Synthesis of 1-azaxanthones by condensation of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with 3-(cyano)benzopyrylium triflates and subsequent domino ‘retro-Michael/nitrile-addition/heterocyclization’ reaction

Functionalized 1-azaxanthones (5-oxo-5H-[1]-benzopyrano[2,3-b]pyridines) were prepared by TMSOTf-mediated condensation of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with 3-cyanochromones and subsequent base-mediated domino ‘retro-Michael/nitrile-addition/heterocyclization’ reaction.     

Large Signal Analysis of the Infrared Semiconductor Mercury-Cadmium-Telluride Detectors

A mathematical model for the relationship between the output voltage and incident radiation of the infrared semiconductor mercury-cadmium-telluride (MCT) detector is presented. The model, basically a sine-series function, can easily yield closed-form expressions for the harmonic and intermodulation performance of the MCT detector with large-amplitude multisinusoidal incident radiation. The special case of two-tone equal-amplitude incident radiation is considered in detail. The results show that the second-order harmonic and intermodulation products are always higher than the third-order components. Moreover, the results show that the second-order intermodulation is always dominant.     

Harmonic and Intermodulation Performance of the Semiconductor Bolometer

A mathematical model for the temperature dependence of the bolometer semiconductor resistance is presented. The model, basically a sine-series function, can easily yield closed-form expressions for the harmonic and intermodulation performance of the acquired interferogram voltage with large-amplitude multisinusoidal variations in the incident radiation. The special case of two-tone equal-amplitude incident radiation is considered in detail. The results show that the intermodulation components are always higher than the harmonic components of the same order. The results also show that the second-order intermodulation is always dominant and is higher than the second-harmonic component by about 6 dB. Moreover, the results show that for relatively small incident amplitudes of the incident radiation the ratio between the second- and third-harmonic components is almost equal to the ratio between the second-harmonic component and the fundamental. The results also show that the ratio between the amplitudes of the second- and third-order intermodulation components is almost equal to the ratio between the amplitudes of the second-order intermodulation component and the fundamental.     

Formation of layered titania and zirconia catalysed by surface-bound silicatein

Silicatein immobilised on self-assembled polymer layers using a histidine-tag chelating anchor group retains its hydrolytical activity for the formation of biosilica, and catalyses the formation of layered arrangements of biotitania and biozirconia.     

Haloxylines A and B, antifungal and cholinesterase inhibiting piperidine alkaloids from Haloxylon salicornicum

Haloxylines A (1) and B (2), new piperidine alkaloids, have been isolated from the chloroform soluble fraction of Haloxylon salicornicum and their structures elucidated by spectroscopic techniques including 2D-NMR. Both the compounds displayed antifungal and cholinesterase enzymes inhibitory potentials.     

The crystal structure and thermal stability of [bis-picrate(pentaethylene glycol)] praseodymium(III)picrate complex

[Bis-picrate(pentaethylene glycol)]praseodymium(III) picrate, [Pr(pic)₂⋅(EO5]⁺[pic]⁻, was successfully obtained from the reaction of praseodymium nitrate hexahydrate, picric acid and pentaethylene glycol in acetonitrile–methanol as solvent. The crystal system is monoclinic with space group P2₁/c, a = 18.91419(11) Å, b = 9.0470(6) Å, c = 24.1209(14) Å and α = γ = 90^∘, β = 109.07(1)^∘, V = 3880.3(4) ų and Z = 4. The Pr atom is coordinated to the flexible and open EO5 ring via all the six oxygen atoms and two picrate ligands, one via phenoxo oxygen atom and the other one with both phenoxo and nitro oxygen atoms in a bidentate manner resulting a 9-coordinate tricapped trigonal prismatic geometry. The two picrate ligands coordinated to the Pr atom are at the opposite sides of the hexadentate EO5 ring with phenyl fragments almost perpendicular with dihedral angle of 89.7(3)^∘. Thermal analysis results show that the complex is stable up to 100^∘C when it began to slowly decompose and followed by an explosive decomposition at 290^∘C.     

Lipoxygenase inhibiting ethyl substituted glycoside from Symplocos racemosa

Phytochemical investigation of Symplocos racemosa resulted in the isolation of a new ethyl substituted glycoside, 1-ethyl brachiose-3'-acetate (1) along with four known compounds ketochaulmoogric acid (2), nonaeicosanol (3), triacontyl palmitate (4) and methyl triacontanoate (5). The substitution of ethyl group on 1 was natural because during the course of extraction and purification ethanol was not used. The structural elucidation of the isolated compounds was based primarily on 1D- and 2D-NMR analysis, including COSY, HMQC, and HMBC correlations. The glycoside 1 and triacontyl palmitate (4) displayed the inhibitory potential against lipoxygenase and urease enzyme, respectively.     

Parkintin: a new flavanone with epoxy-isopentyl moiety from Parkinsonia aculeata Linn. (Caesalpiniaceae)

A new flavanone with epoxy-isopentyl moiety named parkintin has been isolated from the methanol soluble part of Parkinsonia aculeata Linn. belonging to the family Caesalpiniaceae. The structure of parkintin has been established with the aid of spectroscopic techniques including COSY and HMBC experiments.