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61.
Gerelli Y Barbieri S Di Bari MT Deriu A Cantù L Brocca P Sonvico F Colombo P May R Motta S 《Langmuir : the ACS journal of surfaces and colloids》2008,24(20):11378-11384
The combined use of cryo-TEM, dynamic light scattering, and small-angle X-ray and neutron scattering techniques allows a detailed structural model of complex pharmaceutical preparations of soybean lecithin/chitosan nanoparticles used as drug vectors to be worked out. Charge-driven self-organization of the lipid(-)/polysaccharide(+) vesicles occurs during rapid injection, under mechanical stirring, of an ethanol solution of soybean lecithin into a chitosan aqueous solution. We conclude that beyond the charge inversion region of the phase diagram, i.e., entering the redissolution region, the initial stages of particle formation are likely to be affected by a re-entrant condensation effect at the nanoscale. This behavior resembles that at the mesoscale which is well-known for polyion/amphiphile systems. Close to the boundary of the charge inversion region, nanoparticle formation occurs under a maximum condensation condition at the nanoscale and the complexation-aggregation process is driven toward a maximum multilamellarity. Interestingly, the formulation that maximizes vesicle multilamellarity corresponds to that displaying the highest drug loading efficiency. 相似文献
62.
Anna Maria Marini Federico Da Settimo Silvia Salerno Concettina La Motta Francesca Simorini Sabrina Taliani Daniele Bertini Ornella Gia Lisa Dalla Via 《Journal of heterocyclic chemistry》2008,45(3):745-749
63.
Laure Motta Jean-Bernard Regnouf De Vains Claude Bavoux Monique Perrin 《Journal of chemical crystallography》1995,25(7):401-406
The title compound was obtained by treatment ofp-tert-butylcalix[4]arene with (+) camphorsulfonyl chloride in triethylamine and toluene. A (12) complex with toluene has been found. Its structure has been determined by X-ray crystallography. Crystals are triclinic with space group P1,a=16.426(3),b=18.553(3),c=13.661(2) Å, =94.78(2), =110.76(2), =72.83(2)°,V=3720(2) Å3,d
c
=1.127 g/cm3
Z=2. Refinement based on 10495 observed reflections led to a finalR value of 0.100. The two independent molecules of calixarene in the asymmetric unit are in the cone conformation and the calixarene cavities are empty. The guest molecule occupies the interhost space. The norborane skelton of (+) camphorsulfonyl group is the same as ones found in literature. Only van der Waals interactions exist between the host and the guest molecules. 相似文献
64.
65.
Felipe Augusto Ferrari Fernanda Lopes Motta Reinaldo Gaspar Bastos Maria Helena Andrade Santana 《Applied biochemistry and biotechnology》2013,170(6):1491-1502
Hyaluronic acid (HA) is a biopolymer with important applications in the pharmaceutical, medical, and cosmetic fields. This work explores the potentialities of a cylindrical polyurethane foam dowel with central aeration as a novel packed bed bioreactor for the production of HA. The goals were to provide a large surface area for oxygen transfer through the patches of liquid film that form in the pores of the foam in which cell proliferation and HA production occur and to easily recover the HA produced. The resulting yields of HA/cell were higher than 1, and the produced HA was completely recovered by pressing the foam. The external conditions that inhibit catabolism, the deviation of energetic metabolism toward the production of HA, were modulated by aeration and the initial glucose concentration. The production of HA was reproducible in 12 successive fermentation cycles. These findings contribute to the development of efficient strategies for the controlled production and recovery of HA. 相似文献
66.
Y Li W Xu S Di Motta F Negri D Zhu Z Wang 《Chemical communications (Cambridge, England)》2012,48(66):8204-8206
Annulation of thiophenes directly into the bay regions of rylene dyes through effective Stille coupling and subsequent ring-fusion under Scholl conditions leads to core-extended rylene tetracarboxylic diimides with interesting electro-optical properties. 相似文献
67.
Monica Motta 《Applied Mathematics and Optimization》2003,49(1):1-26
We study a class of infinite horizon and exit-time control problems
for nonlinear systems with unbounded data
using the dynamic programming approach. We prove local optimality principles for viscosity
super- and subsolutions of degenerate Hamilton–Jacobi equations in a very general
setting. We apply these results to characterize the (possibly multiple) discontinuous
solutions of Dirichlet and free boundary value problems as suitable
value functions for the above-mentioned control problems. 相似文献
68.
G. Baccolo C. Baroni M. Clemenza B. Delmonte V. Maggi A. Motta M. Nastasi E. Previtali M. C. Salvatore 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(3):1615-1623
The elemental composition of 40 samples of mineral sediments collected in Victoria Land, Antarctica, in correspondence of ice-free sites, is presented. Concentration of 36 elements was determined by instrumental neutron activation analysis, INAA. The selection of 6 standard reference materials and the development of a specific analytical procedure allowed to reduce measurements uncertainties and to verify the reproducibility of the results. The decision to analyze sediment samples from Victoria Land ice-free areas is related to recent investigations regarding mineral dust content in the TALos Dome ICE core (159°11′E; 72°49′S, East Antarctica, Victoria Land), in which a coarse local fraction of dust was recognized. The characterization of Antarctic potential source areas of atmospheric mineral dust is the first step to identify the active sources of dust for the Talos Dome area and to reconstruct the atmospheric pathways followed by air masses in this region during different climatic periods. Principal components analysis was used to identify elements and samples correlations; attention was paid specially to rare earth elements (REE) and incompatible/compatible elements (ICE) in respect to iron, which proved to be the most discriminating elemental groups. The analysis of REE and ICE concentration profiles supported evidences of chemical weathering in ice-free areas of Victoria Land, whereas cold and dry climate conditions of the Talos Dome area and in general of East Antarctica. 相似文献
69.
Paulo Roberto Martins Alessandra Gonçalves Nery Motta Marcelo Nakamura Koiti Araki Lúcio Angnes 《Electroanalysis》2013,25(9):2060-2066
Nanostructured alpha‐nickel hydroxide (α‐Ni(OH)2) immobilized on a Fluorine‐doped Tin Oxide (FTO) surface was explored for the construction of hydrogen peroxide amperometric Flow Injection Analysis (FIA) sensors. Their notable electrocatalytic activity and heterogeneous electron‐transfer rate were confirmed by the appearance of a broad and intense peak associated with the oxidation of hydrogen peroxide and the enhancement of sensibility in hydrodynamic conditions. The α‐Ni(OH)2 electrodes exhibited a broad dynamic range (5×10?6 to 1×10?3 mol L?1), low detection limit (2×10?7 mol L?1), good repeatability (RSD=1.29 % for 20 successive analyses), and a sensitivity greater than 500 µA mmol?1 L?1 cm?2. 相似文献
70.
Antonio Da Settimo Giampaolo Primofiore Anna Maria Marini Federico Da Settimo Concettina La Motta Silvia Salerno 《Journal of heterocyclic chemistry》1999,36(3):639-642
The preparation of two new heterocyclic ring systems, purinobenzodiazepine and purinobenzotriazocine derivatives by the condensation of 8-aminotheophylline or 8-hydrazinotheophylline with o-carboxybenzaldehyde or o-carboxyacetophenone is described. 相似文献