916.
Saeed‐ur‐Rehman Muhammad Arshad Masood Ahmad Khalid Masud Abdul Ghani Nasima Arshad Ammad Hussain Qureshi Sohail Akhtar Ghauri 《中国化学会会志》2000,47(3):501-508
Some of the bis‐complexes of a derivative of phenhomazine (dibenzo[b,f][1:5]diazocine‐6:12‐dione; PHZD) with Ni(II), Cu(II), Co(II), Cd(II), Zn(II) and Hg(II) of the general formula M(PHZD)2X2 [where X = C1, Br and I], were prepared and identified. These complexes have been characterised on the basis of elemental analysis, and spectroscopic, magnetic and conductance data. The thermal mode of decomposition and thermal stability of these complexes was investigated on the basis of the respective thermal curves in a static air atmosphere. The thermoanalytical investigations indicate that these complexes undergo two‐step changes as temperature is raised, except for Cd(II) and Hg(II) complexes, with the formation of metal oxides as end product. The degradation mechanism of the complexes has also been proposed. 相似文献
917.
Bilal Akram Dr. Wenxiong Shi Hao Zhang Shaheed Ullah Muhammad Khurram Prof. Dr. Xun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(22):8575-8579
A single-step solution-based strategy is used to obtain 2D Janus-like free-standing ultrathin nanosheets build from two structurally unrelated species, that is, polyoxomolybdate (POM) and CoO. A controlled 2D-to-1D morphological transition was achieved by judiciously adjusting the solvent choice. These POM-CoO heterostructures can behave as an ideal catalyst for the epoxidation of styrene. Benefiting from their amphiphilic nature, these 2D POM-CoO nanosheets have also been used as surfactant to emulsify immiscible solvents. It is anticipated that structurally diverse polyoxometalates will offer promise as design elements for variety of structurally and compositionally tunable van der Waals integrated heteromaterials having a broad range applications. 相似文献
918.
Muhammad Aizaz Ud Din Syed Irfan Sami Ullah Dar Syed Rizwan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(25):5662-5666
The design of a three-dimensional structure for an Ir-based catalyst offers a great opportunity to improve the electrocatalytic performance and maximize the use of the precious metal. Herein, a novel wet chemical strategy is reported for the synthesis of an IrRuMn catalyst with a sphere structure and porous features. In the synthetic process, the combined use of citric acid and formamide is requisite for the formation of the sphere structure. This method leads to a favorable 3D IrRuMn sphere structure with many fully exposed active sites. Furthermore, an alloying noble metal, such as Ir or Ru, with the transition metal leads to enhanced oxygen evolution reaction (OER) activity. The doping of a transition metal, such as Mn, is an interesting example, because it exhibits stability and activity in both acidic and alkaline media. For the OER, the IrRuMn sphere catalyst exhibits an overpotential of 260 mV at a current density of 10 mA cm−2 in strongly acidic 0.1 m HClO4, which is superior to that of a commercial IrO2/C catalyst. This approach provides a novel way to synthesize an Ir-based multimetallic spherical electrocatalyst, which exhibits exceptional efficiency for the acidic OER. It will pave the way for new approaches to the practical utilization of PEM electrolyzers. 相似文献
919.
NiS (nickel sulfide)–In2O3 (indium oxide) nanostructures and NiS–In2O3 decorated on graphene oxide (GO) were demonstrated by ultrasonic/hydrothermal method. The structural study demonstrates the preparation of bixbyite and hexagonal phase of In2O3 and NiS for all of the synthesized catalysts. The band gap of the synthesized catalyst was determined to be in the range of 2.30–3.00 eV. A morphological evaluation by field emission scanning electron microscopy of NiS–In2O3 decorated on graphene oxide shows support for the NiS–In2O3 on the graphene oxide layer. Different test parameters were performed to study the phase and morphology. The particle sizes of the In2O3, NiS–In2O3 and NiS–In2O3/GO nanocomposites were 56.0, 62.0 and 66.0 nm, respectively. The photocatalytic performance of NiS–In2O3/GO nanocomposites was examined for the degradation of methylene blue dye under a UV lamp. The prepared sample shows 98.25% photocatalytic degradation within 40 min and at pH 9. With the presence the NiS and GO, the photo-degradation capacities of In2O3 and NiS–In2O3 are improved owing to the low band gap being calculated in UV–vis DRS analysis. The high ratio of NiS causes the highest photocatalytic properties of NiS–In2O3 nanocomposites owing to the enhancement of charge separation efficiency and generation of hydroxyl radicals. This study presents a facile and low-cost method to prepare highly active NiS–In2O3/GO nanocomposites. The antibacterial data indicate the significant properties of NiS–In2O3/GO nanocomposites for this study. 相似文献
920.
Khan Muhammad A. Mahmood Hasan Khan Mumtaz S. Iqbal Tariq Ahmad Pervaiz Shafique Muhammad Naeem Muhammad 《Journal of Solid State Electrochemistry》2020,24(5):1123-1132
Journal of Solid State Electrochemistry - In this research work, CuO nanostructures were synthesized using atmospheric pressure microplasma (AMP) electrochemical process. The synthesized CuO... 相似文献