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81.
M.A.G. Soler G.B. Alcantara W.R. Viali J.R.L. Fernandez V.K. Garg P.C. Morais 《Surface science》2007,601(18):3921-3925
In this study γ-Fe2O3 nanoparticle, surface-coated with increasing amount of oleic acid, have been prepared while the stability against particle degradation under laser excitation intensity was investigated. Maghemite nanoparticle was obtained via oxidation of magnetite nanoparticle, the latter synthesized by co-precipitation of Fe (II) and Fe (III) ions in alkaline medium. By varying the experimental conditions of surface-coating maghemite nanoparticles with oleic acid, samples with different grafting coefficient were obtained and investigated using X-ray diffraction and different spectroscopic techniques, namely Raman, Mössbauer, and infrared. The amount of oleic acid adsorbed on the maghemite surface was estimated via the carbon content obtained from elemental analysis. 相似文献
82.
Recent X-ray diffraction studies on α-quartz (SiO2) by Kingmaet al [1], have shown the occurrence of a reversible, crystalline-to-crystalline, phase transition just prior to amorphization
at ≈ 21 GPa. This precursor transition has also been confirmed by our recent molecular dynamics simulation study [2]. In order
to investigate the possibility of a similar behaviour in other isostructural compounds, which also undergo pressure induced
amorphization, α-GeO2 and α-AlPO4 (berlinite form) were studied using energy dispersive X-ray diffraction. In either of these materials, no such phase transition
is detected prior to amorphization. The onset of amorphization and its reversal is found to be time dependent in GeO2. 相似文献
83.
84.
In the present paper, we solve three boundary value problems related to the temperature field in oil strata — the fractional
extensions of the incomplete lumped formulation and lumped formulation in the linear case and the fractional generalization
of the incomplete lumped formulation in the radial case. By using the Caputo differintegral operator and the Laplace transform,
the solutions are obtained in integral forms where the integrand is expressed in terms of the convolution of some auxiliary
functions of Wright function type. A generalization of the Laplace transform convolution theorem, known as Efros’ theorem
is widely used. 相似文献
85.
86.
87.
A method to study domain structure in ferroelectrics, using pyroelectric effect is described. Variation of pyroelectric signal
from the surface of a triglycine sulphate crystal plate has been studied by scanning the surface of the crystal with a low
wattage He-Ne laser beam. The integrated pyroelectric signal is due to two components, namely, (1) the primary component arising
out of the change in spontaneous polarization with temperature and (2) the delayed component arising out of the possible polarization
reversal. The component of an electric field along the ferroelectric axis due to thermal hemisphere within the crystal plate
formed by the laser beam has been calculated and shown to exceed coercive field, making polarization reversal possible. The
delayed pyroelectric signal is a measure of polarization reversal within the patch illuminated and its observed variation
over the surface yields information of the domain structure. 相似文献
88.
Kumar DN Garg BS 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,64(1):141-147
Complexes of zinc(II) with N,N'-disalicylidene-1,2-phenylenediamine (H2dsp), N,N'-disalicylidene-3,4-diaminotoluene (H2dst), 4-nitro-N,N'-disalicylidene-1,2-phenylenediamine (H2ndsp) and N,N'-disalicylidene ethylenediamine (H2salen) have been prepared and characterized by elemental analysis, electronic, IR, 1H NMR and thermal studies. TG studies show that all complexes decomposed in one step. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The activation energy of complexes lies 60-87 kJ mol(-1) range. 相似文献
89.
Gamma-ray induced decomposition of binary mixtures of potassium nitrate with 90, 70, 50, 30 and 10 mol% SiO2, Al2O3, MnO2, V2O5, La2O3, CeO2, Sm2O3, Eu2O3, Gd2O3 and Dy2O3 has been studied at different doses up to 500 kGy. Radiolytic decomposition of the nitrate is affected by the concentration
of the oxide in the binary mixture as well as by the absorbed dose. The enhancement is up to 103 times at 90 mol% of the additive.G(NO2
−) values calculated on the basis of electron fraction of the nitrate decrease with the increasing concentration of the nitrate.
A comparison ofG(NO2
−) for 90 mol% oxides shows decreasing trend as Gd2O3>Sm2O3≈Dy2O3> Eu2O3>CeO2>Al2O3>V2O5>SiO2>MnO2. ESR and TL measurements suggest the formation of radical species which interact with the radical species of nitrate causing
enhanced decomposition by energy transfer mechanism. 相似文献
90.
Polycyclic aromatic hydrocarbons (PAHs), apart from their carcinogenic and mutagenic nature, create many problems in the petrochemical industry due to their tendency toward carbonization. Compounds in C8 aromatic isomer feed are analyzed by means of sample concentration, followed by separation of individual compounds by gas chromatography on a stainless steel OV-101 phase capillary column and identification by gas chromatography/mass spectrometry and gas chromatography/Fourier transform infrared spectroscopy. Various compounds belonging to different classes (mainly monocyclic, dicyclic, and tricyclic aromatics), oxygenated aromatics, and aliphatic saturates are quantified in the concentrated hydrocarbon residue of C8 isomer feed. Both unsubstituted and alkyl substituted ring type compounds are present. Concentrations obtained for PAH compounds in the C8 isomer feed range from 0.2 to 0.42 micrograms/mL. 相似文献